Synthesis Of Manganese Porphyrinosilica Imprinted With Templates Using The Sol-gel Process

dc.creatorSacco H.C.
dc.creatorCiuffi K.J.
dc.creatorBiazzotto J.C.
dc.creatorZuccki M.R.
dc.creatorLeite C.A.P.
dc.creatorNascimento O.R.
dc.creatorSerra O.A.
dc.creatorIamamoto Y.
dc.date2000
dc.date2015-06-30T19:52:22Z
dc.date2015-11-26T14:47:38Z
dc.date2015-06-30T19:52:22Z
dc.date2015-11-26T14:47:38Z
dc.date.accessioned2018-03-28T21:58:12Z
dc.date.available2018-03-28T21:58:12Z
dc.identifier
dc.identifierJournal Of Non-crystalline Solids. , v. 273, n. 01/03/15, p. 150 - 158, 2000.
dc.identifier223093
dc.identifier
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0000244153&partnerID=40&md5=5e7411cabf6be2423ca59df4ac1346fb
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/107425
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/107425
dc.identifier2-s2.0-0000244153
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1253365
dc.descriptionThe optimized conditions for the preparation of a new manganese porphyrinosilica-template material are reported. The manganese porphyrinosilica-template was prepared by the sol-gel process, by the reaction of -SO2Cl groups present in the phenyl rings of MnTDC(SO2Cl)PPCl with 3-aminopropyltriethoxysilane. The reaction produces a precursor porphyrinopropylsilyl species, which were then polymerized with tetraethoxysilane. The presence of manganese porphyrin on xerogel is confirmed by ultraviolet visible absorption spectroscopy and thermogravimetric analysis (TGA). The prepared materials have surface areas between 19 and 674 m2 g-1. Electron spectroscopy imaging of the materials show that manganese distribution in the xerogel is uniform. Both manganese(III) porphyrinosilica-template and a similar iron(III) porphyrinosilica-template can catalyze the epoxidation of cyclooctene using iodozylbenzene as oxygen donor. The metalloporphyrinosilica-template presents catalytic activity similar to that of metaloporphyrin in solution. © 2000 Elsevier Science B.V. All rights reserved.
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dc.languageen
dc.publisher
dc.relationJournal of Non-Crystalline Solids
dc.rightsfechado
dc.sourceScopus
dc.titleSynthesis Of Manganese Porphyrinosilica Imprinted With Templates Using The Sol-gel Process
dc.typeArtículos de revistas


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