Determination of API gravity, kinematic viscosity and water content in petroleum by ATR-FTIR spectroscopy and multivariate calibration

dc.creatorFilgueiras, PR
dc.creatorSad, CMS
dc.creatorLoureiro, AR
dc.creatorSantos, MFP
dc.creatorCastro, EVR
dc.creatorDias, JCM
dc.creatorPoppi, RJ
dc.date2014
dc.dateJAN
dc.date2014-07-30T14:39:00Z
dc.date2015-11-26T16:42:44Z
dc.date2014-07-30T14:39:00Z
dc.date2015-11-26T16:42:44Z
dc.date.accessioned2018-03-28T23:27:25Z
dc.date.available2018-03-28T23:27:25Z
dc.identifierFuel. Elsevier Sci Ltd, v. 116, n. 123, n. 130, 2014.
dc.identifier0016-2361
dc.identifier1873-7153
dc.identifierWOS:000326943400018
dc.identifier10.1016/j.fuel.2013.07.122
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/61350
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/61350
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1273360
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionIn this work, API gravity, kinematic viscosity and water content were determined in petroleum oil using Fourier transform infrared spectroscopy with attenuated total reflectance (FT-IR/ATR). Support vector regression (SVR) was used as the non-linear multivariate calibration procedure and partial least squares regression (PLS) as the linear procedure. In SVR models, the multiplication of the spectra matrix by support vectors resulted in information about the importance of the original variables. The most important variables in PLS models were attained by regression coefficients. For API gravity and kinematic viscosity these variables correspond to vibrations around 2900 cm(-1), 1450 cm(-1) and below to 720 cm(-1) and for water content, between 3200 and 3650 cm(-1), around 1650 cm(-1) and below to 900 cm(-1). The SVR model produced a root mean square error of prediction (RMSEP) of 0.25 for API gravity, 22 mm(2) s(-1) for kinematic viscosity and 0.26% v/v for water content. For PLS models, the RMSEP values for API gravity was 0.38 mm(2) s(-1), for kinematic viscosity was 27 mm(2) s(-1) and for water content was 0.34%. Using the F-test at 95% of confidence it was concluded that the SVR model produced better results than PLS for API gravity determination. For kinematic viscosity and water content the two methods were equivalent. However, a non-linear behavior in the PLS kinematic viscosity model was observed. (C) 2013 Elsevier Ltd. All rights reserved.
dc.description116
dc.description123
dc.description130
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.languageen
dc.publisherElsevier Sci Ltd
dc.publisherOxford
dc.publisherInglaterra
dc.relationFuel
dc.relationFuel
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectCrude oil
dc.subjectATR-FTIR
dc.subjectPartial least squares regression
dc.subjectSupport vector regression
dc.subjectNear-infrared Spectroscopy
dc.subjectSupport Vector Regression
dc.subjectQuality Parameters
dc.subjectRaman-spectroscopy
dc.subjectModels
dc.subjectPls
dc.subjectMachines
dc.subjectNetworks
dc.subjectFigures
dc.subjectSystems
dc.titleDetermination of API gravity, kinematic viscosity and water content in petroleum by ATR-FTIR spectroscopy and multivariate calibration
dc.typeArtículos de revistas


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