| dc.creator | Dunstan, PO | |
| dc.date | 2000 | |
| dc.date | AUG 7 | |
| dc.date | 2014-12-02T16:29:35Z | |
| dc.date | 2015-11-26T16:59:35Z | |
| dc.date | 2014-12-02T16:29:35Z | |
| dc.date | 2015-11-26T16:59:35Z | |
| dc.date.accessioned | 2018-03-28T23:47:15Z | |
| dc.date.available | 2018-03-28T23:47:15Z | |
| dc.identifier | Thermochimica Acta. Elsevier Science Bv, v. 356, n. 41671, n. 19, n. 25, 2000. | |
| dc.identifier | 0040-6031 | |
| dc.identifier | WOS:000087942800003 | |
| dc.identifier | 10.1016/S0040-6031(00)00496-2 | |
| dc.identifier | http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/58085 | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/58085 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/58085 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1278229 | |
| dc.description | The compounds [M(pd)(2)(L)] (where M is manganese(II) or copper(II); pd is pentane-2,4-dionate; and L is piperazine (pipz), 4-cyanopyridine (4-cyanopy), quinoline (quin) or 2,2'-bipyridine (bipy)) were synthesized and characterized by elemental analysis, melting points, thermal studies and electronic and IR spectroscopy. The enthalpies of dissolution of adducts, metal pentane-2,4-dionate and ligands in a 1:3 (v/v) mixture of aqueous HCl 1.2 M and methanol were measured and by using thermochemical cycles the following thermochemical parameters for the adducts have been determined: the standard enthalpies for the Lewis acid/base reaction (Delta(r)H(theta)), the standard enthalpies of formation (Delta(f)H(theta)), the standard enthalpies of decomposition (Delta(D)H(theta)), the lattice standard enthalpies (Delta(M)H(theta)) and the standard enthalpies of the Lewis acid/base reaction in the gaseous phase (Delta(r)H(theta)(g)). The mean standard bond dissociation enthalpies of the manganese-nitrogen and copper-nitrogen bonds have been determined. (C) 2000 Elsevier Science B.V. All rights reserved. | |
| dc.description | 356 | |
| dc.description | 41671 | |
| dc.description | 19 | |
| dc.description | 25 | |
| dc.language | en | |
| dc.publisher | Elsevier Science Bv | |
| dc.publisher | Amsterdam | |
| dc.publisher | Holanda | |
| dc.relation | Thermochimica Acta | |
| dc.relation | Thermochim. Acta | |
| dc.rights | fechado | |
| dc.rights | http://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy | |
| dc.source | Web of Science | |
| dc.subject | Mn-N and Cu-N bonds | |
| dc.subject | manganese(II) and copper(II) pentane-2,4-dionate | |
| dc.subject | Mn(IT) and Cu(II) adducts | |
| dc.subject | thermochemical parameters | |
| dc.subject | thermochemistry | |
| dc.subject | Acetylacetonate Chelate | |
| dc.subject | Arsenic Trihalides | |
| dc.subject | Bases | |
| dc.subject | Complexes | |
| dc.title | Thermochemistry of adducts of manganese(II) and copper(II) pentane-2,4-dionate with heterocyclic amines | |
| dc.type | Artículos de revistas | |
