| dc.creator | dos Santos L.C.R. | |
| dc.creator | de Oliveira S.F. | |
| dc.creator | Espinola J.G.P. | |
| dc.creator | Airoldi C. | |
| dc.date | 1993 | |
| dc.date | 2015-06-30T14:35:47Z | |
| dc.date | 2015-11-26T14:44:14Z | |
| dc.date | 2015-06-30T14:35:47Z | |
| dc.date | 2015-11-26T14:44:14Z | |
| dc.date.accessioned | 2018-03-28T21:52:54Z | |
| dc.date.available | 2018-03-28T21:52:54Z | |
| dc.identifier | | |
| dc.identifier | The Journal Of Chemical Thermodynamics. , v. 25, n. 11, p. 1319 - 1324, 1993. | |
| dc.identifier | 219614 | |
| dc.identifier | 10.1006/jcht.1993.1132 | |
| dc.identifier | http://www.scopus.com/inward/record.url?eid=2-s2.0-0004381748&partnerID=40&md5=e4b0c19be83e14666095f4219b6c4f24 | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/99913 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/99913 | |
| dc.identifier | 2-s2.0-0004381748 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1252038 | |
| dc.description | The new adducts MI 3·L (M = Sb or Bi; L = N,N -dimethylthioacetamide (dmta) or N,N-dimethylthioformamide (dmtf), were isolated, characterized, and studied through reaction-solution calorimetry at the temperature 298.15 K: MI 3(cr)+L(l, cr) = MI 3·L(cr); Δ rH o m(kJ·mol -1) : SbI 3·dmta, -10.58±0.14; SbI 3·dmtf, -14.90±0.14; BiI 3·dmta, -9.96±0.29; and BiI 3·dmtf, -15.19±0.41. Using Δ rH o m and the standard molar enthalpies of formation of ligands and triiodides, the standard molar enthalpies of formation of the crystalline thioamide adducts were calculated; their values for this sequence are: (-177.6, -131.3, -226.6, and -181.2) kJ·mol -1. The mean metal-sulphur bond enthalpies for the same sequence: (112, 117, 144, and 150) kJ·mol -1, were also calculated. © 1993 Academic Press. All rights reserved. | |
| dc.description | 25 | |
| dc.description | 11 | |
| dc.description | 1319 | |
| dc.description | 1324 | |
| dc.language | en | |
| dc.publisher | | |
| dc.relation | The Journal of Chemical Thermodynamics | |
| dc.rights | fechado | |
| dc.source | Scopus | |
| dc.title | Thermochemistry Of Adducts Of N,n-dimethylthioacetamide And Of N,n-dimethylthioformamide With Antimony Triiodide Or Bismuth Triiodide At The Temperature 298.15 K | |
| dc.type | Artículos de revistas | |
