Nitric Oxide As An Activation Agent For Nucleophilic Attack In Trans-[ru(no)(nh3)4{p(oet)3}](pf 6)3

dc.creatorMetzker G.
dc.creatorToledo Jr. J.C.
dc.creatorLima F.C.A.
dc.creatorMagalhaes A.
dc.creatorCardoso D.R.
dc.creatorFranco D.W.
dc.date2010
dc.date2015-06-26T12:35:35Z
dc.date2015-11-26T15:25:38Z
dc.date2015-06-26T12:35:35Z
dc.date2015-11-26T15:25:38Z
dc.date.accessioned2018-03-28T22:34:25Z
dc.date.available2018-03-28T22:34:25Z
dc.identifier
dc.identifierJournal Of The Brazilian Chemical Society. , v. 21, n. 7, p. 1266 - 1273, 2010.
dc.identifier1035053
dc.identifier
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-77954267952&partnerID=40&md5=10b2908807eb69b504863eaf81d64320
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/90959
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/90959
dc.identifier2-s2.0-77954267952
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1260952
dc.descriptionThe complex trans-[Ru(NO)(NH3)4{P(OEt) 3}](PF6)3 undergoes nucleophilic attack on the phosphorus ester ligand in the solid state yielding trans-[Ru(NO)(NH 3)4{P(OH)(OEt)2}](PF6)3. The reaction was monitored and the products analyzed using nuclear magnetic resonance spectroscopy (31P{1H} CP-MAS NMR and 31P{1H} NMR), infrared spectroscopy (FTIR), electron paramagnetic resonance spectroscopy (EPR), cyclic voltammetry (CV), electronic spectroscopy (UV-Vis) and elemental analysis. According to experimental data and quantum mechanical calculations (DFT), the reaction proceeds in the solid state by the nucleophilic attack on the phosphorus ligand, promoted by the strong polarization along the PIII-RuII-NO+ axis induced by the nitrosyl ligand, and takes place following the Michaelis-Arbusov type mechanism for phosphorus ester hydrolysis. In solution, the nucleophilic attack occurs simultaneously at the nitrosyl and triethylphosphite ligands, yielding trans-[Ru(H2O)(NH3)4{P(OEt) 3}]2+ and trans-[Ru(NO)(H2O)(NH 3)4]3+ in comparable amounts.
dc.description21
dc.description7
dc.description1266
dc.description1273
dc.descriptionLundberg, J.O., Weitzberg, E., Gladwin, M.T., (2008) Nat. Rev. Drug Discovery, 7, p. 156
dc.descriptionLi, H., Igarashi, J., Jamal, J., Yang, W., Poulos, T.L., (2006) J. Biol. Inorg. Chem., 11, p. 753
dc.descriptionCullota, E., Koshland, J.D.E., (1992) Science, 258, p. 1862
dc.descriptionToledo, J.C., Silva, H.A.S., Scarpellini, M., Mori, V., Camargo, A.J., Bertotti, M., Franco, D.W., (2004) Eur. J. Inorg. Chem., 9, p. 1879
dc.descriptionTfouni, E., Krieger, M., McGarvey, B.R., Franco, D.W., (2003) Coord. Chem. Rev., 236, p. 57
dc.descriptionClarke, M.J., (2003) Coord. Chem. Rev., 236, p. 209
dc.descriptionMcCleverty, J.A., (2004) Chem. Rev., 104, p. 403
dc.descriptionFranco, D.W., Taube, H., (1978) Inorg. Chem., 17, p. 571
dc.descriptionLopes, L.G.F., Castellano, E.E., Ferreira, A.G., Davanzo, C.U., Clarke, M.J., Franco, D.W., (2005) Inorg. Chim. Acta, 358, p. 2883
dc.descriptionSilva, J.J.N., Osakabe, A.L., Pavanelli, W.R., Silva, J.S., Franco, D.W., (2007) Br. J. Pharmacol., 152, p. 112
dc.descriptionIshmaeva, E.A., Popova, E.V., Mironov, V.F., Aminova, R.M., Vereshchagina, Y.A., Galkin, V.I., Moeller, K., Schmutzler, R., (2004) Russ. J. Org. Chem., 40, p. 1076
dc.descriptionDoak, G.O., Freedman, L.D., (1961) Chem. Rev., 61, p. 31
dc.descriptionCorbridge, D.C.E., (1990) Phosphorus: An Outline of its Chemistry, Biochemistry and Technology, , 4th ed., Elsevier: Amsterdam
