Application of the ERAS-Model to binary mixtures of diethylamine and s-butylamine with acetonitrile in the temperature range (288.15-303.15) K

dc.creatorTorres, RB
dc.creatorFrancesconi, AZ
dc.date2002
dc.dateAUG 1
dc.date2014-11-16T05:11:20Z
dc.date2015-11-26T16:19:59Z
dc.date2014-11-16T05:11:20Z
dc.date2015-11-26T16:19:59Z
dc.date.accessioned2018-03-28T23:02:40Z
dc.date.available2018-03-28T23:02:40Z
dc.identifierFluid Phase Equilibria. Elsevier Science Bv, v. 200, n. 2, n. 317, n. 328, 2002.
dc.identifier0378-3812
dc.identifierWOS:000176885400009
dc.identifier10.1016/S0378-3812(02)00042-0
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/54779
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/54779
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/54779
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1267761
dc.descriptionDensities for binary mixtures of diethylamine and s-butylamine with acetonitrile have been measured at 288.15, 293.15, 298.15 and 303.15 K using a vibrating-tube densimeter. Excess molar volumes (V-m(E)) were determined. Both systems exhibit negative V-m(E) values over the entire composition range in the temperature range studied. ERAS-Model calculations allowing for self-association for the amines and complex formation between acetonitrile and amines were performed. The agreement between theoretical and experimental results is satisfactory only for mole fractions of amines less than 0.50. A simplified version of the model, without the chemical contribution, gives similar results. (C) 2002 Elsevier Science B.V. All rights reserved.
dc.description200
dc.description2
dc.description317
dc.description328
dc.languageen
dc.publisherElsevier Science Bv
dc.publisherAmsterdam
dc.publisherHolanda
dc.relationFluid Phase Equilibria
dc.relationFluid Phase Equilib.
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectexperiments
dc.subjectexcess volumes
dc.subjectmodeling
dc.subjectamines
dc.subjectacetonitrile
dc.subjectExcess Molar Volumes
dc.subjectLiquid Acetonitrile
dc.subject298.15 K
dc.subjectAlkanol
dc.subjectPlus
dc.subjectThermodynamics
dc.subjectEther
dc.subjectAssociation
dc.titleApplication of the ERAS-Model to binary mixtures of diethylamine and s-butylamine with acetonitrile in the temperature range (288.15-303.15) K
dc.typeArtículos de revistas


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