| dc.creator | Gazotti, WA | |
| dc.creator | Spinace, MAS | |
| dc.creator | Girotto, EM | |
| dc.creator | De Paoli, MA | |
| dc.date | 2000 | |
| dc.date | MAY | |
| dc.date | 2014-12-02T16:30:22Z | |
| dc.date | 2015-11-26T17:39:43Z | |
| dc.date | 2014-12-02T16:30:22Z | |
| dc.date | 2015-11-26T17:39:43Z | |
| dc.date.accessioned | 2018-03-29T00:21:17Z | |
| dc.date.available | 2018-03-29T00:21:17Z | |
| dc.identifier | Solid State Ionics. Elsevier Science Bv, v. 130, n. 41732, n. 281, n. 291, 2000. | |
| dc.identifier | 0167-2738 | |
| dc.identifier | WOS:000087541300011 | |
| dc.identifier | 10.1016/S0167-2738(00)00550-6 | |
| dc.identifier | http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/70694 | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/70694 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/70694 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1286519 | |
| dc.description | In this work we studied the ionic conductivity for three copolymers of the title co-monomers as a function of LIClO4 content, temperature and ambient relative humidity. We also investigated the interactions between the salt and the co-monomer blocks in the copolymers and its effect on the morphology and thermal properties of the copolymer/salt complexes. Our data indicate that the Li+ ion predominantly interacts with the ethylene oxide repeating units of the copolymers. The copolymer with the highest ionic conductivity was obtained with an ethylene oxide/epichlorohydrin ratio of 84/16 containing 5.5% (w/w) of LiClO4. It showed a conductivity of 4.1 X 10(-5) S cm(-1) (30 degrees C, humidity < 1 ppm) and 2.6 X 10(-4) S cm(-1) at 84% relative humidity (24 degrees C). The potential stability window of the copolymer/salt complex is 4.0 V, as measured by cyclic voltammetry. For comparison, we also prepared a blend of the corresponding homopolymers containing LiClO4; it showed higher crystallinity and lower ionic conductivity. (C) 2000 Elsevier Science B.V. All rights reserved. | |
| dc.description | 130 | |
| dc.description | 41732 | |
| dc.description | 281 | |
| dc.description | 291 | |
| dc.language | en | |
| dc.publisher | Elsevier Science Bv | |
| dc.publisher | Amsterdam | |
| dc.publisher | Holanda | |
| dc.relation | Solid State Ionics | |
| dc.relation | Solid State Ion. | |
| dc.rights | fechado | |
| dc.rights | http://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy | |
| dc.source | Web of Science | |
| dc.subject | polymeric electrolyte | |
| dc.subject | ionic conductivity | |
| dc.subject | ethylene oxide copolymers | |
| dc.subject | elastomers | |
| dc.subject | Ionic-conductivity | |
| dc.subject | Poly(ethylene Oxide) | |
| dc.subject | Complexes | |
| dc.subject | Blends | |
| dc.subject | Salts | |
| dc.title | Polymer electrolytes based on ethylene oxide-epichlorohydrin copolymers | |
| dc.type | Artículos de revistas | |
