dc.creatorKAISER, CR
dc.creatorRITTNER, R
dc.creatorBASSO, EA
dc.date1994
dc.dateSEP
dc.date2014-12-16T11:34:09Z
dc.date2015-11-26T17:03:13Z
dc.date2014-12-16T11:34:09Z
dc.date2015-11-26T17:03:13Z
dc.date.accessioned2018-03-28T23:51:19Z
dc.date.available2018-03-28T23:51:19Z
dc.identifierMagnetic Resonance In Chemistry. John Wiley & Sons Ltd, v. 32, n. 9, n. 503, n. 508, 1994.
dc.identifier0749-1581
dc.identifierWOS:A1994PJ96200001
dc.identifier10.1002/mrc.1260320902
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/58363
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/58363
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/58363
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1279029
dc.descriptionComplete signal assignments of high-field H-1 NMR spectra for 3-halosubstituted camphors (endo and exo) are presented, allowing a refinement of a previous analysis for the chloro (endo and exo) and bromo (endo) derivatives. in addition, still unpublished data for the dichloro and exo-fluoro derivatives and for three new compounds (endo-fluoro, endo- and exo-iodo), in addition to a revised assignment of the camphor parent molecule, are reported. The precise substituent-induced chemical shifts (SCS) obtained for these difunctional systems are examined on the basis of well known transmission mechanisms aided by correlations with steric and electronic parameters, and taking into account SCS data from monohaloalkanes and the calculated molecular geometry data (using the AM1 method).
dc.description32
dc.description9
dc.description503
dc.description508
dc.languageen
dc.publisherJohn Wiley & Sons Ltd
dc.publisherW Sussex
dc.publisherInglaterra
dc.relationMagnetic Resonance In Chemistry
dc.relationMagn. Reson. Chem.
dc.rightsfechado
dc.rightshttp://olabout.wiley.com/WileyCDA/Section/id-406071.html
dc.sourceWeb of Science
dc.subjectH-1 NMR
dc.subject3-HALOCAMPHORS
dc.subjectCOSY-45
dc.subjectMOLECULAR GEOMETRIES
dc.subjectSUBSTITUENT-INDUCED CHEMICAL SHIFTS
dc.subjectNmr
dc.subjectSpectroscopy
dc.subjectConstants
dc.subjectScs
dc.subjectC=o
dc.titlePROTON-RESONANCE SPECTRA AND SUBSTITUENT-INDUCED CHEMICAL-SHIFTS OF 3-HALOCAMPHORS
dc.typeArtículos de revistas


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