| dc.creator | DOSSANTOS, LCR | |
| dc.creator | DEOLIVEIRA, SF | |
| dc.creator | ESPINOLA, JGP | |
| dc.creator | AIROLDI, C | |
| dc.date | 1992 | |
| dc.date | SEP 10 | |
| dc.date | 2014-12-16T11:36:05Z | |
| dc.date | 2015-11-26T16:10:48Z | |
| dc.date | 2014-12-16T11:36:05Z | |
| dc.date | 2015-11-26T16:10:48Z | |
| dc.date.accessioned | 2018-03-28T22:59:26Z | |
| dc.date.available | 2018-03-28T22:59:26Z | |
| dc.identifier | Thermochimica Acta. Elsevier Science Bv, v. 206, n. 13, n. 18, 1992. | |
| dc.identifier | 0040-6031 | |
| dc.identifier | WOS:A1992JP23500002 | |
| dc.identifier | 10.1016/0040-6031(92)85279-5 | |
| dc.identifier | http://www.repositorio.unicamp.br/jspui/handle/REPOSIP/58074 | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/58074 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/58074 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1266965 | |
| dc.description | The adducts MI3.tmtu (M = Sb, Bi; tmtu = tetramethylthiourea) were prepared, characterized and studied through reaction-solution calorimetry at 298.15 K. The molar standard enthalpy DELTA(R)H(m)empty set of the reaction MI3(cr)+tmtu(cr)=MI3.tmtu(cr) gave -19.84 +/- 0.46 and -13.01 +/- 0.17 kJ mol-1 for Sb and Bi, respectively. From DELTA(r)H(m)empty set values the standard molar enthalpies of formation of the crystalline Sb and Bi adducts were calculated as -158.5 and -201.3 kJ mol-1, respectively. The mean element-sulphur bond enthalpies were also calculated as 122 and 147 kJ mol-1 for Sb-S and Bi-S bonds, respectively. The acidity order AsI3 > SbI3 > BiI3 was established. | |
| dc.description | 206 | |
| dc.description | 13 | |
| dc.description | 18 | |
| dc.language | en | |
| dc.publisher | Elsevier Science Bv | |
| dc.publisher | Amsterdam | |
| dc.publisher | Holanda | |
| dc.relation | Thermochimica Acta | |
| dc.relation | Thermochim. Acta | |
| dc.rights | fechado | |
| dc.rights | http://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy | |
| dc.source | Web of Science | |
| dc.subject | Di-normal-butyldithiocarbamate | |
| dc.subject | Arsenic Trihalides | |
| dc.subject | Donor Ligands | |
| dc.subject | Complexes | |
| dc.subject | Cadmium | |
| dc.subject | Mercury | |
| dc.subject | Zinc | |
| dc.title | THERMOCHEMICAL STUDY OF ADDUCTS OF TETRAMETHYLTHIOUREA WITH ANTIMONY AND BISMUTH TRIIODIDES | |
| dc.type | Artículos de revistas | |
