A continuum thermodynamical approach to electrochemical systems

dc.creatorReis, MC
dc.creatorWang, YQ
dc.creatorBassi, ABMS
dc.date2014
dc.dateFEB
dc.date2014-07-30T13:39:28Z
dc.date2015-11-26T16:20:46Z
dc.date2014-07-30T13:39:28Z
dc.date2015-11-26T16:20:46Z
dc.date.accessioned2018-03-28T23:03:05Z
dc.date.available2018-03-28T23:03:05Z
dc.identifierJournal Of Mathematical Chemistry. Springer, v. 52, n. 2, n. 441, n. 463, 2014.
dc.identifier0259-9791
dc.identifier1572-8897
dc.identifierWOS:000330969600004
dc.identifier10.1007/s10910-013-0271-3
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/53029
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/53029
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1267862
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionThis work focuses on formulating constitutive models for the bulk and double layer regions of an electrochemical system based on the fundamentals of modern continuum thermodynamics. Particularly, the constitutive models proposed accounting for transport phenomena in electrochemical systems by emphasizing the possibility of cross-coupling between two or more phenomena. Upon deriving a set of thermodynamic restrictions from the Muller-Liu approach of the second law of thermodynamics and axioms of constitutive theory, non-equilibrium quantities are examined in detail, and constitutive answers of the bulk and double layer regions are discussed. Moreover, the conditions for the thermodynamic equilibrium are evaluated for each region as well as the occurrence of dissipative mechanisms. Besides offering a proper formulation for non-equilibrium electrochemical systems, the approach described in this work can be easily extended to more complex chemical systems.
dc.description52
dc.description2
dc.description441
dc.description463
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.descriptionGerman Academic Exchange Service (DAAD)
dc.descriptionConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.languageen
dc.publisherSpringer
dc.publisherNew York
dc.publisherEUA
dc.relationJournal Of Mathematical Chemistry
dc.relationJ. Math. Chem.
dc.rightsfechado
dc.rightshttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dc.sourceWeb of Science
dc.subjectElectrochemical systems
dc.subjectSecond law of thermodynamics
dc.subjectConstitutive equations
dc.subjectNon-equilibrium thermodynamics
dc.subjectIrreversible-processes
dc.subjectReciprocal Relations
dc.subjectSimple Fluid
dc.subjectRepresentations
dc.titleA continuum thermodynamical approach to electrochemical systems
dc.typeArtículos de revistas


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