Artículos de revistas
On The Selection Of The State Space In Nonequilibrium Thermodynamics
Registro en:
Physica A: Statistical Mechanics And Its Applications. , v. 248, n. 1-2, p. 111 - 137, 1998.
3784371
2-s2.0-0032491745
Autor
Luzzi R.
Vasconcellos A.R.
Casas-Vazquez J.
Jou D.
Institución
Resumen
We address here the question of the choice and interpretation of state variables in the thermodynamical description of systems arbitrarily away from equilibrium. It is presented a discussion of the topic in the framework of informational statistical thermodynamics, an approach based on Gibbs algorithm for nonequilibrium dissipative systems, which provides mechano-statistical foundations to phenomenological theories of irreversible thermodynamics. The theory is applied in the case of a particular system consisting of the mobile carriers in a highly excited photo-injected plasma in semiconductors. The concepts and results thus obtained are tested against experimental data in time-resolved and time-integrated optical laser spectroscopy. It is shown how nonequilibrium thermodynamic variables are evidenced and measured in such experiments. 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