dc.descriptionKirby, A.J., Warren, S.G., (1967) The Organic Chemistry of Phosphorus, , 1st ed., Elsevier: New York
dc.descriptionToledo, J.C., Lima-Neto, B.S., Franco, D.W., (2005) Coord. Chem. Rev., 249, p. 419
dc.descriptionCaramori, G.F., Frenking, G., (2007) Organometalics, 26, p. 5815
dc.descriptionBezerra, C.W.B., Silva, S.C., Gambardella, M.T.P., Santos, R.H.A., Plicas, L.M.A., Tfouni, E., Franco, D.W., (1999) Inorg. Chem., 8, p. 5660
dc.descriptionNakamoto, K., (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds, , 4th ed., John Wiley &amp
dc.descriptionSons: New York
dc.descriptionSocrates, G., (2001) Infrared and Raman Characteristic Group Frequencies, , 3rd ed., John Wiley &amp
dc.descriptionSons: New York
dc.descriptionSchreiner, A.F., Lin, S.W., Hausser, P.J., Hopcus, E.A., Hamm, D.J., Gunter, J.D., (1972) Inorg. Chem., 11, p. 880
dc.descriptionGorelsky, S.I., Silva, S.C., Lever, A.B.P., Franco, D.W., (2000) Inorg. Chim. Acta, 300, p. 698
dc.descriptionVerdake, J.G., Quin, L.D., (1987) Phophorus-31 NMR Spectroscopy on Stereochemical Analysis, , VCH Paublishers: Deerfield Beach
dc.descriptionAguiar, M.R.M.P., Gemal, A.L., Gil, R.A.S.S., (1999) Quim. Nova, 22, p. 553
dc.descriptionPenner, G.H., Wasylishen, R.E., (1989) Can. J. Chem., 67, p. 1909
dc.descriptionMoynihan, H.A., O'Hare, I.P., (2002) Int. J. Pharmam, 247, p. 179
dc.descriptionSernaglia, R.L., Franco, D.W., (1989) Inorg. Chem., 28, p. 3485
dc.descriptionTruzzi, D.R., Franco, D.W., (2008) Abstracts of the XIV Brazilian Meeting in Inorganic Chemistry, , Foz de Iguaçu, Brazil
dc.descriptionXi, C., Liu, Y., Lai, C., Zhou, L., (2004) Inorg. Chem. Commun., 7, p. 1202
dc.descriptionHan, L.B., Tanaka, M., (1996) J. Am. Chem. Soc., 118, p. 1571
dc.descriptionBrill, T.E., Landon, S.J., (1984) Chem. Rev., 84, p. 577
dc.descriptionBezerra, C.W.B., Silva, S.C., Gambardella, M.T.P., Santos, R.H.A., Plicas, M.L., Tfouni, E., Franco, D.W., (1999) Inorg. Chem., 38, p. 5660
dc.descriptionKoleva, G., Galabov, B., Wu, J.I., Schaefer, H.F., Schleyer, P.R., (2009) J. Am. Chem. Soc., 131, p. 14772
dc.descriptionMazzetto, S.E., Gambardella, M.T.P., Santos, R.H.A., Lopes, L.G.F., Franco, D.W., (1999) Polyhedron., 18, p. 979
dc.descriptionPerrin, D.D., Armarego, W.L.F., (1983) Purification of Laboratory Chemicals, , 3rd ed., Pergamon Press: New York
dc.descriptionKolthoff, I.M., (1969) Quantitative Chemical Analysis, , 4th ed., Macmillan: New York
dc.descriptionShriver, D.F., Drezdzon, M.A., (1986) The Manipulation of Air-Sensitive Compounds, , 2nd ed., Wiley: New York
dc.descriptionFrisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Montgomery Jr., J.A., Pople, J.A., (2004), Gaussian 03 Revision C.02
dc.descriptionWallingfordBecke, A.D., (1993) J. Chem. Phys., 98, p. 5648
dc.descriptionFarkas, O., Schlegel, H.B., (1999) J. Chem. Phys., 111, p. 10806
dc.descriptionCances, E., Mennucci, B., Tomasi, J., (1997) J. Chem. Phys., 107, p. 3032
dc.descriptionReed, A.E., Weinhold, F., (1985) J. Chem. Phys., 83, p. 1736
dc.descriptionReed, A.E., Curtiss, L.A., Weinhold, F., (1988) Chem. Rev., 88, p. 899
dc.descriptionGlendening, E.D., Badenhoop, J.K., Reed, A.E., Carpenter, J.E., Weinhold, F., (1999) NBO4. M
dc.descriptionNBO Analysis Programs, , University of Wisconsin, USA
dc.languageen
dc.publisher
dc.relationJournal of the Brazilian Chemical Society
dc.rightsaberto
dc.sourceScopus
dc.titleNitric Oxide As An Activation Agent For Nucleophilic Attack In Trans-[ru(no)(nh3)4{p(oet)3}](pf 6)3
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución