Artículos de revistas
Understanding The Formation Of The Self-assembly Of Colloidal Copper Nanoparticles By Surfactant: A Molecular Velcro
Registro en:
Journal Of Nanomaterials. , v. 2013, n. , p. - , 2013.
16874110
10.1155/2013/802174
2-s2.0-84880201031
Autor
Bortoleto-Bugs R.K.
Mazon T.
Tarozzo Biasoli M.
Pavani Filho A.
Willibrordus Swart J.
Roque Bugs M.
Institución
Resumen
Self-assembly procedure is employed to synthesize colloidal copper nanoparticles (ccNPs) with cationic surfactant in an environmentally friendly method. Scanning electron microscopy images provide a clear view of the ccNPs formed having an approximate size of 15 nm. The X-ray diffraction reveals that the ccNPs have the two types of copper oxide as well as the metallic copper. The new procedure shows that the cationic surfactant CTAB plays an important role in the understanding and development of self-assembly. There is a strong relationship between the ccNPs formation with the critical micelle concentration of the CTAB which influences both shape and size. The outcomes allowed the development of a molecular model for the ccNPs synthesis showing that the CTAB monomer on the surface has the function of a molecular velcro making the linkage of ccNPs to form an agglomerate with size around 600 nm. Finally, with the emerging new technologies, the synthesis of copper oxide takes a new perspective for their applicability in diverse integrated areas such as the flexible electronics and energy. © 2013 Raquel Kely Bortoleto-Bugs et al. 2013
Zhang, H., Shen, C., Chen, S., Xu, Z., Liu, F., Li, J., Gao, H., Morphologies and microstructures of nano-sized Cu2O particles using a cetyltrimethylammonium template (2005) Nanotechnology, 16 (2), pp. 267-272. , DOI 10.1088/0957-4484/16/2/015 Gao, D., Zhang, J., Zhu, J., Qi, J., Zhang, Z., Sui, W., Shi, H., Xue, D., Vacancy-mediated magnetism in pure copper oxide nanoparticles (2010) Nanoscale Research Letters, 5 (4), pp. 769-772. , 2-s2.0-77951937585 10.1007/s11671-010-9555-8 Poliakoff, M., Fitzpatrick, J.M., Farren, T.R., Anastas, P.T., Green chemistry: Science and politics of change (2002) Science, 297 (5582), pp. 807-810. , DOI 10.1126/science.297.5582.807 Pileni, M.P., The role of soft colloidal templates in controlling the size and shape of inorganic nanocrystals (2003) Nature Materials, 2 (3), pp. 145-150. , 2-s2.0-0037365181 10.1038/nmat817 Scott, R.W.J., Wilson, O.M., Crooks, R.M., Synthesis, characterization, and applications of dendrimer-encapsulated nanoparticles (2005) Journal of Physical Chemistry B, 109 (2), pp. 692-704. , DOI 10.1021/jp0469665 Mott, D., Galkowski, J., Wang, L., Luo, J., Zhong, C.-J., Synthesis of size-controlled and shaped copper nanoparticles (2007) Langmuir, 23 (10), pp. 5740-5745. , DOI 10.1021/la0635092 Magdassi, S., Grouchko, M., Kamyshny, A., Copper nanoparticles for printed electronics: Routes towards achieving oxidation stability (2010) Materials, 3, pp. 4626-4638 Li, X., Gao, H., Murphy, C.J., Gou, L., Nanoindentation of Cu2O nanocubes (2004) Nano Letters, 4 (10), pp. 1903-1907. , 2-s2.0-7544241260 10.1021/nl048941n Brege, J.J., Hamilton, C.E., Crouse, C.A., Barron, A.R., Ultrasmall copper nanoparticles from a hydrophobically immobilized surfactant template (2009) Nano