Axial/equatorial Proportions For 2-substituted Cyclohexanones

dc.creatorBasso E.A.
dc.creatorKaiser C.
dc.creatorRittner R.
dc.creatorLambert J.B.
dc.date1993
dc.date2015-06-30T14:37:24Z
dc.date2015-11-26T14:44:15Z
dc.date2015-06-30T14:37:24Z
dc.date2015-11-26T14:44:15Z
dc.date.accessioned2018-03-28T21:52:56Z
dc.date.available2018-03-28T21:52:56Z
dc.identifier
dc.identifierJournal Of Organic Chemistry. , v. 58, n. 27, p. 7865 - 7869, 1993.
dc.identifier223263
dc.identifier
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0027761903&partnerID=40&md5=2bdcafcba9c4dfcc68f252ddfbbb32fe
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/99927
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/99927
dc.identifier2-s2.0-0027761903
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1252049
dc.descriptionAxial-equatorial conformational proportions have been measured for 2-substituted cyclohexanones in chloroform by the Eliel method for F, Cl, Br, I, MeO, MeS, Me2N, MeSe, and Me. For the first seven of these, at least five experimentally independent measurables were used and the resulting conformational preferences appear to be accurate to within 10%. Systematic errors degraded the results for MeSe and Me. For Me2N, the conformational preference also was measured for the first time at slow exchange in the low-temperature 13C spectrum in several solvents. In chloroform, steric and polar effects contribute to the conformational preferences, with steric effects dominant for large groups such as I and MeS. © 1993 American Chemical Society.
dc.description58
dc.description27
dc.description7865
dc.description7869
dc.languageen
dc.publisher
dc.relationJournal of Organic Chemistry
dc.rightsfechado
dc.sourceScopus
dc.titleAxial/equatorial Proportions For 2-substituted Cyclohexanones
dc.typeArtículos de revistas


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