Volumetric properties of binary mixtures of acetonitrile and chloroalkanes at 25 degrees C and atmospheric pressure

dc.creatorTorres, RB
dc.creatorFrancesconi, AZ
dc.creatorVolpe, PLO
dc.date2003
dc.dateMAY
dc.date2014-11-14T00:53:49Z
dc.date2015-11-26T17:12:20Z
dc.date2014-11-14T00:53:49Z
dc.date2015-11-26T17:12:20Z
dc.date.accessioned2018-03-29T00:00:44Z
dc.date.available2018-03-29T00:00:44Z
dc.identifierJournal Of Solution Chemistry. Kluwer Academic/plenum Publ, v. 32, n. 5, n. 417, n. 434, 2003.
dc.identifier0095-9782
dc.identifierWOS:000183907300004
dc.identifier10.1023/A:1024520827859
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/76235
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/76235
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/76235
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1281302
dc.descriptionExcess molar volumes V-m(E) for binary mixtures of acetonitrile + dichloromethane, acetonitrile + trichloromethane, and acetonitrile + tetracloromethane at 25degreesC have been used to calculate partial molar volumes (V) over bar (i), excess artial molar volumes (V)over bar>(E)(i), and apparent molar volumes V-phii of each component as a function of composition. The V-m(E) values are negative over the entire composition range for the systems studied. The applicability of the Prigogine-Flory-Patterson theory was explored. The agreement between theoretical and experimental results is satisfactory for the systems with dichloromethane and tetrachloromethane. For the unsymmetrical behavior of the system with trichloromethane, however, the agreement is poor.
dc.description32
dc.description5
dc.description417
dc.description434
dc.languageen
dc.publisherKluwer Academic/plenum Publ
dc.publisherNew York
dc.publisherEUA
dc.relationJournal Of Solution Chemistry
dc.relationJ. Solut. Chem.
dc.rightsfechado
dc.sourceWeb of Science
dc.subjectvolumetric properties
dc.subjectPrigogine-Flory-Patterson theory
dc.subjectacetonitrile
dc.subjectchloroalkanes
dc.subjectMolar Excess Volumes
dc.subjectStatistical Thermodynamics
dc.subjectDifferent Temperatures
dc.subjectHeat-capacities
dc.subjectLiquid Mixtures
dc.subject298.15 K
dc.subjectSystems
dc.subjectEnthalpies
dc.titleVolumetric properties of binary mixtures of acetonitrile and chloroalkanes at 25 degrees C and atmospheric pressure
dc.typeArtículos de revistas


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