High pressure solid-liquid equilibria of fatty acids

dc.creatorCosta, MC
dc.creatorKrahenbuhl, MA
dc.creatorMeirelles, AJA
dc.creatorDaridon, JL
dc.creatorPauly, J
dc.creatorCoutinho, JAP
dc.date2007
dc.dateMAY 1
dc.date2014-11-19T06:48:13Z
dc.date2015-11-26T17:03:25Z
dc.date2014-11-19T06:48:13Z
dc.date2015-11-26T17:03:25Z
dc.date.accessioned2018-03-28T23:51:32Z
dc.date.available2018-03-28T23:51:32Z
dc.identifierFluid Phase Equilibria. Elsevier Science Bv, v. 253, n. 2, n. 118, n. 123, 2007.
dc.identifier0378-3812
dc.identifierWOS:000245963500005
dc.identifier10.1016/j.fluid.2007.02.007
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/68356
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/68356
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/68356
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1279065
dc.descriptionThe solid-liquid phase diagrams of two binary mixtures of saturated fatty acids, formed by caprylic acid (C(8:0)) + myristic acid (C(14:0)) and lauric acid (C(12:0)) + myristic acid (C(14:0)), were measured using high pressure microscopy in the range of 0. 1-90 MPa. It is shown that unlike for other long chain alkyl compounds such as alkanes the phase diagrams are only slightly affected by the pressure, even in very large pressure ranges such as studied in this work. The modeling of the measured phase diagrams was attempted using an approach previously developed by the authors for n-alkane mixtures. It is here shown that this model can provide an accurate description of the high pressure solid-liquid equilibrium of fatty acid mixtures. (C) 2007 Elsevier B.V. All rights reserved.
dc.description253
dc.description2
dc.description118
dc.description123
dc.languageen
dc.publisherElsevier Science Bv
dc.publisherAmsterdam
dc.publisherHolanda
dc.relationFluid Phase Equilibria
dc.relationFluid Phase Equilib.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectsolid-liquid equilibrium
dc.subjecthigh pressure
dc.subjectphase diagrams
dc.subjectcaprylic acid
dc.subjectlauric acid
dc.subjectmyristic acid
dc.subjectmodeling
dc.subjectLocal Composition Models
dc.subjectWax Formation
dc.subjectPredictive Uniquac
dc.subjectPhase-equilibria
dc.subjectBinary-systems
dc.subjectLight Gases
dc.subjectLauric-acid
dc.subjectLcvm Model
dc.subjectOleic-acid
dc.subjectMixtures
dc.titleHigh pressure solid-liquid equilibria of fatty acids
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución