Measurements Of Excess Molar Enthalpy And Excess Molar Heat Capacity Of (1-heptanol Or 1-octanol)+(diethylamine Or S-butylamine) Mixtures At 298.15 K And 0.1 Mpa

dc.creatorCheconi R.F.
dc.creatorFrancesconi A.Z.
dc.date2009
dc.date2015-06-26T13:37:38Z
dc.date2015-11-26T15:38:35Z
dc.date2015-06-26T13:37:38Z
dc.date2015-11-26T15:38:35Z
dc.date.accessioned2018-03-28T22:47:05Z
dc.date.available2018-03-28T22:47:05Z
dc.identifier
dc.identifierJournal Of Thermal Analysis And Calorimetry. , v. 97, n. 2, p. 747 - 753, 2009.
dc.identifier13886150
dc.identifier10.1007/s10973-008-9602-1
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-70350399146&partnerID=40&md5=7848dc31948ea55120c0e91721742e43
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/92832
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/92832
dc.identifier2-s2.0-70350399146
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1263939
dc.descriptionExperimental data of excess molar enthalpy (H mE ) and excess molar heat capacity (C pmE ) of binary mixtures containing (1-heptanol or 1-octanol)+(diethylamine or s-butylamine) have been determined as a function of composition at 298.15 K and at 0.1 MPa using a modified 1455 Parr solution calorimeter. The excess molar enthalpy data are negative and show parabolic format over the whole composition range; however, the excess molar heat capacity values, whose curves show a S-shape, are positive in the 0.0 to 0.7 molar fraction range and negative between the molar fraction values 0.7 to 1.0. The applicability of the ERAS-model to correlate the excess molar enthalpy data was tested. The calculated data values are in good agreement with the experimental ones. The experimental behavior of H mE is interpreted in terms of specific interactions between 1-alkanol and amine molecules. © 2009 Akadémiai Kiadó, Budapest, Hungary.
dc.description97
dc.description2
dc.description747
dc.description753
dc.descriptionAcronym; Sponsor: MBIE; National Science and Technology Development Agency
dc.descriptionReimann, R., Heintz, A., (1991) J. Sol. Chem., 20, p. 29. , 10.1007/BF00651638 1:CAS:528:DyaK3MXhtlSnsLY%3D
dc.descriptionFunke, H., Wetzel, M., Heintz, A., (1989) Pure Appl. Chem., 8, p. 1429. , 10.1351/pac198961081429
dc.descriptionMatteoli, E., Lepori, L., Spanedda, A., Thermodynamic study of heptane + amine mixtures: I. Excess and solvation enthalpies at 298.15 K (2003) Fluid Phase Equilibria, 212 (1-2), pp. 41-52. , DOI 10.1016/S0378-3812(03)00260-7
dc.descriptionPina, C.G., Francesconi, A.Z., (1998) Fluid Phase Equilib., 143, p. 142. , 10.1016/S0378-3812(97)00294-X
dc.descriptionTorres, R.B., Francesconi, A.Z., (2003) J. Mol. Liq., 103, p. 99. , 10.1016/S0167-7322(02)00129-0
dc.descriptionTorres, R.B., Pina, C.G., Francesconi, A.Z., (2003) J. Mol. Liquids, 107, p. 127. , 10.1016/S0167-7322(03)00145-4 1:CAS:528:DC%2BD3sXlsl2jur4%3D
dc.descriptionTorres, R.B., Francesconi, A.Z., Volpe, P.L.O., (2004) J. Mol. Liquids, 110, p. 81. , 10.1016/j.molliq.2003.09.003 1:CAS:528:DC%2BD2cXht12qtLk%3D
dc.descriptionGonzalez, J.A., La Fuentá, I.G., Cobos, J.C., Thermodynamics of mixtures with strongly negative deviations from Raoult's law. Part 4. Application of the DISQUAC model to mixtures of 1-alkanols with primary or secondary linear amines. Comparison with Dortmund UNIFAC and ERAS results (2000) Fluid Phase Equilibria, 168 (1), pp. 31-58. , DOI 10.1016/S0378-3812(99)00326-X
dc.descriptionTorres, R.B., Francesconi, A.Z., Application of the ERAS-Model to binary mixtures of diethylamine and s-butylamine with acetonitrile in the temperature range (288.15-303.15) K (2002) Fluid Phase Equilibria, 200 (2), pp. 317-328. , DOI 10.1016/S0378-3812(02)00042-0, PII S0378381202000420
dc.descriptionTorres, R.B., Francesconi, A.Z., Volpe, P.L.O., Experimental study and modelling using the ERAS-Model of the excess molar volume of acetonitrile-alkanol mixtures at different temperatures and atmospheric pressure (2003) Fluid Phase Equilibria, 210 (2), pp. 287-306. , DOI 10.1016/S0378-3812(03)00167-5
dc.descriptionCheconi, R.F., Francesconi, A.Z., (2005) J. Therm. Anal Cal., 80, p. 295. , 10.1007/s10973-005-0650-5 1:CAS:528:DC%2BD2MXjvVCmt78%3D
dc.descriptionCheconi, R.F., D'Agostini, L., Francesconi, A.Z., (2008) J. Chem. Thermodyn., 40, p. 759. , 10.1016/j.jct.2008.01.017 1:CAS:528:DC%2BD1cXkvVeiurc%3D
