A new elemental analysis procedure based on an ICPOES technique to determine arsenic, phosphorus and titanium in titanium phenylphosphonate or titanium phenylarsonate

dc.creatorRuiz, VSO
dc.creatorRibeiro, AS
dc.creatorAiroldi, C
dc.date2005
dc.dateJUN
dc.date2014-11-13T20:17:32Z
dc.date2015-11-26T16:02:23Z
dc.date2014-11-13T20:17:32Z
dc.date2015-11-26T16:02:23Z
dc.date.accessioned2018-03-28T22:51:48Z
dc.date.available2018-03-28T22:51:48Z
dc.identifierCurrent Analytical Chemistry. Bentham Science Publ Ltd, v. 1, n. 2, n. 171, n. 175, 2005.
dc.identifier1573-4110
dc.identifierWOS:000235225600006
dc.identifier10.2174/1573411054021510
dc.identifierhttp://www.repositorio.unicamp.br/jspui/handle/REPOSIP/76175
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/76175
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/76175
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1265051
dc.descriptionA new methodology is proposed for arsenic, phosphorus and titanium determination in crystalline lamellar phenylarsonate and phenylphosphonate samples by an ICP OES technique. Nitric acid, hydrofluoric acid and hydrogen peroxide were used to decompose mass aliquots of about 50 mg of titanium phenylphosphonate and phenylarsonate in a closed microwave oven. This method was shown to be suitable, reproducible and simple, and the elemental determinations provided the knowledge of the precise stoichiometry of the synthesized compounds. The concentration values obtained from triplicate gave 0.353 +/- 0.008 and 0.113 +/- 0.003 g g(-1) for arsenic and titanium in titanium phenylarsonate samples with relative standard deviations (RSD) 2.3 and 2.7%, respectively. The titanium phenylphosphonate sample gave phosphorus and metal concentrations of 0.153 +/- 0.017 and 0.119 +/- 0.003 g g(-1) with RSD of 11.1 and 2.5%, respectively. Based on the obtained results, the molar concentrations for the species were calculated as 4.71 and 2.36 mmol g(-1) for the arsenic and titanium elements for phenylarsonate compound, while the values 4.94 and 2.48 mmol g(-1) for phosphorus and metal were determined for titanium phenylphosphonate, respectively. The data obtained for these elements in aqueous insoluble inorganic lamellar materials, enable to establish a 2:1 proportion, whose value conformed to the expected and reliable minimum formula for the synthesized Ti(O3PC6H5)(2) and Ti(O3AsC6H5)(2) compounds.
dc.description1
dc.description2
dc.description171
dc.description175
dc.languageen
dc.publisherBentham Science Publ Ltd
dc.publisherSharjah
dc.publisherEmirados Árabes Unidos
dc.relationCurrent Analytical Chemistry
dc.relationCurr. Anal. Chem.
dc.rightsfechado
dc.sourceWeb of Science
dc.subjectarsenic
dc.subjectphosphorus
dc.subjecttitanium
dc.subjectICPOES
dc.subjectorganophosphonate
dc.subjectOptical-emission-spectrometry
dc.subjectAlpha-zirconium Phosphate
dc.subjectOes
dc.subjectIntercalation
dc.subjectCrystal
dc.subjectCalcium
dc.subjectPhosphonates
dc.subjectChemistry
dc.subjectNonmetals
dc.subjectSulfur
dc.titleA new elemental analysis procedure based on an ICPOES technique to determine arsenic, phosphorus and titanium in titanium phenylphosphonate or titanium phenylarsonate
dc.typeArtículos de revistas


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