Artículos de revistas
Physicochemical Properties Related To The Development Of Nation ® Membranes For Application In Fuel Cells [propriedades Físico-químicas Relacionadas Ao Desenvolvimento De Membranas De Nation ® Para Aplicações Em Células A Combustível Do Tipo Pemfc]
Registro en:
Polimeros. , v. 18, n. 4, p. 281 - 288, 2008.
1041428
2-s2.0-61349089767
Autor
Perles C.E.
Institución
Resumen
Fuel Cells (FC) continue to receive growing attention, in spite of not being a new technology, for they are considered as the "energy source of the future" owing to characteristics such as high energetic yield and low emission of pollutants. FC technology may lead to a reduction in the negative impact from energy sources on the enviroment, thus improving the quality of life and extending the lifetime of fossil combustible reserves. The mainstream of research in FC is now directed at mobile, portable systems, for which the most promising technology is the Polymer Electrolyte Fuel Cells, also known as PEMFC (Polymer Electrolyte Fuel Cell). Research in this topic focuses on the development of polymer membranes whose target is to reduce its production costs. In this work we shall focus on physicochemical aspects related to development of polymeric membranes. A discussion on structural aspects of Nation ® will be carried, which will be related to the following physicochemical properties: electrosmotic flux, gaseous permeability, water transport through polimeric membrane, chemical and thermal stabilities. All the discussion was made using Nation ® as model of perfluorated polymers. 18 4 281 288 Zink, F. Lu, Y. Schaefer, L. & Schefer, L. - Energy Convers. Manage, 48, p. 809-818 (2007)Blomen, L.J.M.J., Mugerwa, M.N., (1993) Fuel Cell Systems, , Plenum Press, New York DoITPoms (Dissemination of information technology for the Promotion of Materials Science), University of Cambridge, site: http://www.doitpoms.ac.uk/ tlplib/fuel-cells/history.php, acessed in 30 th May 2007Meier-Haack, J. Taeger, A. Vogel, C. Schlenstedt, K. Lenk, W. & Lehmann, D. - Sep. Purif. Technol.., 41, p. 207-220 (2005)Hartmut, W. Linardi, M. & Aricó, R. M. - Quím. Nova, 25, p. 470-476 (2002)Amado, R.S., Malta, L.F.B., Garrido, F.M.S., Medeiros, M.E., (2007) Quím. Nova, 30, pp. 189-197 Lister, S., McLean, G., (2004) J. Power Sources, 130, pp. 61-76 Smitha, B. Sridhar, S. & Khan, A. A. - J. Membr. Sci., 259, p. 10-26 (2005)Carrette, L. Friedrich, K. A. & Stimming, U. - ChemPhys- Chem, 1, p. 162-193 (2000)Kreuer, K. D. Paddison, S. J. Spohr, E. & Schuster, M. - Chem. Rev., 104, p. 4637-4678 (2004)Mauritz, K.A., Moore, R.B., (2004) Chem. Rev, 104, pp. 4535-4585 Biyikoglu, A., (2005) Int. J. Hydrogen Energy, 30, pp. 1181-1212 Matsuura, T. Kato, M. & Hori, M. - J. Power Sources, 161, p. 74-78 (2006)Oh, M. H. Yoon, Y. S. & Park, S. G. - Electrochim. Acta., 50, p. 777-780 (2004)Kuan, H. C. Ma, C. C. M. Chen, K. H. & Chen, S. M. - J. Power Sources, 134, p. 7-17 (2004)Hornung, R., Kappelt, G., (1998) J. Power Sources, 72, pp. 20-21 Wee, J.H., (2006) J. Power Sources, 161, pp. 1-10 Jiang, L. H. Sun, G. Q. Wang, S. L. Wang, G. X. Xin, Q. Zhou, Z. H. & Zhou, B. - Electrochem. Commun, 7, p. 663-668 (2005)Wee, J. H. Song, D. J. Jun, C. S. Lin, T. H. Hong, S. A. Lim, H. C. & Lim, K. Y - J. Alloys Compd, 390, p. 155-160 (2005)Antolini, E., (2004) J. Appl. Electrochem, 34, pp. 563-576 Ren, X.M., Gottesfeld, S., (2001) J. Electrochem. Soc, 148, pp. A87-A93 Vishnyakov, V.M., (2006) Vacuum, 80, pp. 1053-1065 Zawodzinski, T. A. Springer, T. E. Davey, J. Jestel, R. Lopez, C. Valerio, J. & Gottesfeld, S. - J. Electrochem. Soc., 140, p. 1981-1985 (1993)Jannasch, P., (2003) Curr. Opin. Colloid Interface Sci, 8, pp. 96-102 Chou, J. McFarland, E. W. & Metiu, H. - J. Phys. Chem. B., 109, p. 3252-3256 (2005)Choi, P. Jalani, N. H. & Datta, R. - J. Electrochem. Soc., 152, p. E123-E130 (2005)Janssen, G.J.M., (2001) J. Electrochem. Soc, 148, pp. A1313-A1323 Kreuer, K. D. Rabenau, A. & Weppner, W. - Angew. Chem., Int. Ed., 21, p. 208-209 (1982)Pivovar, B., (2006) Polymer, 47, pp. 4194-4202 Costamagna, P., Srinivasan, S., (2001) J. Power Sources, 102, pp. 253-269 Zawodzinski, T. A. Neeman, M. Sillerud, L. O. & Gottesfel, S. - J. Phys. Chem., 95, p. 6040-6044 (1991)Ise, M. Kreuer, K. D. & Maier, J. - Solid State Ionics, 125, p. 213-223 (1999)Zawodzinski, T. A. Davey, J. Valerio, J. & Gottesfeld, S. - Electrochim. Acta, 40, p. 297-302 (2006)Kreuer, K.D., (1997) Solid State Ionics, 97, pp. 1-15 Watanabe, M. Uchida, H. Seki, Y. Emori, M. & Stonehart, P. - J. Electrochem. Soc., 143, p. 3847-3852 (1996)Ogumi, Z. Kuroe, T. & Takehara, Z. - J. Electrochem. Soc., 132, p. 2601-2605 (1985)Sakai, T. Takenaka, H. Wakabayashi, N. Kawami, Y. & Torikae, E. - J. Electrochem. Soc., 132, p. 1328-1332 (1985)Yeager, H.L., Steck, A., (1981) J. Electrochem. Soc, 128, pp. 1880-1884 Falk, M., (1980) Can. J. Chem.-Rev. Can. Chim, 58, pp. 1495-1501 Broka, K., Ekdunge, P., (1997) J. Appl. Electrochem, 27, pp. 117-123 Curtin, D. E. Lousenberg, R. D. Henry, T. J. Tangeman, P. C. & Tisak, M. E. - J. Power Sources, 131, p. 41-48 (2004)Samms, S. R. Wasmus, S. & Savinell, R.F. - J. Electrochem. Soc., 143, p. 1498-1504 (1996)Surowiec, J., Bogoczek, R., (1988) J. Therm. Anal, 33, pp. 1097-1102 Wilkie, C. A. Thomsen, J. R. & Mittleman, M. L. - J. Appl. Polym. Sci., 42, p. 901-909 (1991)Lage, L. G. Delgado, P. G. & Kawano, Y - J. Therm. Anal. Calorim., 175, p. 521-530 (2004)