Artículos de revistas
Extraction Of Corn Colorants (zea Mays L.) [extração De Corantes De Milho (zea Mays L.)]
Registro en:
Ciencia E Tecnologia De Alimentos. , v. 29, n. 1, p. 62 - 69, 2009.
1012061
2-s2.0-67649837049
Autor
Gamarra F.M.C.
Leme G.C.
Tambourgi E.B.
Bittencourt E.
Institución
Resumen
Natural colorants were craftly made and widely used before the discovery of the synthetic colorants. The study and the use of natural colorants have become important again in the last few years due to questions raised by the international health organizations and consumers related to the indiscriminate use of synthetic colorants which were linked to the development of degenerative illnesses and environmental impact. The colorant extracted from purple corn (Zea Mays L.) was used by the Inca civilization to prepare food and to dye textile fibers. In this work, pigments from the anthocyanin group were extracted from purple corn and red corn (Zea Mays L.) varieties and were later characterized. Three extraction methods were used: immersion, lixiviation with some changes, and supercritical extraction (ESC). The best method of extraction was lixiviation, which reached 88% (m/m) of performance as a function of the mass of colorant extracted and of the raw materials. Also using the modified lixiviation it was possible to concentrate the acylate compounds in 3% as well as to recover 85% of solvent used. A pH indicator was obtained by fixing the anthocyanins on a filter paper based on anthocyanins stabilization. This technique can be utilized in laboratory chemistry lessons. 29 1 62 69 Abdel-Aal, E.S.M., Hucl, P., A rapid method for quantifying total anthocyanins in blue aleurone and purple pericarp wheats (1999) Cereal Chemistry, 76 (3), pp. 350-354 Abdel-Aal, E.S.M., Young, C.H., Rabalski, I., Anthocyanin composition in black, blue, pink, purple, and red cereal grains (2006) Journal of Agricultural and Food Chemistry, 54 (13), pp. 4696-4704 Acquaviva, R., Cyanidin and cyanidin 3-O-β-D-glucoside as DNA cleavage protectors and antioxidants (2003) Cell Biology and Toxicology, 19 (4), pp. 243-252 (1995) Official Methods of Analysis, , ASSOCIATION OF OFFICIAL ANALYTICAL CHEMISTS - AOAC., Edited by Sidney Williams. Washington, EUA Awika, J.M., Rooney, L.W., Waniska, R.D., Anthocyanins from black sorghum and their antioxidant properties (2004) Food Chemistry, 90 (1-2), pp. 293-301 Bluhm, E.C., Personal hair dye use and risks of glioma, meningioma, and acoustic neuroma among adults (2007) American Journal of Epidemiology, 165 (1), pp. 63-71 Brack-Egg, A., Zea Mays, L., (1999) Diccionario enciclopédico de plantas útiles del Peru, pp. 537-538. , 1 ed. Cuzco, Perú: Imprenta-Editorial del Centro Bartolomé de Las Casas Brouillard, R., Chemical structure of anthocyanins (1982) Anthocyanins as Food Colors, pp. 1-38. , P. Markakis (Ed.). New York: Academic Press Cabrita, L., Fossen, T., Andersen, O.M., Colour and stability of the six common anthocyanidin 3-glucosides in aqueous solutions (2000) Food Chemistry, 68 (1), pp. 101-107 Drust, R.W., Wrolstad, R.E., Separation and characterization of anthocyanins by Hplc (2001) Current Protocols in Food Analytical Chemistry, , In: Wrolstad, R. E. (Ed.), New York: John Wiley & Sons, Fl 3.1-3.13 Fossen, T., Slimestad, R., Andersen, O.M., Anthocyanins from maize (Zea mays) and reed canarygrass (Phalaris arundinacea) (2001) Journal of Agricultural and Food Chemistry, 49 (5), pp. 2318-2321 Fuleki, T., Francis, F.J., Quantitative methods for anthocyanins. 2. Determination of total anthocyanin and degradation index for cranberry juice (1968) Journal of Food Science, 33, pp. 78-83 Gago-Dominguez, M., Use of permanent hair dyes and bladder-cancer risk (2001) Internacional. Journal of Cancer, 91 (4), pp. 575-579 Giusti, M.M., Anthocyanin pigment composition of red radish cultivars as potential food colorants (1998) Journal of Food Science, 63 (2), pp. 219-224 Hagiwara, A., Pronounced inhibition by a natural anthocyanin, purple corn color, of 2-amino-1-methyl- 6-phenylimidazo [4,5-b] pyridine (PhIP)-associated colorectal carcinogenesis in male F344 rats pretreated with1,2- dimethylhydrazine (2001) Cancer Letters, 171 (1), pp. 17-25 Harborne, J.B., The Anthocyanin pigments (1967) Comparative Biochemistry of the Flavonoids, pp. 1-30. , New York, Academic Press Hartge, P., Use of hair dyes and risk of bladder cancer (1982) Cancer