dc.creatorKLEIMAN, GG
dc.creatorLANDERS, R
dc.creatorDECASTRO, SGC
dc.creatorROGERS, JD
dc.date1991
dc.dateOCT 15
dc.date2014-12-16T11:34:41Z
dc.date2015-11-26T17:05:12Z
dc.date2014-12-16T11:34:41Z
dc.date2015-11-26T17:05:12Z
dc.date.accessioned2018-03-28T23:53:32Z
dc.date.available2018-03-28T23:53:32Z
dc.identifierPhysical Review B. American Physical Soc, v. 44, n. 16, n. 8529, n. 8535, 1991.
dc.identifier1098-0121
dc.identifierWOS:A1991GN30400013
dc.identifier10.1103/PhysRevB.44.8529
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/70811
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/70811
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/70811
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1279523
dc.descriptionWe report the results of measurements, by x-ray excited Auger spectroscopy, of the shifts of the Cu L2,3M4,5M4,5 energy spectrum in the alloy CuxPd1-x for various concentrations. Comparison with self-consistent coherent-potential-approximation calculations of E(F)CU-E(F)(x), the negative of the alloy Fermi energy relative to that of Cu, manifests a remarkable agreement in magnitude and concentration dependence. By resorting to a simple version of the quasiatomic model of excited-state electron screening, we demonstrate the physical origin of the various contributions to the Auger shift and show under what conditions the noble-metal Auger shift can be identified with the negative of the relative Fermi energy. Experimental evidence indicates that the charge transfer is very small (of the order of hundredths of electrons per atom) in a number of alloys containing noble metals. The nonlinear systematics exhibited by the data emphasizes the importance of considering a large number of alloys.
dc.description44
dc.description16
dc.description8529
dc.description8535
dc.languageen
dc.publisherAmerican Physical Soc
dc.publisherCollege Pk
dc.publisherEUA
dc.relationPhysical Review B
dc.relationPhys. Rev. B
dc.rightsaberto
dc.sourceWeb of Science
dc.subjectElectronic-structure Calculations
dc.subjectAuger Relaxation Energies
dc.subjectTransition-metal Alloys
dc.subjectOrbital Method
dc.subjectGold Alloys
dc.subjectPd Alloys
dc.subjectShifts
dc.subjectCu
dc.subjectSpectra
dc.subjectDensity
dc.titleRELATIVE FERMI ENERGIES IN COPPER-PALLADIUM ALLOYS
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución