Total synthesis of (-)-basiliskamide B

dc.creatorDias, LC
dc.creatorGoncalves, CDS
dc.date2008
dc.dateMAY
dc.date2014-11-15T17:27:16Z
dc.date2015-11-26T16:12:48Z
dc.date2014-11-15T17:27:16Z
dc.date2015-11-26T16:12:48Z
dc.date.accessioned2018-03-28T23:00:47Z
dc.date.available2018-03-28T23:00:47Z
dc.identifierAdvanced Synthesis & Catalysis. Wiley-blackwell, v. 350, n. 41858, n. 1017, n. 1021, 2008.
dc.identifier1615-4150
dc.identifierWOS:000255790100015
dc.identifier10.1002/adsc.200700589
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/77754
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/77754
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/77754
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1267295
dc.descriptionThe total synthesis of the polyketide antibiotic (-)-basiliskamide B is described. The convergent asymmetric synthesis relies on the use of a diastereoselective ethyl ketone aldol reaction followed by a syn selective reduction of a beta-hydroxy ketone and a Stille cross-coupling between a Z-vinylstannane and an E-vinyl iodide to establish the (Z,E)dienamide moiety.
dc.description350
dc.description41858
dc.description1017
dc.description1021
dc.languageen
dc.publisherWiley-blackwell
dc.publisherMalden
dc.publisherEUA
dc.relationAdvanced Synthesis & Catalysis
dc.relationAdv. Synth. Catal.
dc.rightsfechado
dc.rightshttp://olabout.wiley.com/WileyCDA/Section/id-406071.html
dc.sourceWeb of Science
dc.subjectaldol reaction
dc.subjectantitumor compounds
dc.subjectStille cross-coupling
dc.subjecttotal synthesis
dc.subjectPi-face Selectivity
dc.subjectAldol Reactions
dc.subjectTetrapropylammonium Perruthenate
dc.subject1,3-diol Acetonides
dc.subjectOrganic-synthesis
dc.subjectStille Reaction
dc.subjectAntifungal
dc.subjectConversion
dc.subjectKetones
dc.subject(+)-discodermolide
dc.titleTotal synthesis of (-)-basiliskamide B
dc.typeArtículos de revistas


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