Letters, 9 (6), pp. 2239-2242. , 2-s2.0-66749167686 10.1021/nl900080f Grzelczak, M., Vermant, J., Furst, M.E., Liz-Marzan, M.L., Directed self-assembly of nanoparticles (2010) ACS Nano, 4, pp. 3591-3605 Kelly, K.L., Coronado, E., Zhao, L.L., Schatz, G.C., The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment (2003) Journal of Physical Chemistry B, 107 (3), pp. 668-677. , 2-s2.0-0037461639 10.1021/jp026731y Huitink, D., Kundu, S., Park, C., Mallick, B., Huang, J.Z., Liang, H., Nanoparticle shape evolution identified through multivariate statistics (2010) Journal of Physical Chemistry A, 114 (17), pp. 5596-5600. , 2-s2.0-77951848180 10.1021/jp100421t Mehta, S.K., Kumar, S., Chaudhary, S., Bhasin, K.K., Gradzielski, M., Evolution of ZnS nanoparticles via facile CTAB aqueous micellar solution route: A study on controlling parameters (2009) Nanoscale Research Letters, 4 (1), pp. 17-28. , 2-s2.0-58549120823 10.1007/s11671-008-9196-3 Diaz-Droguett, D.E., Espinoza, R., Fuenzalida, V.M., Copper nanoparticles grown under hydrogen: Study of the surface oxide (2011) Applied Surface Science, 257 (10), pp. 4597-4602. , 2-s2.0-79551572018 10.1016/j.apsusc.2010.12.082 Hoa, N.D., An, S.Y., Dung, N.Q., Van Quy, N., Kim, D., Synthesis of p-type semiconducting cupric oxide thin films and their application to hydrogen detection (2010) Sensors and Actuators B, 146 (1), pp. 239-244. , 2-s2.0-77949916074 10.1016/j.snb.2010.02.045 Gou, L., Murphy, C.J., Solution-phase synthesis of Cu2O nanocubes (2003) Nano Letters, 3 (2), pp. 231-234. , DOI 10.1021/nl0258776 Yin, M., Wu, C.-K., Lou, Y., Burda, C., Koberstein, J.T., Zhu, Y., O'Brien, S., Copper oxide nanocrystals (2005) Journal of the American Chemical Society, 127 (26), pp. 9506-9511. , DOI 10.1021/ja050006u Ren, G., Hu, D., Cheng, E.W., Vargas-Reus, M.A., Reip, P., Allaker, R.P., Characterizations of copper oxide nanoparticles for antimicrobial applications (2009) International Journal of Antimicrobial Agents, 33, pp. 587-590 Li, C.-J., Trost, B.M., Green chemistry for chemical synthesis (2008) Proceedings of the National Academy of Sciences of the United States of America, 36, pp. 13197-13202 Liang, X., Gao, L., Yang, S., Sun, J., Facile synthesis and shape evolution of single-crystal cuprous oxide (2009) Advanced Materials, 21 (20), pp. 2068-2071. , 2-s2.0-66249131347 10.1002/adma.200802783 Lisiecki, I., Billoudet, F., Pileni, M.P., Control of the shape and the size of copper metallic particles (1996) Journal of Physical Chemistry, 100 (10), pp. 4160-4166 Zhang, D.W., Chen, C.H., Zhang, J., Ren, F., Novel electrochemical milling method to fabricate copper nanoparticles and nanofibers (2005) Chemistry of Materials, 17 (21), pp. 5242-5245. , DOI 10.1021/cm051584c Blosi, M., Albonetti, S., Dondi, M., Martelli, C., Baldi, G., Microwave-assisted polyol synthesis of Cu nanoparticles (2011) Journal of Nanoparticle Research, 13 (1), pp. 127-138. , 2-s2.0-79551580133 10.1007/s11051-010-0010-7 Kim, H.S., Dhage, S.R., Shim, D.E., Hahn, H.T., Intense pulsed light sintering of copper nanoink for printed electronics (2009) Applied Physics A, 97 (4), pp. 791-798. , 2-s2.0-70450237108 10.1007/s00339-009-5360-6 Ryu, J., Kim, H.S., Hahn, H.T., Reactive sintering of copper nanoparticles using