dc.creatorZabot G.L.
dc.creatorMoraes M.N.
dc.creatorMeireles M.A.A.
dc.date2014
dc.date2015-06-25T17:49:43Z
dc.date2015-11-26T15:25:20Z
dc.date2015-06-25T17:49:43Z
dc.date2015-11-26T15:25:20Z
dc.date.accessioned2018-03-28T22:34:09Z
dc.date.available2018-03-28T22:34:09Z
dc.identifier
dc.identifierJournal Of Supercritical Fluids. Elsevier, v. 94, n. , p. 234 - 244, 2014.
dc.identifier8968446
dc.identifier10.1016/j.supflu.2014.07.020
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-84907356767&partnerID=40&md5=5ba80113b7b87ff4d054e13fb4d99d2b
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/85702
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/85702
dc.identifier2-s2.0-84907356767
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1260887
dc.descriptionBed geometry plays an important role in supercritical fluid extraction kinetics. Thus, the objective of this study was to compare the overall extraction curves (OEC's) of rosemary compounds obtained in two beds of 1 L each with different geometries (in terms of height to bed (HB) diameter (DB) ratios, HB/DB). A scale-up study was carried out maintaining the solvent mass to feed mass (S/F) ratio equal for both beds. Other process variables, such as bed porosity, apparent and true densities of the raw material, particle average size, temperature, pressure and time of extraction, were also maintained constant. The kinetic parameters were obtained by fitting the OEC to a spline model. The results revealed differences of mass transfer rates, mass ratios of solute in the fluid phase and yields of extract in the constant extraction rate period. The evaluation of the OEC's and kinetic parameters indicated that the bed with lower HB/DB ratio (HB/DB = 2.7) was more favorable for obtaining rosemary extract. The kinetics of extraction of oxygenated monoterpenes (i.e., 1,8-cineole and camphor) and phenolic diterpenes (i.e., carnosic acid) were also different for both bed geometries. These behaviors suggest that the bed geometry presents a pronounced influence in the mass transport properties in supercritical media. Thus, in spite of the scale-up criterion be successful for several botanic matrices such as clove buds, sugarcane residue and grape seeds residue, the criterion applied in this study (maintaining a constant S/F ratio for a given time of extraction) was not suitable for this raw material. © 2014 Elsevier B.V.
dc.description94
dc.description
dc.description234
dc.description244
dc.descriptionZabot, G.L., Moraes, M.N., Meireles, M.A.A., Supercritical fluid extraction of bioactive compounds from botanic matrices: Experimental data, process parameters and economic evaluation (2012) Recent Patents on Engineering, 6, pp. 182-206
dc.descriptionZabot, G.L., Moraes, M.N., Petenate, A.J., Meireles, M.A.A., Influence of the bed geometry on the kinetics of the extraction of clove bud oil with supercritical CO2 (2013) J. Supercritical Fluids, , 10.1016/j.supflu.2013.1010.1001
dc.descriptionMoura, L.S., Carvalho Jr., R.N., Stefanini, M.B., Ming, L.C., Meireles, M.A.A., Supercritical fluid extraction from fennel (Foeniculum vulgare): Global yield, composition and kinetic data (2005) Journal of Supercritical Fluids, 35 (3), pp. 212-219. , DOI 10.1016/j.supflu.2005.01.006, PII S089684460500032X
dc.descriptionCarvalho Jr., R.N., Moura, L.S., Rosa, P.T.V., Meireles, M.A.A., Supercritical fluid extraction from rosemary (Rosmarinus officinalis): Kinetic data, extract's global yield, composition, and antioxidant activity (2005) Journal of Supercritical Fluids, 35 (3), pp. 197-204. , DOI 10.1016/j.supflu.2005.01.009, PII S0896844605000288
dc.descriptionQuispe-Condori, S., Foglio, M.A., Rosa, P.T.V., Meireles, M.A.A., Obtaining β-caryophyllene from Cordia verbenacea de Candolle by supercritical fluid extraction (2008) J. Supercritical Fluids, 46, pp. 27-32
dc.descriptionSánchez-Vicente, Y., Cabañas, A., Renuncio, J.A.R., Pando, C., Supercritical fluid extraction of peach (Prunus persica) seed oil using carbon dioxide and ethanol (2009) J. Supercritical Fluids, 49, pp. 167-173
dc.descriptionIbanez, E., Oca, A., De Murga, G., Lopez-Sebastian, S., Tabera, J., Reglero, G., Supercritical fluid extraction and fractionation of different preprocessed rosemary plants (1999) Journal of Agricultural and Food Chemistry, 47 (4), pp. 1400-1404. , DOI 10.1021/jf980982f
dc.descriptionVicente, G., Martín, D., García-Risco, M.R., Fornari, T., Reglero, G., Supercritical carbon dioxide extraction of antioxidants from rosemary (Rosmarinus officinalis) leaves for use in edible vegetable oils (2012) J. Oleo Science, 61, pp. 689-697
dc.descriptionBorrás-Linares, I., Arráez-Román, D., Herrero, M., Ibáñez, E., Segura-Carretero, A., Fernández-Gutiérrez, A., Comparison of different extraction procedures for the comprehensive characterization of bioactive phenolic compounds in Rosmarinus officinalis by reversed-phase high-performance liquid chromatography with diode array detection coupled to electrospray time-of-flight mass spectrometry (2011) J. Chromatography A, 1218, pp. 7682-7690
dc.descriptionMulinacci, N., Innocenti, M., Bellumori, M., Giaccherini, C., Martini, V., Michelozzi, M., Storage method, drying processes and extraction procedures strongly affect the phenolic fraction of rosemary leaves: An HPLC/DAD/MS study (2011) Talanta, 85, pp. 167-176
dc.descriptionSilva, N., Alves, S., Gonçalves, A., Amaral, J.S., Poeta, P., Antimicrobial activity of essential oils from mediterranean aromatic plants against several foodborne and spoilage bacteria (2013) Food Science and Technology International, 19, pp. 503-510
dc.descriptionRamadan, K.S., Khalil, O.A., Danial, E.N., Alnahdi, H.S., Ayaz, N.O., Hypoglycemic and hepatoprotective activity of Rosmarinus officinalis extract in diabetic rats (2013) J. Physiology and Biochemistry, 69, pp. 779-783
dc.descriptionChen, X., Zhang, Y., Zu, Y., Yang, L., Lu, Q., Wang, W., Antioxidant effects of rosemary extracts on sunflower oil compared with synthetic antioxidants (2014) International J. Food Science and Technology, 49, pp. 385-391
dc.descriptionErrafiy, N., Ammar, E., Soukri, A., Protective effect of some essential oils against oxidative and nitrosative stress on Tetrahymena thermophila growth (2013) J. Essential Oil Research, 25, pp. 339-347
dc.descriptionValdés, A., García-Cañas, V., Rocamora-Reverte, L., Gómez-Martínez, Á., Ferragut, J.A., Cifuentes, A., Effect of rosemary polyphenols on human colon cancer cells: Transcriptomic profiling and functional enrichment analysis (2013) Genes and Nutrition, 8, pp. 43-60
dc.descriptionMonino, I., Martinez, C., Sotomayor, J.A., Lafuente, A., Jordan, M.J., Polyphenols transmission to Segureño lamb meat from ewes' diet supplemented with the distillate from rosemary (Rosmarinus officinalis) leaves (2008) Journal of Agricultural and Food Chemistry, 56 (9), pp. 3363-3367. , DOI 10.1021/jf7036856
dc.descriptionShin, H.B., Choi, M.S., Ryu, B., Lee, N.R., Kim, H.I., Choi, H.E., Chang, J., Inn, K.S., Antiviral activity of carnosic acid against respiratory syncytial virus (2013) Virology J., 10, pp. 303-313
dc.descriptionJirovetz, L., Buchbauer, G., Denkova, Z., Stoyanova, A., Murgov, I., Schmidt, E., Geissler, M., Antimicrobial testings and gas chromatographic analysis of pure oxygenated monoterpenes 1,8-cineole, α-terpineol, terpinen-4-ol and camphor as well as target compounds in essential oils of pine (Pinus pinaster), rosemary (Rosmarinus officinalis), tea tree (Melaleuca alternifolia) (2005) Scientia Pharmaceutica, 73 (1), pp. 27-38
