Thermodynamic Analysis Of Autothermal Reforming Of Methane Via Entropy Maximization: Hydrogen Production

dc.creatorDe Souza T.L.
dc.creatorRossi C.D.C.R.D.S.
dc.creatorAlonso C.G.
dc.creatorGuirardello R.
dc.creatorCabral V.F.
dc.creatorFernandes-Machado N.R.C.
dc.creatorSpecchia S.
dc.creatorZabaloy M.S.
dc.creatorCardozo-Filho L.
dc.date2014
dc.date2015-06-25T18:03:46Z
dc.date2015-11-26T15:06:05Z
dc.date2015-06-25T18:03:46Z
dc.date2015-11-26T15:06:05Z
dc.date.accessioned2018-03-28T22:16:37Z
dc.date.available2018-03-28T22:16:37Z
dc.identifier
dc.identifierInternational Journal Of Hydrogen Energy. Elsevier Ltd, v. 39, n. 16, p. 8257 - 8270, 2014.
dc.identifier3603199
dc.identifier10.1016/j.ijhydene.2014.03.078
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-84900333034&partnerID=40&md5=e11413d7afdcea9693d8665b3359fa86
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/88066
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/88066
dc.identifier2-s2.0-84900333034
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1257173
dc.descriptionIn this work a thermodynamic analysis of the autothermal reforming (ATR) of methane was performed. Equilibrium calculations employing entropy maximization were performed in a wide range of oxygen to methane mole ratio (O/M), steam to methane ratio (S/M), inlet temperature (IT), and system pressure (P). The main calculated parameters were hydrogen yield, carbon monoxide formation, methane conversion, coke formation, and equilibrium temperature. Further, the optimum operating oxygen to methane feed ratio that maximizes hydrogen production, at P = 1 bar, has been calculated. The nonlinear programming problem applied to the simultaneous chemical and phase equilibrium calculation was implemented in GAMS®, using CONOPT2 solver. The maximum amount of hydrogen obtained was in the order of 3 moles of hydrogen per mole of fed methane at IT = 1000 °C, P = 1 bar, S/M = 5, and O/M = 0.18. Experimental literature data are in good agreement with calculation results obtained through proposed methodology. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
dc.description39
dc.description16
dc.description8257
dc.description8270
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dc.languageen
dc.publisherElsevier Ltd
dc.relationInternational Journal of Hydrogen Energy
dc.rightsfechado
dc.sourceScopus
dc.titleThermodynamic Analysis Of Autothermal Reforming Of Methane Via Entropy Maximization: Hydrogen Production
dc.typeActas de congresos


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