dc.creatorNakagaki, S
dc.creatorXavier, CR
dc.creatorWosniak, AJ
dc.creatorMangrich, AS
dc.creatorWypych, F
dc.creatorCantao, MP
dc.creatorDenicolo, I
dc.creatorKubota, LT
dc.date2000
dc.dateAUG 31
dc.date2014-12-02T16:26:46Z
dc.date2015-11-26T17:40:18Z
dc.date2014-12-02T16:26:46Z
dc.date2015-11-26T17:40:18Z
dc.date.accessioned2018-03-29T00:21:58Z
dc.date.available2018-03-29T00:21:58Z
dc.identifierColloids And Surfaces A-physicochemical And Engineering Aspects. Elsevier Science Bv, v. 168, n. 3, n. 261, n. 276, 2000.
dc.identifier0927-7757
dc.identifierWOS:000087469300008
dc.identifier10.1016/S0927-7757(99)00503-8
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/74062
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/74062
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/74062
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1286687
dc.descriptionMetalloporphyrins of Fe(III) and Cu(II) were prepared inside the large pores of the zeolite NaY by a process of sequential introduction of components followed by assembly inside the void space of the zeolite. The appropriate process chosen for the porphyrin synthesis was using the propionic acid solvent for reaction between pyrrole and benzaldehyde and this solvent was not destructive for zeolite. The powder X-ray diffraction data confirmed that the crystallinity of the zeolite was maintained. The resulting materials were purified by Soxhlet extractor. The zeolite-included metalloporphyrins were identified for studies using UV-Vis, FTIR and EPR Spectroscopy, CA (chemical analysis), AAS (atomic absorption spectroscopy), TG/DSC, XRD, SEM and (13)C-NMR techniques. The catalytic activity of these products was examined and the catalyst showed to be a promising catalytic system to aliphatic hydrocarbon oxidation reactions. (C) 2000 Elsevier Science B.V. All rights reserved.
dc.description168
dc.description3
dc.description261
dc.description276
dc.languageen
dc.publisherElsevier Science Bv
dc.publisherAmsterdam
dc.publisherHolanda
dc.relationColloids And Surfaces A-physicochemical And Engineering Aspects
dc.relationColloid Surf. A-Physicochem. Eng. Asp.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectporphyrin
dc.subjectcytochrome P-450
dc.subjectzeolite
dc.subjectimmobilized catalyst
dc.subjectencapsulation
dc.subjectCopper(ii) Porphyrins
dc.subjectComplexes
dc.subjectOxidation
dc.subjectCatalysts
dc.subjectIron
dc.subjectPhthalocyanines
dc.subjectHydrocarbons
dc.subjectRothemund
dc.subjectChemistry
dc.subjectMatrices
dc.titleSynthesis and characterization of zeolite-encapsulated metalloporphyrins
dc.typeArtículos de revistas


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