| dc.creator | DESOUZA, AG | |
| dc.creator | DESOUZA, JH | |
| dc.creator | AIROLDI, C | |
| dc.date | 1991 | |
| dc.date | JUL | |
| dc.date | 2014-12-16T11:37:08Z | |
| dc.date | 2015-11-26T17:27:27Z | |
| dc.date | 2014-12-16T11:37:08Z | |
| dc.date | 2015-11-26T17:27:27Z | |
| dc.date.accessioned | 2018-03-29T00:14:35Z | |
| dc.date.available | 2018-03-29T00:14:35Z | |
| dc.identifier | Journal Of The Chemical Society-dalton Transactions. Royal Soc Chemistry, n. 7, n. 1751, n. 1754, 1991. | |
| dc.identifier | 0300-9246 | |
| dc.identifier | WOS:A1991FW47800016 | |
| dc.identifier | 10.1039/dt9910001751 | |
| dc.identifier | http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/56589 | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/56589 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/56589 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1284799 | |
| dc.description | The standard molar enthalpies of formation of crystalline [M(S2CNBu(n)2)2] (M = Zn, Cd or Hg), determined through reaction-solution calorimetry at 298.15 K, were found to be -471.23 +/- 3.90, -440.74 +/- 3.79 and -319.29 +/- 3.38 kJ mol-1, respectively. The corresponding molar enthalpies of sublimation, 107 +/- 3, 123 +/- 3 and 195 +/- kJ mol-1, were estimated by means of differential scanning calorimetry. From the standard molar enthalpies of formation of the gaseous chelates, -364 +/- 5, 318 +/- 5 and -124 +/- 5 kJ mol-1, the homolytic and heterolytic mean metal-sulphur bond enthalpies were calculated. The homolytic enthalpies decrease from zinc to mercury, while the heterolytic values are almost constant. | |
| dc.description | 7 | |
| dc.description | 1751 | |
| dc.description | 1754 | |
| dc.language | en | |
| dc.publisher | Royal Soc Chemistry | |
| dc.publisher | Cambridge | |
| dc.publisher | Inglaterra | |
| dc.relation | Journal Of The Chemical Society-dalton Transactions | |
| dc.relation | J. Chem. Soc.-Dalton Trans. | |
| dc.rights | fechado | |
| dc.source | Web of Science | |
| dc.subject | Dissociation Enthalpies | |
| dc.subject | Complexes | |
| dc.subject | Thermochemistry | |
| dc.subject | Ligands | |
| dc.title | METAL-SULFUR BOND ENTHALPY DETERMINATION OF DI-NORMAL-BUTYLDITHIOCARBAMATE CHELATES OF ZINC, CADMIUM AND MERCURY | |
| dc.type | Artículos de revistas | |
