dc.creatorSilva, GG
dc.creatorLemes, NHT
dc.creatordaFonseca, CNP
dc.creatorDePaoli, MA
dc.date1996
dc.dateDEC
dc.date2014-12-16T11:35:50Z
dc.date2015-11-26T17:14:03Z
dc.date2014-12-16T11:35:50Z
dc.date2015-11-26T17:14:03Z
dc.date.accessioned2018-03-29T00:02:23Z
dc.date.available2018-03-29T00:02:23Z
dc.identifierSolid State Ionics. Elsevier Science Bv, v. 93, n. 41671, n. 105, n. 116, 1996.
dc.identifier0167-2738
dc.identifierWOS:A1996WK52200008
dc.identifier10.1016/S0167-2738(96)00493-6
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/71794
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/71794
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/71794
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1281720
dc.descriptionElastomers constituted of the homopolymer of epichlorohydrin, its copolymer with ethylene oxide and its terpolymer with ethylene oxide and allyl-glycidyl-ether were studied as polymeric electrolytes in polymer/LiClO4 systems. The variation of the ionic conductivity with salt concentration indicated that the copolymer and the terpolymer show the highest conductivities, ca. 10(-5) S cm(-1) at 30 degrees C. Also, the fitting of the ionic conductivity versus inverse of temperature curves with the VTF equation indicated a conductivity mechanism similar to poly(ethylene oxide) for the copolymer and the terpolymer. The potential stability window determined by cyclic voltammetry is 3.5 V and the polymers are stable to heating up to 250 degrees C. These results confirm the feasibility of using the copolymer and the terpolymer systems with LiClO4 as polymeric solid state electrolytes.
dc.description93
dc.description41671
dc.description105
dc.description116
dc.languageen
dc.publisherElsevier Science Bv
dc.publisherAmsterdam
dc.publisherHolanda
dc.relationSolid State Ionics
dc.relationSolid State Ion.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectsolid state electrolytes
dc.subjectpolymeric electrolytes
dc.subjectplasticizers
dc.subjectthermal behaviour
dc.subjectionic conductivity
dc.subjectPoly(ethylene
dc.subjectConductivity
dc.subjectBattery
dc.titleSolid state polymeric electrolytes based on poly(epichlorohydrin)
dc.typeArtículos de revistas


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