dc.creatorRippel, MM
dc.creatorCosta, CAR
dc.creatorGalembeck, F
dc.date2004
dc.dateMAY 11
dc.date2014-11-14T15:18:04Z
dc.date2015-11-26T16:07:17Z
dc.date2014-11-14T15:18:04Z
dc.date2015-11-26T16:07:17Z
dc.date.accessioned2018-03-28T22:55:58Z
dc.date.available2018-03-28T22:55:58Z
dc.identifierPolymer. Elsevier Sci Ltd, v. 45, n. 10, n. 3367, n. 3375, 2004.
dc.identifier0032-3861
dc.identifierWOS:000221135800029
dc.identifier10.1016/j.polymer.2004.03.013
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/63441
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/63441
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/63441
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1266095
dc.descriptionAddition of sodium polyphosphate (NaPP) to natural rubber latex at 0.4 weight ratio improves the adhesion of cast latex dry films to flat glass surfaces. Rubber-polyphosphate dispersions were analyzed by turbidimetric titration, PCS and ultramicroscopy, and the results indicate the formation of two domains within the latex-polyphosphate dispersions: one domain has higher rubber particle content than the other. Thick rubber films were examined by AFM, scanning electric potential and modulated force microscopy. The images show that rubber film morphology is completely altered by NaPP addition. Two types of domains are observed in the dry latex film: one type carries excess positive charges and is harder than the other, negative domains. Both domains are compatible, as shown by the extensive interfaces observed in all images observed. In the latex-glass joints, the positive domains concentrate in the vicinity of the negative glass surface, thus making an electrostatic contribution to glass-latex adhesion. (C) 2004 Elsevier Ltd. All rights reserved.
dc.description45
dc.description10
dc.description3367
dc.description3375
dc.languageen
dc.publisherElsevier Sci Ltd
dc.publisherOxford
dc.publisherInglaterra
dc.relationPolymer
dc.relationPolymer
dc.rightsfechado
dc.rightshttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.sourceWeb of Science
dc.subjectlatex-glass adhesion
dc.subjectcolloidal phase separations
dc.subjectscanning electric potential microscopy
dc.subjectFilms
dc.subjectMicroscopy
dc.subjectAttraction
dc.subjectColloids
dc.titleNatural rubber latex modification by sodium polyphosphate: a SPM study on the improved latex adhesion to glass sheet
dc.typeArtículos de revistas


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