dc.descriptionGalvao, A.C., Francesconi, A.Z., ERAS modeling of the excess molar enthalpies of binary liquid mixtures of 1-pentanol and 1-hexanol with acetonitrile at atmospheric pressure and 288, 298, 313 and 323 K (2006) Thermochimica Acta, 450 (1-2), pp. 81-86. , DOI 10.1016/j.tca.2006.08.007, PII S0040603106004448
dc.descriptionKinart, C.M., Kinart, W.J., Checinska-Majak, D., Bald, A., (2004) J. Therm. Anal Cal., 75, p. 347. , 10.1023/B:JTAN.0000017355.26845.a4 1:CAS:528:DC%2BD2cXhsFaju7Y%3D
dc.descriptionPińeiro, M.M., Cominges, B.E., Legido, J.L., Garcia-Garabal, S., Lopez, M., Andrade, M.I.P., (1998) J. Therm. Anal Cal., 52, p. 799. , 10.1023/A:1010170825253
dc.descriptionKimura, T., Fujisawa, M., Nakano, Y., Kamiyama, T., Otsu, T., Maeda, M., Takagi, S., Calorimetric study on inclusion of some alcohols into α-cyclodextrin cavities: Molecular mechanical calculation of hydration Gibbs energies (2007) Journal of Thermal Analysis and Calorimetry, 90 (2), pp. 581-585. , DOI 10.1007/s10973-007-7914-1
dc.descriptionTamura, K., (2001) Fluid Phase Equilib., 182, p. 303. , 10.1016/S0378-3812(01)00407-1 1:CAS:528:DC%2BD3MXktVGlu78%3D
dc.descriptionNishimoto, M., Tamura, T., Murakami, S., (1997) J. Chem. Thermodyn., 29, p. 15. , 10.1006/jcht.1996.0134 1:CAS:528:DyaK2sXpvVWksg%3D%3D
dc.descriptionCheconi, R.F., Francesconi, A.Z., (2007) J. Sol. Chem., 36, p. 913. , 10.1007/s10953-007-9155-0 1:CAS:528:DC%2BD2sXlslSqsbY%3D
dc.descriptionHeintz, A., (1985) Ber. Buns. Phys. Chem., 89, p. 172. , 1:CAS:528:DyaL2MXhtlyltLc%3D
dc.descriptionLide, D.R., (2005) Handbook of Chemistry and Physics, , CRC Press Boca Raton
dc.descriptionLama, R.F., Lu, B.C.Y., (1965) J. Chem. Eng. Data, 10, p. 216. , 10.1021/je60026a003 1:CAS:528:DyaF2MXksFSitL8%3D
dc.descriptionBoyne, J.A., Williamson, A.G., (1967) J. Chem. Eng. Data, 12, p. 318. , 10.1021/je60034a008 1:CAS:528:DyaF2sXkslKrs74%3D
dc.descriptionCostigan, M.J., Hodges, L.J., Marsh, K.N., Stokes, R.H., Tuxford, C.W., (1980) Australian J. Chem., 33, p. 2103. , 1:CAS:528:DyaL3MXjsleqtA%3D%3D
dc.descriptionFlory, P.J., Orwoll, R.A., Vrij, A.J., (1964) J. Am. Chem. Soc., 86, p. 3507. , 10.1021/ja01071a023 1:CAS:528:DyaF2cXksFOqurg%3D
dc.descriptionRosenbrock, H.H., (1960) Computer J., 3, p. 175. , 10.1093/comjnl/3.3.175
dc.descriptionKuester, J.L., Mize, J.H., (1973) Optimization Techniques, , McGraw-Hill New York
dc.descriptionNath, A., Bender, E., (1981) Fluid Phase Equilib., 7, p. 275. , 10.1016/0378-3812(81)80012-X 1:CAS:528:DyaL38XnsFChtA%3D%3D
dc.descriptionSaint-Victor, M.E., Patterson, D., W-SHAPE CONCENTRATION DEPENDENCE OF CPE AND SOLUTION NON-RANDOMNESS: KETONES plus NORMAL AND BRANCHED ALKANES. (1987) Fluid Phase Equilibria, 35 (1-3), pp. 237-252. , DOI 10.1016/0378-3812(87)80015-8
dc.descriptionAndreolli-Ball, L., Costas, M., Paquet, P., Patterson, D., Saint-Victor, M.E., (1989) Pure Appl. Chem., 61, p. 1075. , 10.1351/pac198961061075
dc.descriptionTroncoso, J., Cerdeirina, C.A., Carballo, E., Romani, L., Quantitative analysis of the W-shaped excess heat capacities of binary liquid mixtures in the light of the local composition concept (2005) Fluid Phase Equilibria, 235 (2), pp. 201-210. , DOI 10.1016/j.fluid.2005.07.005, PII S0378381205002402
dc.descriptionNishikawa, K., Tamura, K., Murakami, S., (1998) J. Chem. Thermodyn., 30, p. 229. , 10.1006/jcht.1997.0296 1:CAS:528:DyaK1cXit1Sltbs%3D
dc.descriptionNakamura, M., Tamura, K., Murakami, S., (1995) Thermochim. Acta, 253, p. 127. , 10.1016/0040-6031(94)02086-4 1:CAS:528:DyaK2MXlsFGqsrk%3D
dc.descriptionTamura, K., Osaki, A., Murakami, S., Ohji, H., Ogawa, H., Laurent, B., Grolier, J.-P.E., Thermodynamic properties of binary mixtures {an alkoxyethanol + n- octane}. Excess molar enthalpies and excess molar heat capacities at 298.15 K (1999) Fluid Phase Equilibria, 156 (1-2), pp. 137-147. , DOI 10.1016/S0378-3812(99)00036-9, PII S0378381299000369
dc.languageen
dc.publisher
dc.relationJournal of Thermal Analysis and Calorimetry
dc.rightsfechado
dc.sourceScopus
dc.titleMeasurements Of Excess Molar Enthalpy And Excess Molar Heat Capacity Of (1-heptanol Or 1-octanol)+(diethylamine Or S-butylamine) Mixtures At 298.15 K And 0.1 Mpa
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución