Chemoselective Aromatic Azido Reduction With Concomitant Aliphatic Azide Employing Al/gd Triflates/nal And Esi-ms Mechanistic Studies

dc.creatorKamal A.
dc.creatorMarkandeya N.
dc.creatorShankaraiah N.
dc.creatorRatna Reddy C.
dc.creatorPrabhakar S.
dc.creatorSanjeeva Reddy C.
dc.creatorEberlin M.N.
dc.creatorSantos L.S.
dc.date2009
dc.date2015-06-26T13:37:11Z
dc.date2015-11-26T15:37:43Z
dc.date2015-06-26T13:37:11Z
dc.date2015-11-26T15:37:43Z
dc.date.accessioned2018-03-28T22:46:09Z
dc.date.available2018-03-28T22:46:09Z
dc.identifier
dc.identifierChemistry - A European Journal. , v. 15, n. 29, p. 7215 - 7224, 2009.
dc.identifier9476539
dc.identifier10.1002/chem.200900853
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-67650609405&partnerID=40&md5=76fdbe67c513c48bcbfbdb918cf005f6
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/92709
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/92709
dc.identifier2-s2.0-67650609405
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1263716
dc.descriptionAluminium and gadolinium inflates catalyze the chemoselective reduction of aromatic azides to the corresponding amines in combination with sodium iodide. This mild chemoselective method has been applied to the synthesis of various aryl amines, C2azido-substituted pyrrolo[2,1-c]-[1,4]benzodiazepines, and fused[2,1b]quinazolinones by an intramolecular azido reduction tandem cyclization reaction. Interestingly, this methodology selectively reduces aryl azides with enhanced yields and proceeds in shorter reaction times than previous strategies. The mechanistic aspects have been investigated and the intermediates associated with this selective transformation have been intercepted and characterized by online monitoring of the reaction by ESI-MS. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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dc.languageen
dc.publisher
dc.relationChemistry - A European Journal
dc.rightsfechado
dc.sourceScopus
dc.titleChemoselective Aromatic Azido Reduction With Concomitant Aliphatic Azide Employing Al/gd Triflates/nal And Esi-ms Mechanistic Studies
dc.typeArtículos de revistas


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