Statistically Designed Study Of Ternary Electrolyte Polymer Material (peo/liclo4/ethylene Carbonate)

dc.creatorSilva G.G.
dc.creatorMarzana B.E.
dc.creatorBruns R.E.
dc.date2000
dc.date2015-06-30T19:52:14Z
dc.date2015-11-26T14:47:35Z
dc.date2015-06-30T19:52:14Z
dc.date2015-11-26T14:47:35Z
dc.date.accessioned2018-03-28T21:58:06Z
dc.date.available2018-03-28T21:58:06Z
dc.identifier
dc.identifierJournal Of Materials Science. Kluwer Academic Publishers, Dordrecht, Netherlands, v. 35, n. 18, p. 4721 - 4728, 2000.
dc.identifier222461
dc.identifier10.1023/A:1004807224486
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0034270727&partnerID=40&md5=c1c7984499d5ceb20a9bba7abd848269
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/107412
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/107412
dc.identifier2-s2.0-0034270727
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1253345
dc.descriptionStatistically designed mixture experiments were performed for the ternary electrolyte polymer system poly(ethylene oxide) (PEO) - lithium perchlorate - ethylene carbonate (EC). Ionic conductivities and crystalline/glass transition temperatures were measured for 15 ternary mixtures of varying ingredient proportions. Although conductivity increases with salt concentration, the plasticizer/polymer ratio is important in determining conductivities at higher salt proportions. A quadratic mixture model provides an accurate description of how conductivity at room temperature changes with varying ingredient proportions. It predicts a maximum conductivity for a 0.50 PEO, 0.21 LiClO4, 0.29 EC (weight fractions) mixture. A special cubic model is found to be most appropriate for representing how the corrected transition temperature values depend on ingredient proportions. The temperature dependence of conductivity was measured for some of the mixtures. The same composition exhibited higher conductivities at room temperature and up to 100 °C. The VTF parameters for the plasticized systems were compared with those of non-plasticized ones.
dc.description35
dc.description18
dc.description4721
dc.description4728
dc.descriptionArmand, M., (1994) Solid State Ionics, 69, p. 309
dc.descriptionGray, F.M., (1991) Solid Polymer Electrolytes, , VCH, Cambridge
dc.descriptionMeyer, W.H., (1998) Advanced Materials, 10 (6), p. 439
dc.descriptionKelly, I.E., Owen, J.R., Steele, B.C.H., (1984) J. Electroanal. Chem., 168, p. 467
dc.descriptionGorecki, M., Andreani, R., Berthier, C., Armand, M.B., Mali, M., Roos, J., Brinkmann, D., (1986) Solid State Ionics, 18, p. 295
dc.descriptionMacfarlane, D.R., Sun, J., Meakin, P., Fasoulopoulos, P., Hey, J., Forsyth, M., (1995) Electrochim. Acta, 40 (13-14), p. 2131
dc.descriptionHuq, R., Koksbang, R., Tonder, P.E., Farrington, G.C., (1992) Electrochim. Acta, 37 (9), p. 1681
dc.descriptionYang, X.Q., Lee, H.S., Hanson, L., Mcbreen, J., Okamoto, Y., (1995) J. of Power Sources, 54, p. 198
dc.descriptionChintapalli, S., Frech, R., (1996) Macromolecules, 29, p. 3499
dc.descriptionReiche, A., Steurich, T., Sandner, B., Lobitz, P., Fleischer, G., (1995) Electrochim. Acta, 40, p. 2153
dc.descriptionGozdz, A.S., Tarascon, J.M., Warren, P.C., Schmutz, C.N., Shokoohi, F.K., (1996) Proc. of the Fifth Int. Symp. on Pol. Electrolytes, , Sweeden, Paper O-12
dc.descriptionQuartarone, E., Tomasi, C., Mustarelli, P., Appetecchi, G.B., Croce, F., (1998) Electrochim. Acta, 43 (10-11), p. 1435
dc.descriptionHuang, B., Wang, Z., Li, Q., Huang, H., Xue, R., Chen, L., Wang, F., (1996) Solid State Ionics, 85, p. 79
