Artículos de revistas
Water sorption thermodynamic properties applied to persimmon skin and pulp
Registro en:
Thermochimica Acta. Elsevier Science Bv, v. 343, n. 41671, n. 49, n. 56, 2000.
0040-6031
WOS:000084693100008
10.1016/S0040-6031(99)00379-2
Autor
Telis, VRN
Gabas, AL
Menegalli, FC
Telis-Romero, J
Institución
Resumen
Moisture equilibrium data of persimmon skin and pulp were determined using the static gravimetric method. Adsorption and desorption isotherms were obtained in the range of 20-70 degrees C, to water activities (a(w)) from 0.02 to 0.85. The application of the GAB model to the experimental results, using direct nonlinear regression analysis, provided a good agreement between experimental and calculated values. The net isosteric heat of sorption was estimated from equilibrium sorption data, using the Clausius-Clapeyron equation. Isosteric heats of sorption were found to increase with increasing temperature and could be well adjusted by an exponential relationship. The enthalpy-entropy compensation theory was applied to sorption isotherms and plots of Delta H versus Delta S for skin and pulp provided the isokinetic temperatures, indicating an enthalpy controlled sorption process. (C) 2000 Elsevier Science B.V. All rights reserved. 343 41671 49 56