Msn Of The Six Isomers Of (glcn)2(glcnac)2 Aminoglucan Tetrasaccharides (diacetylchitotetraoses): Rules Of Fragmentation For The Sodiated Molecules And Application To Sequence Analysis Of Hetero-chitooligosaccharides

dc.creatorVijayakrishnan B.
dc.creatorIssaree A.
dc.creatorCorilo Y.E.
dc.creatorFerreira C.R.
dc.creatorEberlin M.N.
dc.creatorPeter M.G.
dc.date2011
dc.date2015-06-30T20:37:33Z
dc.date2015-11-26T14:52:14Z
dc.date2015-06-30T20:37:33Z
dc.date2015-11-26T14:52:14Z
dc.date.accessioned2018-03-28T22:04:17Z
dc.date.available2018-03-28T22:04:17Z
dc.identifier
dc.identifierCarbohydrate Polymers. , v. 84, n. 2, p. 713 - 726, 2011.
dc.identifier1448617
dc.identifier10.1016/j.carbpol.2010.04.041
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-79951509919&partnerID=40&md5=95c9f49105ad54d2f2422f0f5f6272ca
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/108677
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/108677
dc.identifier2-s2.0-79951509919
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1254780
dc.descriptionThe six possible isomers of di-N-acetylchitotetraoses [AADD, ADDA, ADAD, DADA, DAAD, and DDAA, where D stands for 2-amino-2-deoxy-β-d-glucose (GlcN) and A for 2-acetamido-2-deoxy-β-d-glucose (GlcNAc)] were analyzed by ESI(+)-MSn. Collision induced dissociation via MSn experiments were performed for the sodiated molecules of m/z 769 [M+Na] + for each isomer, and fragments were generated mainly by glycosidic bond and cross-ring cleavages. Rules of fragmentation were then established. A reducing end D residue yields the O,2A4 cross-ring [M-59+Na]+ fragment of m/z 710 as the most abundant, whereas isomers containing a reducing end A prefer to lose water to form the [M-18+Na] + ion of m/z 751, as well as abundant O,2A4 cross-ring [M-101+Na]+ fragments of m/z 668 and B3 [M-221+Na]+ ions of m/z 548. MS3 of C- and Y-type ions shows analogous fragmentation behaviour that allows identification of the reducing end next-neighbour residue. Due to gas-phase anchimeric assistance, B-type cleavage between the glycosidic oxygen and the anomeric carbon atom is favoured when the glycon is an A residue. Relative ion abundances are generally in the order B ≫ C > Y, but may vary depending on the next neighbour towards the non-reducing end. These fragmentation rules were used for partial sequence analysis of hetero-chitooligosaccharides of the composition D 2A3, D3A3, D2A 4, D4A3, and D3A4. © 2011 Elsevier Ltd. All rights reserved.
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dc.languageen
dc.publisher
dc.relationCarbohydrate Polymers
dc.rightsfechado
dc.sourceScopus
dc.titleMsn Of The Six Isomers Of (glcn)2(glcnac)2 Aminoglucan Tetrasaccharides (diacetylchitotetraoses): Rules Of Fragmentation For The Sodiated Molecules And Application To Sequence Analysis Of Hetero-chitooligosaccharides
dc.typeActas de congresos


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