The asymmetric synthesis of (+)-sitophilure, the natural form of the aggregation pheromone of Sitophilus oryzae L-and Sitophilus zeamais M.

dc.creatorPilli, RA
dc.creatorRiatto, VB
dc.date1999
dc.dateSEP-OCT
dc.date2014-12-02T16:28:07Z
dc.date2015-11-26T16:35:56Z
dc.date2014-12-02T16:28:07Z
dc.date2015-11-26T16:35:56Z
dc.date.accessioned2018-03-28T23:18:34Z
dc.date.available2018-03-28T23:18:34Z
dc.identifierJournal Of The Brazilian Chemical Society. Soc Brasileira Quimica, v. 10, n. 5, n. 363, n. 368, 1999.
dc.identifier0103-5053
dc.identifierWOS:000084012100005
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/78376
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/78376
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/78376
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1271675
dc.descriptionThe asymmetric synthesis of (+)-sitophilure, the aggregation pheromone of Sitophilus oryzae L,. and Sitophilus zeamais M., was carried out in 12 steps, 18% overall yield and 82% enantiomeric excess from the enzymatic reduction of methyl 3-oxopentanoate with S. cerevisiae in the presence of ethyl chloroacetate.
dc.description10
dc.description5
dc.description363
dc.description368
dc.languageen
dc.publisherSoc Brasileira Quimica
dc.publisherSao Paulo
dc.publisherBrasil
dc.relationJournal Of The Brazilian Chemical Society
dc.relationJ. Braz. Chem. Soc.
dc.rightsaberto
dc.sourceWeb of Science
dc.subject(+)-sitophilure
dc.subjectpheromone
dc.subjectasymmetric reduction
dc.subjectS-cerevisiae
dc.subjectStereochemical Control
dc.subjectMicrobial Reduction
dc.subjectAldol Reactions
dc.subjectBakers-yeast
dc.subjectMaize Weevil
dc.subjectRice Weevil
dc.subject5-hydroxy-4-methyl-3-heptanone
dc.subjectEsters
dc.titleThe asymmetric synthesis of (+)-sitophilure, the natural form of the aggregation pheromone of Sitophilus oryzae L-and Sitophilus zeamais M.
dc.typeArtículos de revistas


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