Artículos de revistas
Physicochemical Properties Of Interesterified Blends Of Fully Hydrogenated Crambe Abyssinica Oil And Soybean Oil
Registro en:
Jaocs, Journal Of The American Oil Chemists' Society. , v. 91, n. 1, p. 111 - 123, 2014.
0003021X
10.1007/s11746-013-2360-7
2-s2.0-84892496991
Autor
Guedes A.M.M.
Ming C.C.
Ribeiro A.P.B.
Da Silva R.C.
Gioielli L.A.
Goncalves L.A.G.
Institución
Resumen
The chemical interesterification of blends of soybean (SO) and fully hydrogenated crambe oil (FHCO) in the ratios of 80:20, 75:25, 70:30, 65:35, and 60:40 (w/ w), respectively, was investigated. FHCO is a source of behenic acid. The blends and the interesterified fats were analyzed for fatty acid and triacylglycerol composition, regiospecific distribution, slip melting point, solid profile, and consistency. The regiospecific analysis of the TAG indicated random insertion of saturated fatty acids at sn-2 of the glycerol of the interesterified blends with more significant alterations at sn-2 than at sn-1 and sn-3. The gradual addition of FHCO increased the solid fat content and the slip melting point. The chemical interesterification formed new TAG facilitating the miscibility between SO and FHCO. The 70:30 interesterified blend was suitable for general use, 60:40 for use as a base stock. At 35 °C, the 65:35 interesterified blend showed suitable plasticity for use in products with fat contents below 80 %. FHCO, rich in behenic acid, is not associated with increased total cholesterol and LDL cholesterol, and it can be used as a low trans fat. FHCO is not associated with increased total cholesterol and LDL cholesterol, and it can be used as a low trans fat alternative. © AOCS 2013. 91 1 111 123 O'Brien, R.D., (2004) Fats and Oils: Formulating and Processing for Applications, , CRC Press, New York DeMan, J.N., DeMan, L., Texture of fats (2002) Physical Properties of Lipids, , In: Marangoni AG, Narine SS (eds), CRC Press, New York http://www.ienica.net/crops/crambe.pdf, Interactive European Network for Industrial crops and their applications (Accessed February 2011) CRAMBE Abyssinian mustard. http://www.ienica.net/crops/ crambe.pdfGunstone, F., (1999) Fatty acid and lipid chemistry, , Aspen, Gaithersburg Grimaldi, R., Gonçalves, L.A.G., Ando, M.Y., Otimizaçaão da reaçaão de interesterificação química de óleo de palma (2005) Quím Nova, 28, pp. 633-636 Hartman, L., Lago, R.C.A., Rapid preparation of fatty methyl esters from lipids (1973) Lab Practice, 22, pp. 475-477 (2009) Official Methods and Recommended Practices of the AOCS, , American Oil Chemists Society, AOCS Press, Champaign Antoniosi Filho, N., Mendes, O.L., Lanças, F.M., Computer perdition of triacylglycerol 8 composition of vegetable oils by HRGC (1995) Chromatographia, 40, pp. 557-562 Vlahov, G., Regiospecific analysis of natural mixtures of triglycerides using quantitative 13C nuclear magnetic resonance of acyl chain carbonyl carbons (1998) Magn Reson Chem, 36, pp. 359-362 Márquez-Ruiz, G., Jorge, N., Martín-Polvillo, M., Dobarganes, M.C., Rapid, quantitative determination of polar compounds in fats and oils by solid-phase extraction and size-exclusion chromatography using monostearin an internal standard (1996) J Chromat, 749, pp. 55-60 Braipson-Danthine, S., Deroanne, C., Influence of SFC, microstructure and polymorphism on texture (hardness) of binary blends of fats involved in the preparation of industrial shortenings (2004) Food Res Int, 37, pp. 941-948 Goh, E.M., Ker, T.H., Relationship between slip melting point and pulsed NMR data of palm kernel oil (1991) J Am Oil Chem Soc, 68, pp. 144-146 Ribeiro, A.P.B., Grimaldi, R., Gioielli, L.A., Gonçalves, L.A.G., Zero trans fats from soybean oil and fully hydrogenated soybean oil: Physico-chemical properties and food applications (2009) Food Res Int, 42, pp. 401-410 Haighton, A.J., The measurement of the hardness of margarine and fats with cone penetrometers (1959) J Am Oil Chem Soc, 36, pp. 345-348 Vargas-Lopes, J.M., Wiesenborn, D., Tostenson, K., Cihacek, L., Processing of crambe for oil and isolation of erucic acid (1999) J Am Oil Chem Soc, 76, pp. 801-809 Kojima, M., Tachibana, N., Yamahira, T., Seino, S., Izumisawa, A., Sagi, N., Arishima, T., Ikeda, I., Structured triacylglycerol containing behenic and oleic acids suppresses triacylglycerol absorption and prevents obesity in rats (2010) Lipids Health Dis, 9, p. 77 Karupaiaha, T., Noora, M.I., Sundram, K., Dietary fatty acids and their influence on blood lipids and lipoproteins (2005) Healthful Lipids, , In: Akoh CC, Lai OM (eds), AOCS Press, Champaign Siew, W.L., Ng, W.L., Influence of diglycerides on crystallization of palm oil (1999) J Sci Food Agric, 79, pp. 722-726 Ramamurthi, S., McCurdy, A.R., Interesterification-current status and future prospects (1995) Development and Processing of Vegetable Oils for Human Nutrition, , In: Przybylski R, McDonald BE (eds), AOCS Press, Champaign Akoh, C.C., Fat-based fat substitutes (2008) Fatty Acids in Foods and Their Health Iimplications, , In: Chow CK (ed), 3rd edn. CRC Press, Boca Ratón Rousseau, D.R., Marangoni, A.G., The effects of interesterification on the physical properties of fats (2002) Physical Properties of Lipids, , In: Marangoni AG, Narine S (eds), CRC Press, New York Woerfel, J.B., Formulation of soy oil products (1995) Grasas Aceites, 46, pp. 357-365 Krawczyk, G.R., Buliga, G.S., Bertrand, D.T., Humphreys, W.M., Reviewing the technology of low fat spreads (1996) Inform, 7, pp. 635-639 Petrauskaite, V., De Greyt, W., Kellens, M., Huyghebaert, A., Physical and chemical properties of trans-free fats produced by chemical interesterification of vegetable oil blends (1998) J Am Oil Chem Soc, 75, pp. 489-493 Silva, R.C., Soares, D.F., Lourenço, M.B., Soares, F.A.S.M., Silva, K.G., Gonçalves, M.I.A., Gioielli, L.A., Structured lipids obtained bychemical interesterification of olive oil and palm stearin (2010) Food Sci Technol, 43, pp. 752-758 Lambelet, P., Raemy, A., Iso-solid diagrams of fat blends from thermal analysis data (1983) Food Sci Technol, 60, pp. 845-847 Traitler, H., Dieffenbacher, A., Palm oil and palm kernel oil in food products (1985) Food Sci Technol, 61, pp. 417-421 Bach, M., Juul, B., (2007) Non-Lauric, Non-Trans, Non-Temper Fat Compositions, 7 (309), p. 508. , U.S. Patent