Measurement and correlation of the excess molar enthalpy of (1-nonanol, or 1-decanol + acetonitrile) mixtures at (298.15, 303.15, and 308.15) K and atmospheric pressure

dc.creatorViola, DHL
dc.creatorFrancesconi, AZ
dc.date2012
dc.dateAPR
dc.date2014-07-30T13:40:00Z
dc.date2015-11-26T16:29:11Z
dc.date2014-07-30T13:40:00Z
dc.date2015-11-26T16:29:11Z
dc.date.accessioned2018-03-28T23:10:17Z
dc.date.available2018-03-28T23:10:17Z
dc.identifierJournal Of Chemical Thermodynamics. Academic Press Ltd- Elsevier Science Ltd, v. 47, n. 28, n. 32, 2012.
dc.identifier0021-9614
dc.identifierWOS:000299039100006
dc.identifier10.1016/j.jct.2011.09.011
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/53381
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/53381
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1269671
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionExperimental excess molar enthalpies (H-m(E)) of binary liquid mixtures containing (1-nonanol, or 1-decanol + acetonitrile) have been determined as a function of composition at atmospheric pressure and (298.15, 303.15, and 308.15) K using a modified 1455 Parr solution calorimeter. The experimental values are positive for both systems over the whole composition range, and increase with temperature and with alkanol chain length. The Extended Real Associated Solution Model (ERAS-Model) allowing for self-association of the alkanols and complex formation between acetonitrile and alkanols have been used to correlate experimental data. Agreement between theoretical and experimental values is satisfactory. (C) 2011 Elsevier Ltd. All rights reserved.
dc.description47
dc.description28
dc.description32
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.languageen
dc.publisherAcademic Press Ltd- Elsevier Science Ltd
dc.publisherLondon
dc.publisherInglaterra
dc.relationJournal Of Chemical Thermodynamics
dc.relationJ. Chem. Thermodyn.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectExcess molar enthalpy
dc.subjectExperimental
dc.subjectERAS-Model
dc.subjectAlkanols
dc.subjectAcetonitrile
dc.subjectLiquid Vapor Equilibrium
dc.subjectAtmospheric-pressure
dc.subjectEras-model
dc.subjectAcetonitrile System
dc.subject318 K
dc.subjectMixtures
dc.subjectAlkanol
dc.subjectBinary
dc.subjectThermodynamics
dc.subjectTemperatures
dc.titleMeasurement and correlation of the excess molar enthalpy of (1-nonanol, or 1-decanol + acetonitrile) mixtures at (298.15, 303.15, and 308.15) K and atmospheric pressure
dc.typeArtículos de revistas


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