| dc.creator | Dias, LC | |
| dc.creator | Meira, PRR | |
| dc.date | 2000 | |
| dc.date | JAN | |
| dc.date | 2014-12-02T16:29:04Z | |
| dc.date | 2015-11-26T16:38:35Z | |
| dc.date | 2014-12-02T16:29:04Z | |
| dc.date | 2015-11-26T16:38:35Z | |
| dc.date.accessioned | 2018-03-28T23:21:58Z | |
| dc.date.available | 2018-03-28T23:21:58Z | |
| dc.identifier | Synlett. Georg Thieme Verlag, n. 1, n. 37, n. 40, 2000. | |
| dc.identifier | 0936-5214 | |
| dc.identifier | WOS:000086556300007 | |
| dc.identifier | http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/63102 | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/63102 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/63102 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1272287 | |
| dc.description | Addition of chiral allylsilane 4 to chiral N-Boc-alpha-amino aldehydes in the presence of SnCl4 in CH2Cl2 at -78 degrees C affords 1,2-syn homoallylic alcohols, potential intermediates for the synthesis of hydroxyethylene peptide isosteres. The diastereoselectivity depends on the aldehyde absolute configuration, with (R)-alpha-aminoaldehydes (matched case/anti-Felkin addition) exhibiting higher stereoselectivity than its enantiomer (mismatched case/Felkin addition). | |
| dc.description | o TEXTO COMPLETO DESTE ARTIGO, ESTARÁ DISPONÍVEL À PARTIR DE AGOSTO DE 2015. | |
| dc.description | 1 | |
| dc.description | 37 | |
| dc.description | 40 | |
| dc.language | en | |
| dc.publisher | Georg Thieme Verlag | |
| dc.publisher | Stuttgart | |
| dc.publisher | Alemanha | |
| dc.relation | Synlett | |
| dc.relation | Synlett | |
| dc.rights | embargo | |
| dc.source | Web of Science | |
| dc.subject | chiral allylsilane | |
| dc.subject | alpha-amino aldehydes | |
| dc.subject | dipeptide isosteres | |
| dc.subject | homoallylic alcohols | |
| dc.subject | oxazolidines | |
| dc.subject | Hydroxyethylene Dipeptide Isosteres | |
| dc.subject | Hiv-1 Protease Inhibitors | |
| dc.subject | Substituted Aldehydes | |
| dc.subject | Asymmetric-synthesis | |
| dc.subject | Organic-synthesis | |
| dc.subject | Acid | |
| dc.subject | Aminoaldehydes | |
| dc.subject | Convenient | |
| dc.subject | Versatile | |
| dc.title | Chiral allylsilane additions to chiral N-Boc-alpha-amino aldehydes | |
| dc.type | Artículos de revistas | |
