Diastereoselective Approach to Substituted Oxazolidinones from Morita-Baylis-Hillman Adducts

dc.creatorRezende, P
dc.creatorPaioti, PHS
dc.creatorCoelho, F
dc.date2011
dc.date2014-07-30T14:42:21Z
dc.date2015-11-26T16:44:02Z
dc.date2014-07-30T14:42:21Z
dc.date2015-11-26T16:44:02Z
dc.date.accessioned2018-03-28T23:29:15Z
dc.date.available2018-03-28T23:29:15Z
dc.identifierSynthetic Communications. Taylor & Francis Inc, v. 41, n. 2, n. 227, n. 242, 2011.
dc.identifier0039-7911
dc.identifierWOS:000285387600009
dc.identifier10.1080/00397910903534023
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/61692
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/61692
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1273785
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionWe disclose herein a new strategy for the diastereoselective preparation of 4- and 4,5-substituted oxazolidinones from Morita-Baylis-Hillman adducts. The strategy is based on an intramolecular cyclization involving a nucleophilic attack of an alkoxide ion to the carbonyl group of a carbamate. The latter is prepared from a Curtius rearrangement having Morita-Baylis-Hillman adduct as substrate. The oxazolidinones were prepared in six steps with an overall yield of 18% and 49%.
dc.description41
dc.description2
dc.description227
dc.description242
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.languageen
dc.publisherTaylor & Francis Inc
dc.publisherPhiladelphia
dc.publisherEUA
dc.relationSynthetic Communications
dc.relationSynth. Commun.
dc.rightsfechado
dc.rightshttp://journalauthors.tandf.co.uk/permissions/reusingOwnWork.asp
dc.sourceWeb of Science
dc.subjectCurtius rearrangement
dc.subjectheterocycles
dc.subjectMorita-Baylis-Hillman
dc.subjectoxazolidinones
dc.subjectElectrospray-ionization Mass
dc.subjectDiels-alder Reactions
dc.subjectAsymmetric-synthesis
dc.subjectChiral Auxiliary
dc.subjectStereoselective-synthesis
dc.subjectEnantioselective Synthesis
dc.subjectOxidative Carbonylation
dc.subjectAlternative Approach
dc.subjectCarbon-dioxide
dc.subjectMechanism
dc.titleDiastereoselective Approach to Substituted Oxazolidinones from Morita-Baylis-Hillman Adducts
dc.typeArtículos de revistas


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