intense pulsed light for printed electronics (2011) Journal of Electronic Materials, 40 (1), pp. 42-50. , 2-s2.0-78650722567 10.1007/s11664-010-1384-0 Jeong, S., Song, H.C., Lee, W.W., Lee, S.S., Choi, Y., Son, W., Kim, E.D., Ryu, B.H., Stable aqueous based Cu nanoparticle ink for printing well-defined highly conductive features on a plastic substrate (2011) Langmuir, 27 (6), pp. 3144-3149. , 2-s2.0-79952608575 10.1021/la104136w Kang, B., Han, S., Kim, J., Ko, S., Yang, M., One-step fabrication of copper electrode by laser-induced direct local reduction and agglomeration of copper oxide nanoparticles (2011) The Journal of Physical Chemistry C, 115, pp. 23664-23670 Wang, H., Shen, Q., Li, X., Liu, F., Fabrication of copper oxide dumbbell-like architectures via the hydrophobic interaction of adsorbed hydrocarbon chains (2009) Langmuir, 25 (5), pp. 3152-3158. , 2-s2.0-65249114090 10.1021/la803276z Zeng, F., Zimmerman, S.C., Dendrimers in supramolecular chemistry: From molecular recognition to self-assembly (1997) Chemical Reviews, 97 (5), pp. 1681-1712 Ganguli, A.K., Ganguly, A., Vaidya, S., Microemulsion-based synthesis of nanocrystalline materials (2010) Chemical Society Reviews, 39, pp. 474-485 Cifuentes, A., Bernal, J.L., Diez-Masa, J.C., Determination of critical micelle concentration values using capillary electrophoresis instrumentation (1997) Analytical Chemistry, 69 (20), pp. 4271-4274. , 2-s2.0-0031572719 Ottaviani, M.F., Andechaga, P., Turro, N.J., Tomalia, D.A., Model for the interactions between anionic dendrimers and cationic surfactants by means of the spin probe method (1997) Journal of Physical Chemistry B, 101 (31), pp. 6057-6065 Donners, J.J.J.M., Heywood, B.R., Meijer, E.W., Nolte, R.J.M., Roman, C., Schenning, A.P.H.J., Sommerdijk, N.A.J.M., Amorphous calcium carbonate stabilised by poly(propylene imine) dendrimers (2000) Chemical Communications, (19), pp. 1937-1938. , 2-s2.0-0034619218 Ko, S.H., Pan, H., Grigoropoulos, C.P., Luscombe, C.K., Frechet, J.M.J., Poulikakos, D., All-inkjet-printed flexible electronics fabrication on a polymer substrate by low-temperature high-resolution selective laser sintering of metal nanoparticles (2007) Nanotechnology, 18 (34), p. 345202. , DOI 10.1088/0957-4484/18/34/345202, PII S0957448407481351 Perelaer, J., Smith, P.J., Mager, D., Soltman, D., Volkman, S.K., Subramanian, V., Korvink, J.G., Schubert, U.S., Printed electronics: The challenges involved in printing devices, interconnects, and contacts based on inorganic materials (2010) Journal of Materials Chemistry, 20 (39), pp. 8446-8453. , 2-s2.0-77957765642 10.1039/c0jm00264j Han, W.-S., Hong, J.-M., Kim, H.-S., Song, Y.-W., Multi-pulsed white light sintering of printed Cu nanoinks (2011) Nanotechnology, 22. , 395705 Lin, Z., Cai, J.J., Scriven, L.E., Davis, H.T., Spherical-to-wormlike micelle transition in CTAB solutions (1994) Journal of Physical Chemistry, 98 (23), pp. 5984-5993. , 2-s2.0-33751158571 Wu, S.-H., Chen, D.-H., Synthesis of high-concentration Cu nanoparticles in aqueous CTAB solutions (2004) Journal of Colloid and Interface Science, 273 (1), pp. 165-169. , DOI 10.1016/j.jcis.2004.01.071, PII S0021979704001432 Discovery Studio Modeling Environment, Release 3.0, , San Diego, Calif, USA, 2011