dc.descriptionGray, F., (1997) Polymer Electrolytes, , RSC Materials Monographs, Royal Society of Chemistry, Cambridge
dc.descriptionValee, A., Besner, S., PruD' Homme, J., (1992) Electrochim. Acta, 37, p. 1579
dc.descriptionGoulart Silva, G., Lemes, N.H.T., Polo Da Fonseca, C.N., De Paoli, M.-A., (1997) Solid State Ionics, 93, p. 105
dc.descriptionTorrel, L.M., Schantz, S., (1989) Polymer Electrolyte Reviews - 2, 2. , edited by J. MacCallum and C. A. Vincent Elsevier, New York
dc.descriptionSilva, R.A., Goulart Silva, G., Pimenta, M.A., Appl. Phys. Lett., 67 (22), p. 3352
dc.descriptionForsyth, M., Meakin, P., Macfarlane, D.R., Hill, A.J., (1995) J. Phys.: Condens. Matter, 7, p. 7601
dc.descriptionBishop, A.G., Macfarlane, D.R., Mcnaughton, D., Forsyth, M., (1996) Solid State Ionics, 85, p. 129
dc.descriptionNg, S.T.C., Jollife, C., Goodwin, A., Forsyth, M., Macfarlane, D.R., (1998) Electrochim. Acta, 43 (10-11), p. 1499
dc.descriptionForsyth, M., Garcia, M., Macfarlane, D.R., Meakin, P., Ng, S., Smith, M.E., (1996) Solid State Ionics, 85, p. 209
dc.descriptionHill, A.J., Macfarlane, D.R., Li, J., Jones, P.L., Forsyth, M., (1998) Electrochim. Acta, 43 (10-11), p. 1481
dc.descriptionClericuzio, M., Parker W.O., Jr., Soprani, M., Andrei, M., (1995) Solid State Ionics, 82, p. 179
dc.descriptionBandara, L.R.A.K., Dissanayake, M.A.K.L., Mellander, B.-E., (1998) Electrochim. Acta, 43 (10-11), p. 1447
dc.descriptionMarzana, B.G.E., De Souza, P.P., Goulart Silva, G., Bruns, R.E., (1997) Proc. of 20th Annual Meeting of Sociedade Brasileira de Química, , QM 075
dc.descriptionRobitaille, C.D., Fauteux, D., (1986) J. Electrochim. Soc., 133, p. 315
dc.descriptionCornell, J.A., (1990) Experiments with Mixtures,2nd Ed., , Wiley, New York
dc.descriptionBox, G.E.P., Hunter, W.G., Hunter, J.S., (1978) Statistics for Experimenters, , Wiley, New York
dc.descriptionDe Barros Neto, B., Scarminio, I.S., Bruns, R.E., (1995) Planejamento e Otimização de Experimentos, , Editora da Unicamp, Campinas,SP, Brazil
dc.descriptionPiepel, G., Redgate, T., (1997) J. Am. Ceram. Soc., 80, p. 3038
dc.descriptionPiepel, G., Redgate, T., Masuga, P., (1997) Glass Technol., 38, p. 210
dc.descriptionVojnovic, D., Campisi, B., Mattei, A., Favretto, L., (1995) Chemom. Intell. Lab. Syst., 27, p. 205
dc.descriptionWegscheider, W., Walner, V., (1993) Chemom. Intell. Lab. Syst., 19, p. 169
dc.descriptionBruns, R.E., De Andrade, J.C., Reis, C., Nakai, D., (1996) Chemom. Intell. Lab. Syst., 33, p. 159
dc.descriptionReis, C., De Andrade, J.C., Bruns, R.E., Moran, R.C.C.P., (1997) Anal. Chim. Acta, 369, p. 269
dc.descriptionVogel, H., (1921) Phys. Z., 22, p. 645
dc.descriptionTamman, G., Hesse, W., (1926) Z. Anorg. All. Chem., 156, p. 245
dc.descriptionFulcher, G.S., (1925) J. Am. Ceram. Soc., 8, p. 339
dc.descriptionSouquet, J.L., Duclot, M., Levy, M., (1996) Solid State Ionics, 85, p. 149
dc.descriptionFurtado, C.A., Goulart Silva, G., Machado, J.C., Pimenta, M.A., Silva, R.A., (1999) J. Phys. Chem., 34-103, p. 7102
dc.descriptionHubbard, H.V.St.A., Southall, J.P., Cruickshank, J.M., Davies, G.R., Ward, I.M., (1998) Electrochim. Acta, 43 (10-11), p. 1485
dc.languageen
dc.publisherKluwer Academic Publishers, Dordrecht, Netherlands
dc.relationJournal of Materials Science
dc.rightsfechado
dc.sourceScopus
dc.titleStatistically Designed Study Of Ternary Electrolyte Polymer Material (peo/liclo4/ethylene Carbonate)
dc.typeArtículos de revistas


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