dc.descriptionVicente, G., Molina, S., González-Vallinas, M., García-Risco, M.R., Fornari, T., Reglero, G., De Molina, A.R., Supercritical rosemary extracts, their antioxidant activity and effect on hepatic tumor progression (2013) J. Supercritical Fluids, 79, pp. 101-108
dc.descriptionPronyk, C., Mazza, G., Design and scale-up of pressurized fluid extractors for food and bioproducts (2009) J. Food Engineering, 95, pp. 215-226
dc.descriptionPrado, J.M., Prado, G.H.C., Meireles, M.A.A., Scale-up study of supercritical fluid extraction process for clove and sugarcane residue (2011) J. Supercritical Fluids, 56, pp. 231-237
dc.descriptionAlbuquerque, C.L.C., Obtaining defatted seeds and oil rich in tocotrienols from annatto by supercritical extraction: Study of process parameters, scale-up and economical feasibility (2013) School of Food Engineering, p. 288. , University of Campinas Brazil
dc.descriptionPrado, J.M., Scale-up study of supercritical fluid extraction process in fixed bed (2010) School of Food Engineering, p. 283. , University of Campinas Brazil
dc.descriptionPrado, J.M., Dalmolin, I., Carareto, N.D.D., Basso, R.C., Meirelles, A.J.A., Oliveira, J.V., Batista, E.A.C., Meireles, M.A.A., Supercritical fluid extraction of grape seed: Process scale-up, extract chemical composition and economic evaluation (2012) J. Food Engineering, 109, pp. 249-257
dc.descriptionMartinez, J., Rosa, P.T.V., Meireles, M.A.A., Extraction of clove and vetiver oils with supercritical carbon dioxide: Modeling and simulation (2007) The Open Chemical Engineering J., 1, pp. 1-7
dc.descriptionSilva, L.P.S., Mathematical modeling of mass transfer in supercritical fluid extraction process from red pepper (2013) School of Food Engineering, p. 215. , University of Campinas Brazil
dc.descriptionTakeuchi, T.M., Supercritical extraction of macela, clove and vetiver: Technological and economical aspects (2009) School of Food Engineering, p. 417. , University of Campinas Brazil
dc.descriptionAsae, (1998) Method of Determining and Expressing Fineness of Feed Materials by Sieving, , ASAE St. Joseph, MI
dc.descriptionJacobs, M.B., (1973) The Chemical Analysis of Foods and Food Products, , R.E. Krieger Pub. Co. Huntington, NY
dc.descriptionTakeuchi, T.M., Leal, P.F., Favareto, R., Cardozo-Filho, L., Corazza, M.L., Rosa, P.T.V., Meireles, M.A.A., Study of the phase equilibrium formed inside the flash tank used at the separation step of a supercritical fluid extraction unit (2008) Journal of Supercritical Fluids, 43 (3), pp. 447-459. , DOI 10.1016/j.supflu.2007.08.002, PII S0896844607002963
dc.descriptionRodrigues, V.M., Rosa, P.T.V., Marques, M.O.M., Petenate, A.J., Meireles, M.A.A., Supercritical extraction of essential oil from aniseed (Pimpinella anisum L.) using CO2: Solubility, kinetics, and composition data (2003) J. Agricultural and Food Chemistry, 51, pp. 1518-1523
dc.descriptionMeireles, M.A.A., Extraction of bioactive compounds from Latin American plants (2008) Supercritical Fluid Extraction of Nutraceuticals and Bioactive Compounds, pp. 243-274. , J. Martinez, CRC/Taylor & Francis Boca Raton, FL/London
dc.descriptionCuvelier, M.-E., Richard, H., Berset, C., Antioxidative activity and phenolic composition of pilot-plant and commercial extracts of sage and rosemary (1996) JAOCS, Journal of the American Oil Chemists' Society, 73 (5), pp. 645-652
dc.descriptionZabot, G.L., Moraes, M.N., Rostagno, M.A., Meireles, M.A.A., Fast analysis of phenolic terpenes by high-performance liquid chromatography using a fused-core column (2014) Analytical Methods, , 10.1039/C1034AY01124D
