The Mechanism Of Tröger's Base Formation Probed By Electrospray Ionization Mass Spectrometry

dc.creatorAbella C.A.M.
dc.creatorBenassi M.
dc.creatorSantos L.S.
dc.creatorEberlin M.N.
dc.creatorCoelho F.
dc.date2007
dc.date2015-06-30T18:37:23Z
dc.date2015-11-26T15:01:26Z
dc.date2015-06-30T18:37:23Z
dc.date2015-11-26T15:01:26Z
dc.date.accessioned2018-03-28T22:12:28Z
dc.date.available2018-03-28T22:12:28Z
dc.identifier
dc.identifierJournal Of Organic Chemistry. , v. 72, n. 11, p. 4048 - 4054, 2007.
dc.identifier223263
dc.identifier10.1021/jo062556w
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-34249796694&partnerID=40&md5=93344b4d2b4fa435cc4bfca7f17cdb66
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/104034
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/104034
dc.identifier2-s2.0-34249796694
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1256280
dc.description(Chemical Equation Presented) Using direct infusion electrospray ionization mass and tandem mass spectrometric experiments [ESI-MS(/MS)], we have performed on-line monitoring of some reactions used to form Tröger's bases. Key intermediates, either as cationic species or as protonated forms of neutral species, have been intercepted and characterized. The role of urotropine as the methylene source in these reactions has also been accessed. Reaction pathways shown by ESI-MS(/MS) have been probed by gas-phase ion/molecule reactions, and an expanded mechanism for Tröger's base formation based on the mass spectrometric data has been elaborated. © 2007 American Chemical Society.
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dc.description4048
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dc.languageen
dc.publisher
dc.relationJournal of Organic Chemistry
dc.rightsfechado
dc.sourceScopus
dc.titleThe Mechanism Of Tröger's Base Formation Probed By Electrospray Ionization Mass Spectrometry
dc.typeArtículos de revistas


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