Artículos de revistas
Production Of Monoglycerides And Diglycerides Through Lipase-catalyzed Glycerolysis And Molecular Distillation [produção De Monoacilgliceróis E Diacilgliceróis Via Glicerólise Enzimática E Destilação Molecular]
Registro en:
Quimica Nova. , v. 32, n. 6, p. 1539 - 1543, 2009.
1004042
2-s2.0-70349895054
Autor
Fregolente P.B.L.
Pinto G.M.F.
Wolf-Maciel M.R.
Filho R.M.
Batistella C.B.
Institución
Resumen
Monoacilglycerides and diacilglycerides are produced through lipase-catalyzed glycerolysis of soybean oil using Candida antárctica B in a solvent-free system. The reaction was carried out at a glycerol to triacylglycerol molar ratio of 8:1 with 2% of lipase. Acylglycerides, free fatty acids (FFA) and glycerol produced were separated employing the molecular distillation process. Starting from a product of enzymatic reaction 25.06% of triacylglycerols, 46.63% of diacylglycerides, 21.72% of monoacylglycerides, 5.38% of FFA and 1.21% of glycerol and after consecutively distillations, monoacylglycerides with 80% of purity was obtained and also oil with 54% of diacylglycerides to be used in human dietary. 32 6 1539 1543 Meng, X., Zou, D., Shi, Z., Duan, Z., Mao, Z., (2006) Lipids, 39, p. 37 Hickman, K.C.D., (1943) Chem. Rev., 34, p. 51 Watanabe, H., Onizawa, K., Naito, S., Taguchi, H., Goto, N., Nagao, T., Matsuo, N., Itakura, H., (2001) Ann. Nutr. Metab., 45, p. 264 Maki, C.K., Davidson, M., Tsushima, R., Matsuo, N., Tokimitsu, I., Umporowicz, D.N., Dicklin, M.R., Bell, M., (2002) Am. J. Clin. Nutr., 76, p. 1230 Yasunaga, K., Glinsmann, W.H., Seo, Y., Katsuragi, Y., Kobayashi, S., Flickinger, B., Kennepohl, E., Borzelleca, J., (2004) Food Chem. Toxicol., 42, p. 1419 Shimizu, M., Moriwaki, J., Nishide, T., Nakajima, Y., (2004) J. Am. Oil Chem. Soc., 81, p. 571 Yamamoto, K., Takeshita, M., Tokimitsu, I., Watanabe, H., Mizuno, T., Asakawa, H., Tokunaga, K., Yagi, N., (2006) Nutrition, 22, p. 23 Li, D., Xu, T., Takase, H., Tokimitsu, I., Zhang, P., Wang, Q., Yu, X., Zhang, A., (2008) Clinical Nutrition, 27, p. 203 Sonntag, N.O.V., (1982) J. Am. Oil Chem. Soc., 59, p. 795 Ferreira-Dias, S., Correia, A.C., Baptista, F.O., Fonseca, M.M.R., (2001) J. Mol. Catal. B: Enzym., 11, p. 699 Guo, Z., Xu, X., (2006) Green Chem., 8, p. 54 Micov, M., Lutisan, J., Cvengros, J., (1997) Sep. Sci. Technol., 32, p. 3051 Batistella, C.B., Maciel, M.R.W., (1996) Comput. Chem. Eng., 20, p. 19 Fregolente, L.V., Batistella, C.B., Maciel, R., Wolf-Maciel, M.R., (2005) J. Am. Oil Chem. Soc., 82, p. 673 Batistella, C.B., Moraes, E.B., Maciel Filho, R., Maciel, M.R.W., (2002) Appl. Biochem. Biotechnol., 98, p. 1149 Moraes, E.B., Batistella, C.B., Alvarez, M.E.T., Maciel Filho, R., Maciel, M.R.W., (2004) Appl. Biochem. Biotechnol., 113, p. 689 Breivik, H., Haraldsson, G.G., Kristinsson, B., (1997) J. Am. Oil Chem. Soc., 74, p. 1425 Kwon, S.J., Han, J.J., Rhee, J.S., (1995) Enzyme Microb. Technol., 17, p. 700 Fregolente, P.B.L., Fregolente, L.V., Pinto, G.M.F., Batistella, C.B., Wolf-Maciel, M.R., Maciel Filho, R., (2008) Appl. Biochem. Biotechnol., 146, p. 165 Schoenfelder, W., (2003) Eur. J. Lip. Sei. Technol., 105, p. 45