dc.creatorDias, JC
dc.creatorKubota, LT
dc.creatorNesterenko, PN
dc.creatorHaddad, PR
dc.date2012
dc.dateAUG
dc.date2014-07-30T16:52:13Z
dc.date2015-11-26T16:39:58Z
dc.date2014-07-30T16:52:13Z
dc.date2015-11-26T16:39:58Z
dc.date.accessioned2018-03-28T23:23:43Z
dc.date.available2018-03-28T23:23:43Z
dc.identifierChromatographia. Springer Heidelberg, v. 75, n. 15-16, n. 867, n. 873, 2012.
dc.identifier0009-5893
dc.identifierWOS:000307248900005
dc.identifier10.1007/s10337-012-2265-x
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/62958
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/62958
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1272618
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionThe chelidamic acid (CDA) is proposed as a new eluent reagent in high performance chelation ion chromatography for the simultaneous isocratic separation of Fe2+ and Fe3+, Mn2+, Pb2+, Cd2+, Zn2+, Co2+ and Cu2+ on an iminodiacetic acid functionalized silica column 150 x 4.0 mm i.d., with an optimized eluent composed of 2 mmol L-1 CDA, 3 mmol L-1 triethanolamine, 12 mmol L-1 HCl, and 50 % v/v of methanol at flow rate of 0.5 mL min(-1). Post-column reaction with 4-(2-Pyridylazo)resorcinol (PAR) was used for sensitive spectrophotometric detection at 510 nm. The developed method is suitable for the quantitative speciation of iron as well as for the determination of other metals. The applicability of this method to the direct analysis of fuel ethanol was demonstrated.
dc.description75
dc.description15-16
dc.description867
dc.description873
dc.descriptionIRGS grant of the University of Tasmania
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionFAPESP [2010/05015-8]
dc.descriptionCNPq [573672/2008-3]
dc.languageen
dc.publisherSpringer Heidelberg
dc.publisherHeidelberg
dc.publisherAlemanha
dc.relationChromatographia
dc.relationChromatographia
dc.rightsfechado
dc.rightshttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dc.sourceWeb of Science
dc.subjectHigh performance chelation ion chromatography
dc.subjectChelidamic acid
dc.subjectTransition metals
dc.subjectIron speciation
dc.subjectFuel ethanol
dc.subjectOn-column Complexation
dc.subject4-chlorodipicolinic Acid
dc.subjectTrace-metals
dc.subjectIron
dc.subjectIron(iii)
dc.subjectTransition
dc.subjectSeparation
dc.subjectPhase
dc.subjectSpeciation
dc.subjectSamples
dc.titleChelidamic Acid as a New Eluent for the Determination of Fe(II) and Fe(III) Species and Other Metals by High Performance Chelation Ion Chromatography
dc.typeArtículos de revistas


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