Research, 42, pp. 4784-4787 Heinonen, I.M., Meyer, A.S., Frankel, E.N., Antioxindat activity of berry phenolics on human low-density lipoprotein and liposome oxidation (1998) Journal of Agricultural and Food Chemistry, 46 (10), pp. 4107-4112 Hyun, J.W., Chung, H.S., Cyanidin and malvidin from oryza sativa cv. heugjinjubyeo mediate cytotoxicity against human monocytic leukemia cells by arrest of G2/M phase and induction of apoptosis (2004) Journal of Agricultural and Food Chemistry, 52 (8), pp. 2213-2217 Jayaprakasam, B., Insulin secretion by bioactive anthocyanins and anthocyanidins present in fruits (2005) Journal of Agricultural and Food Chemistry, 53 (1), pp. 28-31 Kallithraka, S., Determination of major anthocyanin pigments in Hellenic native grapes varieties (Vitis vinifera sp.): Association with antiradical activity (2005) Journal of Food Composition and Analysis, 18 (5), pp. 375-386 Kamei, H., Suppression of tumor cell growth by anthocyanins in vitro (1995) Cancer Invest, 13 (6), pp. 590-594 Kirschbaum, J., Krause, C., Brückner, H., Liquid chromatographic quantification of synthetic colorants in fish roe and caviar (2006) European Food Research and Technology, 222 (5-6), pp. 572-579 Longo, L., Vasapollo, G., Rescio, L., Identification of anthocyanins in Rhamnus alaternus L. Berries (2005) Journal of Agricultural and Food Chemistry, 53 (5), pp. 1723-1727 Markakis, P., (1982) Anthocyanins as Food Colors, p. 262. , New York, USA: Academic Press Mozetic, B., Trebse, P., Hribar, J., Determination and quantification of anthocyanins and hydroxycinnamic acids in different cultivars of sweet cherries (Prunusa Vium L.) from Nova Gorica Region (Slovenia) (2002) Food Technology Biotechnology, 40 (3), pp. 207-212 Nam, S.H., Antioxidative activities of bran from twenty one pigmented rice cultivars (2006) Food Chemistry, 94 (4), pp. 613-620 Pedreschi, R., Cisneros-Zevallos, L., Phenolic profiles of andean purple corn (Zea mays L.) (2007) Food Chemistry, 100 (3), pp. 956-963 Philpott, M., In situ and in vitro antioxidant activity of sweetpotato anthocyanins (2004) Journal of Agricultural and Food Chemistry, 52 (6), pp. 1511-1513 Rodríguez-Saona, L.E., Giusti, M.M., Wrolstad, R.E., Anthocyanin pigment composition of red-fleshed potatoes (1998) Journal of Food Science, 63 (3), pp. 458-465 Silva, G.F., Extraction of Bixin from Annatto seeds using supercritical carbon dioxide (2008) Brazilian Journal of Chemical Engineering, , Accept Smith, B., Pollution prevention needs and opportunities in the textile industry (1994) Materials Research, , Center for Hazardous, In press Strack, D., Wray, V., Anthocyanins (1989) Methods in Plant Biochemistry, 1, pp. 325-356. , Harborne, J.B. (Ed.). London: Academic Press Takeoka, G.R., Characterization of black bean (Phaseolus vulgaris L.) anthocyanins (1997) Journal of Agricultural and Food Chemistry, 45 (9), pp. 339-53400 Tsuda, T., Protective effects of dietary cyanidin 3-O-β-D-glucoside on liver ischemia-reperfusion injury in rats (1999) Archives of Biochemistry and Biophysics, 368 (2), pp. 361-366 Tsuda, T., Absorption and metabolism of cyanidin 3-O-β-D-glucoside in rats (1999) FEBS Letters, 449 (2-3), pp. 179-182 Tsuda, T., Dietary 581 cyanidin 3-O- β-D-glucoside-rich purple corn color prevents obesity and ameliorates hyperglycemia (2003) Journal Nutrition, 133 (7), pp. 2125-2130 Tsuda, T., Antioxidative pigments isolated from the seeds of Phaseolus vulgaris L. (1994) Journal of Agricultural and Food Chemistry, 42 (2), pp. 248-251 Wang, C.J., Protective effect of Hibiscus anthocyanins against tert-butyl hydroperoxide-induced hepatic toxicity in rats (2000) Food and Chemical Toxicology, 38 (5), pp. 411-416 Wang, F., Properties of anthocyanins from grape cell culture (1997) Journal of Food Science, 62 (2), pp. 246-248 Wang, H., Antioxidant and anti-inflammatory activities of anthocyanins and their aglicons, cyanidin, from a tart cherries (1999) Journal of Natural Products, 62 (2), pp. 294-296 Yong, J.Z., Howar, L.R., Effects of solvent and temperature on pressurized liquid extraction of anthocyanins and total phenolics from dried red grape skin (2003) Journal of Agricultural and Food Chemistry, 51 (18), pp. 5207-5213 Zhao, C., Effects of commercial anthocyanin-rich extracts on colonic cancer and nontumorigenic colonic cell growth (2004) Journal of Agricultural and Food Chemistry, 52 (20), pp. 6122-6128