A simple method for mild oxidation of alpha-hydroxysilanes to provide aroylsilanes

dc.creatorPatrocinio, AF
dc.creatorMoran, PJS
dc.date2001
dc.date2014-12-02T16:26:40Z
dc.date2015-11-26T16:54:47Z
dc.date2014-12-02T16:26:40Z
dc.date2015-11-26T16:54:47Z
dc.date.accessioned2018-03-28T23:42:05Z
dc.date.available2018-03-28T23:42:05Z
dc.identifierSynthetic Communications. Marcel Dekker Inc, v. 31, n. 16, n. 2457, n. 2461, 2001.
dc.identifier0039-7911
dc.identifierWOS:000170711400011
dc.identifier10.1081/SCC-100105124
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/53772
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/53772
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/53772
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1276950
dc.descriptionPotassium permanganate supported onto alumina in hexane-water is a good oxidizing agent to convert alpha -hydroxysilanes into acylsilanes. This mild oxidation afforded aroylsilanes having electron-donating groups attached to the aromatic ring, in 70-86% yield.
dc.description31
dc.description16
dc.description2457
dc.description2461
dc.languageen
dc.publisherMarcel Dekker Inc
dc.publisherNew York
dc.publisherEUA
dc.relationSynthetic Communications
dc.relationSynth. Commun.
dc.rightsfechado
dc.sourceWeb of Science
dc.subjectAcyl Silanes
dc.subjectAlpha,beta-unsaturated Acylsilanes
dc.subjectIntramolecular Cyclizations
dc.subjectEnantioselective Synthesis
dc.subjectRadical Cyclizations
dc.subjectBrook Rearrangement
dc.subjectDirect Conversion
dc.subjectAldehydes
dc.subjectPermanganate
dc.subjectCarbon
dc.titleA simple method for mild oxidation of alpha-hydroxysilanes to provide aroylsilanes
dc.typeArtículos de revistas


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