Artículos de revistas
Thermochemistry of Quinoline and Morpholine Adducts of Cadmium(II) Halides
Registro en:
Journal Of Chemical And Engineering Data. Amer Chemical Soc, v. 55, n. 11, n. 4995, n. 4998, 2010.
0021-9568
WOS:000284017600067
10.1021/je100579w
Autor
Dunstan, PO
Institución
Resumen
The adducts [CdX(2)(L)(n)], where X = Cl, Br, or I; L = quinoline (quin) or morpholine (morph); and n = 1, 1.5, or 2, were synthesized and characterized by melting point and elemental analysis, thermal studies, and IR spectroscopy. From calorimetric studies in solution, the standard enthalpies of formation of the adducts and several thermodynamic parameters were determined. The mean standard enthalpies of the cadmium-nitrogen bonds were calculated. 55 11 4995 4998