The intercalation of n-alkyldiamines into crystalline layered titanate

dc.creatorAiroldi, C
dc.creatorNunes, LM
dc.creatorde Farias, RF
dc.date2000
dc.dateOCT
dc.date2014-12-02T16:27:09Z
dc.date2015-11-26T16:27:32Z
dc.date2014-12-02T16:27:09Z
dc.date2015-11-26T16:27:32Z
dc.date.accessioned2018-03-28T23:08:29Z
dc.date.available2018-03-28T23:08:29Z
dc.identifierMaterials Research Bulletin. Pergamon-elsevier Science Ltd, v. 35, n. 13, n. 2081, n. 2090, 2000.
dc.identifier0025-5408
dc.identifierWOS:000167658600002
dc.identifier10.1016/S0025-5408(00)00426-8
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/73549
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/73549
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/73549
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1269218
dc.descriptionThe synthesis, characterization, and intercalation of n-alkyldiamines H2N(CH2)(n)NH2 (n = 2, 3, 4, 6, 7, and 8) into layered hydrous tetratitanic acid H2Ti4O9. nH(2)O are reported. From the elemental analysis, the following formula were proposed for the intercalated compounds: (C2H8N2)(0.3)-H2Ti4O9.0.40H(2)O, (C3H10N2)(0.6)H2Ti4O9.0.89H(2)O, (C4H12N2)(0.3)H2Ti4O9.0.40H(2)O, (C6H16N2)(0.6)-H2Ti4O9.0.92H(2)O, (C7H18N2)(0.5)H2Ti4O9.0.50H(2)O and (C8H20N2)(0.6)H2Ti4O9.0.60H(2)O. X-ray diffraction patterns for these matrices showed that the 920 pm interlayer space of the original matrix has the d-spacing values increased to 1118, 1318, 1549, 1662, 1720, and 1766 pm, respectively, for the C-2-C-8 sequence of intercalated n-alkyldiamine. The infrared data are in agreement with the protonated nitrogen atoms of the diamines located in the cavity space. The hydrous matrix showed two mass loss steps in the thermogravimetric curve, corresponding to the release of physisorbed and lattice water molecules. A third mass loss was observed for the intercalated matrices due to the release of organic moiety. From these values, the intercalated matrices represented by the number of carbons in the organic chains can be ordered in the following sequence of thermal stability: C-4 > C-2 > C-3 congruent to C-6 > C-7 congruent to C-8. The lowest amount of intercalated n-alkyldiamines gave the largest thermal stability of the hybrid. (C) 2001 Elsevier Science Ltd. All rights reserved.
dc.description35
dc.description13
dc.description2081
dc.description2090
dc.languageen
dc.publisherPergamon-elsevier Science Ltd
dc.publisherOxford
dc.publisherInglaterra
dc.relationMaterials Research Bulletin
dc.relationMater. Res. Bull.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectlayered compounds
dc.subjectnanostructures
dc.subjectintercalation reactions
dc.subjectthermogravimetric analysis (TGA)
dc.subjectX-ray diffraction
dc.subjectHydrous Titanium-dioxide
dc.subjectIon-exchange
dc.subjectZirconium Titanate
dc.subjectAlkylammonium
dc.subjectHydrogenphosphate
dc.subjectCations
dc.subjectH2ti3o7
dc.subjectHydrate
dc.subjectOxides
dc.subjectForms
dc.titleThe intercalation of n-alkyldiamines into crystalline layered titanate
dc.typeArtículos de revistas


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