| dc.creator | Badshah S. | |
| dc.creator | Airoldi C. | |
| dc.date | 2014 | |
| dc.date | 2015-06-25T17:56:02Z | |
| dc.date | 2015-11-26T14:42:26Z | |
| dc.date | 2015-06-25T17:56:02Z | |
| dc.date | 2015-11-26T14:42:26Z | |
| dc.date.accessioned | 2018-03-28T21:50:02Z | |
| dc.date.available | 2018-03-28T21:50:02Z | |
| dc.identifier | | |
| dc.identifier | Journal Of Environmental Chemical Engineering. Elsevier Ltd, v. 2, n. 3, p. 1386 - 1393, 2014. | |
| dc.identifier | 22133437 | |
| dc.identifier | 10.1016/j.jece.2014.03.010 | |
| dc.identifier | http://www.scopus.com/inward/record.url?eid=2-s2.0-84905587880&partnerID=40&md5=d16497bfa4825933a2c51f535a4ceeaa | |
| dc.identifier | http://www.repositorio.unicamp.br/handle/REPOSIP/86946 | |
| dc.identifier | http://repositorio.unicamp.br/jspui/handle/REPOSIP/86946 | |
| dc.identifier | 2-s2.0-84905587880 | |
| dc.identifier.uri | http://repositorioslatinoamericanos.uchile.cl/handle/2250/1251272 | |
| dc.description | A lamellar inorganic-organic talc-like magnesium phyllosilicate has been synthesized through a single step sol-gel route under mild conditions, using a newly synthesized [3-(3-trimethoxysilylpropyl)thiopropanamide] silylating agent, obtained from acrylamine and 3-mercaptopropyltrimethoxysilane. Elemental analysis data based on the sulfur atom showed an incorporation of 3.66 mmol g-1 of the thiopropanamide group inside the galleries of the hybrid. Infrared spectroscopy and nuclear magnetic resonance (NMR) in the solid state for the 13C nucleus confirmed the thiopropanamide moiety covalently bonded inside the lamellar structural galleries. Solid state 29Si NMR showed the presence of Tn silicon species in the backbone in agreement to the hydrolysis and condensation reactions during the sol-gel process. X-ray diffractions gave a basal distance of 1.854 nm, near twice that of the natural talc and the 060 reflection confirmed a structure similar to natural talc. The basic centers on pendant chain coordinate divalent nickel, cadmium and lead cations from aqueous solution at the solid/liquid interface. Based on the Langmuir model, the maximum sorption capacity of the hybrid for these cations was 0.70, 1.10 and 2.71 mmol g-1, respectively. The thermodynamic data for cation/basic center interactions were determined through calorimetric titration, demonstrating spontaneous interactions, ΔG, exothermic enthalpic ΔH and positive entropy ΔS values. These favorable results for removal these toxic cations in a heterogeneous system may be useful for remove ions from wastewaters. © 2014 Elsevier Ltd. | |
| dc.description | 2 | |
| dc.description | 3 | |
| dc.description | 1386 | |
| dc.description | 1393 | |
| dc.description | Sanchez, C., Belleville, P., Popall, M., Nicole, L., Applications of advanced hybrid organic-inorganic nanomaterials: From laboratory to market (2011) Chemical Society Reviews, 40, pp. 696-753. , arxiv:/21229132, 10.1039/c0cs00136h | |
| dc.description | Hoffmann, F., Fröba, M., Vitalising porous inorganic silica networks with organic functions - PMOs and related hybrid materials (2011) Chemical Society Reviews, 40, pp. 608-620. , arxiv:/21180714, 10.1039/c0cs00076k | |
| dc.description | De Paiva, L.B., Morales, A.R., Valenzuela Dïaz, F.R.V., Organoclays: Properties, preparation and applications (2008) Applied Clay Science, 42, pp. 8-24. , 10.1016/j.clay.2008.02.006 | |
