Study On Determination And Removal Of Metallic Ions From Aqueous And Alcoholic Solutions Using A New Poss Adsorbent

dc.creatorVieira E.G.
dc.creatorSoares I.V.
dc.creatorPires G.
dc.creatorRamos R.A.V.
dc.creatordo Carmo D.R.
dc.creatorDias Filho N.L.
dc.date2015
dc.date2015-06-25T12:52:57Z
dc.date2015-11-26T15:06:27Z
dc.date2015-06-25T12:52:57Z
dc.date2015-11-26T15:06:27Z
dc.date.accessioned2018-03-28T22:16:55Z
dc.date.available2018-03-28T22:16:55Z
dc.identifier
dc.identifierChemical Engineering Journal. Elsevier, v. 264, n. , p. 77 - 88, 2015.
dc.identifier13858947
dc.identifier10.1016/j.cej.2014.11.050
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-84913585577&partnerID=40&md5=edeadb5c790b4e8235bb07124bdbdc79
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/85412
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/85412
dc.identifier2-s2.0-84913585577
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1257243
dc.descriptionIn this study, a new nanostructured organosilicate, named Octakis[(thiourea)propyl] octasilsesquioxane (POSS-Pr-THIO) was prepared, characterized and used for determination and removal of the ions Fe3+, Cr3+, V3+ and Zn2+ and compared with 3-[(thiourea) propyl] silica gel (SG-Pr-THIO). To the best of our knowledge, this study is the first that has reported the preparation of POSS-Pr-THIO and the comparison with its analogous SG-Pr-THIO for removal by batch and column experiments of toxics metals from natural waters, fuel ethanol and sugar-cane spirits. Langmuir and pseudo-second order models were the most appropriate to describe the adsorption and kinetic data respectively. Thermodynamic functions showed a feasible, spontaneous and endothermic process. The method of quantitative analysis of metal ions in natural waters, fuel ethanol and sugar-cane spirits by Flame AAS was validated using, namely, linearity, limit of detection, limit of quantification, and the relative standard deviation and accuracy. The results obtained in the flow of experiments in natural waters, fuel ethanol and sugar-cane spirit solutions, showed a recovery of nearly 100% of the metal ions adsorbed in a column packed with 1.0g of material, using 5mL of 1.0M HCl solution as eluent.
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dc.languageen
dc.publisherElsevier
dc.relationChemical Engineering Journal
dc.rightsfechado
dc.sourceScopus
dc.titleStudy On Determination And Removal Of Metallic Ions From Aqueous And Alcoholic Solutions Using A New Poss Adsorbent
dc.typeArtículos de revistas


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