dc.descriptionSovová, H., Rate of the vegetable oil extraction with supercritical CO2 - I. Modelling of extraction curves (1994) Chemical Engineering Science, 49, pp. 409-414
dc.descriptionBrunner, G., (1994) Gas Extraction: An Introduction to Fundamentals of Supercritical Fluids and the Application to Separation Processes, , Steinkopff/Springer Darmstadt/New York
dc.descriptionFerreira, S.R.S., Meireles, M.A.A., Cabral, F.A., Extraction of essential oil of black pepper with liquid carbon dioxide (1993) Journal of Food Engineering, 20 (2), pp. 121-133. , DOI 10.1016/0260-8774(93)90010-H
dc.descriptionFerreira, S.R.S., Nikolov, Z.L., Doraiswamy, L.K., Meireles, M.A.A., Petenate, A.J., Supercritical fluid extraction of black pepper (Piper nigrun L.) essential oil (1999) Journal of Supercritical Fluids, 14 (3), pp. 235-245. , PII S0896844698000928
dc.descriptionDe Franca, L.F., Reber, G., Meireles, M.A.A., Machado, N.T., Brunner, G., Supercritical extraction of carotenoids and lipids from buriti (Mauritia flexuosa), a fruit from the Amazon region (1999) Journal of Supercritical Fluids, 14 (3), pp. 247-256. , PII S0896844698001223
dc.descriptionDe França, L.F., Meireles, M.A.A., Modeling the extraction of carotene and lipids from pressed palm oil (Elaes guineensis) fibers using supercritical CO2 (2000) J. Supercritical Fluids, 18, pp. 35-47
dc.descriptionFerreira, S.R.S., Meireles, M.A.A., Modeling the supercritical fluid extraction of black pepper (Piper nigrum L.) essential oil (2002) J. Food Engineering, 54, pp. 263-269
dc.descriptionSilva, D.C.M.N., Bresciani, L.F.V., Dalagnol, R.L., Danielski, L., Yunes, R.A., Ferreira, S.R.S., Supercritical fluid extraction of carqueja (Baccharis trimera) oil: Process parameters and composition profiles (2009) Food and Bioproducts Processing, 87, pp. 317-326
dc.descriptionJesus, S.P., Calheiros, M.N., Hense, H., Meireles, M.A.A., A simplified model to describe the kinetic behavior of supercritical fluid extraction from rice oil byproduct (2013) Food and Public Health, 3, pp. 215-222
dc.descriptionRodrigues, V.M., Sousa, E., Monteiro, A.R., Chiavone-Filho, O., Marques, M.O.M., Meireles, M.A.A., Determination of the solubility of extracts from vegetable raw material in pressurized CO2: A pseudo-ternary mixture formed by cellulosic structure plus solute plus solvent (2002) J. Supercritical Fluids, 22, pp. 21-36
dc.descriptionLaurent, A., Lack, E., Gamse, T., Marr, R., Separation operations and equipment (2001) High Pressure Process Technology: Fundamentals and Applications, pp. 351-403. , A.V.G. Bertucco, Elsevier Amsterdam/New York
dc.descriptionGarcía-Risco, M.R., Hernández, E.J., Vicente, G., Fornari, T., Señoráns, F.J., Reglero, G., Kinetic study of pilot-scale supercritical CO2 extraction of rosemary (Rosmarinus officinalis) leaves (2011) J. Supercritical Fluids, 55, pp. 971-976
dc.descriptionRodríguez-Rojo, S., Visentin, A., Maestri, D., Cocero, M.J., Assisted extraction of rosemary antioxidants with green solvents (2012) J. Food Engineering, 109, pp. 98-103
dc.descriptionZibetti, A.W., Aydi, A., Livia, M.A., Bolzan, A., Barth, D., Solvent extraction and purification of rosmarinic acid from supercritical fluid extraction fractionation waste: Economic evaluation and scale-up (2013) J. Supercritical Fluids, 83, pp. 133-145
dc.languageen
dc.publisherElsevier
dc.relationJournal of Supercritical Fluids
dc.rightsfechado
dc.sourceScopus
dc.titleInfluence Of The Bed Geometry On The Kinetics Of Rosemary Compounds Extraction With Supercritical Co2
dc.typeArtículos de revistas


Este ítem pertenece a la siguiente institución