Microbial monooxygenases applied to fragrance compounds

dc.creatorPinheiro, L
dc.creatorMarsaioli, AJ
dc.date2007
dc.dateFEB 1
dc.date2014-11-17T02:32:49Z
dc.date2015-11-26T16:35:48Z
dc.date2014-11-17T02:32:49Z
dc.date2015-11-26T16:35:48Z
dc.date.accessioned2018-03-28T23:18:22Z
dc.date.available2018-03-28T23:18:22Z
dc.identifierJournal Of Molecular Catalysis B-enzymatic. Elsevier Science Bv, v. 44, n. 2, n. 78, n. 86, 2007.
dc.identifier1381-1177
dc.identifierWOS:000243749800007
dc.identifier10.1016/j.molcatb.2006.08.007
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/56677
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/56677
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/56677
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1271626
dc.descriptionBiotransformation is an important tool in organic syntheses, especially for the production of chiral molecules and whenever chemical reactions are inefficient. Fragrance compounds were biotransformed by Trichosporum cutaneum CCT 1903 whole cells. Batch reactions with cis-jasmone (1), (R)-(-)-carvone (3), alpha- and beta-ionones (4, 5) and (R)-(+)-limonene (10) produced 4-hydroxyjasmone (1a), 7,8-epoxyjasmone (1b), 7,8-dihydroxyjasmone (1c), (1S,2R,4R)-neoisodihydrocarveol (3a), (6R)-isoprenyl-(3R)-methyl-2-oxo-oxepanone (3b), (3R)-isopropenyl-6-oxoheptanoic acid (3c), 2,3-epoxy-(5R)-isopropenyl-2-methylcyclohexenoI (3d), alpha-homo-cycloaeraniol (4a), 4-oxo-7,8-dihydro-beta-ionone (5a), uroterpenol (10a) and (R)-(+)-limonene-1,2-diol (10b) as pure samples for spectroscopic identification (H-1 and C-13 NMR,H-1,H-1-gCOSY, HSQC, gHMBC). The stereochemical consequences of the transformations are also discussed. (c) 2006 Elsevier B.V. All rights reserved.
dc.description44
dc.description2
dc.description78
dc.description86
dc.languageen
dc.publisherElsevier Science Bv
dc.publisherAmsterdam
dc.publisherHolanda
dc.relationJournal Of Molecular Catalysis B-enzymatic
dc.relationJ. Mol. Catal. B-Enzym.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectbiotransformation
dc.subjectmonoterpenes
dc.subjectBaeyer-Villiger monooxygenase
dc.subjectepoxidation
dc.subjecthydroxylation
dc.subjectBaeyer-villiger Monooxygenase
dc.subjectMicrobiological Transformations
dc.subjectBeta-ionone
dc.subjectBiotransformation
dc.subjectMicroorganisms
dc.subjectImplementation
dc.subjectDihydrocarvone
dc.subjectOxidations
dc.subjectAssignment
dc.subjectCulture
dc.titleMicrobial monooxygenases applied to fragrance compounds
dc.typeArtículos de revistas


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