Application of the Prigogine-Flory-Patterson model to excess molar enthalpy of binary liquid mixtures containing acetonitrile and 1-alkanol

dc.creatorGalvao, AC
dc.creatorFrancesconi, AZ
dc.date2008
dc.date42064
dc.date2014-11-16T05:34:05Z
dc.date2015-11-26T17:23:33Z
dc.date2014-11-16T05:34:05Z
dc.date2015-11-26T17:23:33Z
dc.date.accessioned2018-03-29T00:10:52Z
dc.date.available2018-03-29T00:10:52Z
dc.identifierJournal Of Molecular Liquids. Elsevier Science Bv, v. 139, n. 41699, n. 110, n. 116, 2008.
dc.identifier0167-7322
dc.identifierWOS:000254322000016
dc.identifier10.1016/j.molliq.2007.11.009
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/54788
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/54788
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/54788
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1283856
dc.descriptionExcess molar enthalpy of acetonitrile + 1-pentanol and acelonitrile + 1-hexanol as a function of composition at 288.15, 293.15, 298.15 and 303.15 K under atmospheric pressure were used to test the applicability of the Prigogine-Flory-Patterson (PFP) model. The model, with only one adjustable parameter, shows to be able to correlate the experimental data of the investigated mixtures within a standard deviation up to 163 Jmol(-1). The interactional contribution of the model plays the main role to describe the excess molar enthalpy and its ability of multiproperty description is not observed for the studied systems. (c) 2007 Elsevier B.V. All rights reserved.
dc.description139
dc.description41699
dc.description110
dc.description116
dc.languageen
dc.publisherElsevier Science Bv
dc.publisherAmsterdam
dc.publisherHolanda
dc.relationJournal Of Molecular Liquids
dc.relationJ. Mol. Liq.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectexcess molar enthalpy
dc.subjectPFP model
dc.subjectacetonitrile
dc.subjectalkanol
dc.subjectNormal Paraffin Hydrocarbons
dc.subjectChain Molecule Liquids
dc.subjectStatistical Thermodynamics
dc.subjectT=298.15 K
dc.subjectIsentropic Compressibilities
dc.subjectAtmospheric-pressure
dc.subjectN-alkanes
dc.subjectVolumes
dc.subjectPlus
dc.subjectViscosity
dc.titleApplication of the Prigogine-Flory-Patterson model to excess molar enthalpy of binary liquid mixtures containing acetonitrile and 1-alkanol
dc.typeArtículos de revistas


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