| dc.description | Da Fonseca, M.G., Airoldi, C., New layered inorganic-organic nanocomposites containing n-propylmercapto copper phyllosilicates (2000) Journal of Materials Chemistry, 10, pp. 1457-1463. , 10.1039/b001556n | |
| dc.description | Carrado, K.A., Xu, L., Csencsits, R., Muntean, J.V., Use of organo- and alkoxysilanes in the synthesis of grafted and pristine clays (2001) Chemistry of Materials, 13 (10), pp. 3766-3773. , DOI 10.1021/cm010104o | |
| dc.description | Melo, Jr.M.A., Oliveira, F.J.V.E., Airoldi, C., Novel talc-like nickel phyllosilicates functionalized with ethanolamine and diethanolamine (2008) Applied Clay Science, 42, pp. 130-136. , 10.1016/j.clay.2008.01.017 | |
| dc.description | Badshah, S., Airoldi, C., Layered organoclay with talc-like structure as agent for thermodynamics of cations sorption at the solid/liquid interface (2011) Chemical Engineering Journal, 166, pp. 420-427. , 10.1016/j.cej.2010.10.078 | |
| dc.description | Macedo, T.R., Petrucelli, G.C., Pinto, A.A., Airoldi, C., Layered inorganic/organic mercaptopropyl pendant chain hybrid for chelating heavy cations (2011) Materials Research Bulletin, 46, pp. 2346-2352. , 10.1016/j.materresbull.2011.08.042 | |
| dc.description | Moscofian, A.S.O., Pires, V.M.T., Viana, A.P., Airoldi, C., Orgnanofunctionalized magnesium phyllosilicates as mono- or bifunctional entities for industrial dyes removal (2012) RSC Advances, 2, pp. 3502-3511. , 10.1039/c2ra00935h | |
| dc.description | Badshah, S., Airoldi, C., Layered inorganic-organic hybrid with talc-like structure for cation removal at the solid/liquid interface (2013) Thermochimica Acta, 552, pp. 28-36. , 10.1016/j.tca.2012.11.005 | |
| dc.description | Holmstrom, S.C., Patil, A.J., Butler, M., Mann, S., Influence of polymer co-intercalation on guest release from aminopropyl-functionalized magnesium phyllosilicate mesolamellar nanocomposites (2007) Journal of Materials Chemistry, 17 (37), pp. 3894-3900. , DOI 10.1039/b705158a | |
| dc.description | Lee, Y.C., Kim, E.J., Yang, J.W., Shin, H.J., Removal of malachite green by adsorption and precipitation using aminopropyl functionalized magnesium phyllosilicate (2011) Journal of Hazardous Materials, 192, pp. 62-70. , arxiv:/21616589 | |
| dc.description | Lee, Y.C., Kim, E.J., Ko, D.A., Yang, J.W., Water-soluble organo-building blocks of aminoclay as a soil-flushing agent for heavy metal contaminated soil (2011) Journal of Hazardous Materials, 196, pp. 101-108. , arxiv:/21944705, 10.1016/j.jhazmat.2011.08.077 | |
| dc.description | Gil, A.L., Arenas, J., Villaroel, M., Imbert, F., Castillo, H., Fontal, B., Heavier alcohols synthesis on cobalt phyllosilicate catalysts (2005) Journal of Molecular Catalysis. A, Chemical, 228, pp. 339-344. , 10.1016/j.molcata.2004.09.071 | |
| dc.description | Patil, A.J., Muthusamy, E., Mann, S., Synthesis and self-assembly of organoclay-wrapped biomolecules (2004) Angewandte Chemie - International Edition, 43 (37), pp. 4928-4933. , DOI 10.1002/anie.200453868 | |
| dc.description | Da Fonseca, M.G., Silva, C.R., Barone, J.A.S., Airoldi, C., Layered hybrid nickel phyllosilicates and reactivity of the gallery space (2000) Journal of Materials Chemistry, 10, pp. 789-795. , 10.1039/a907804e | |
| dc.description | Fonseca, M., Airoldi, C., Phyllosilicate-like structure anchored silylating agents: Calorimetric data on divalent cation-aminated centre interactions in the lamellar cavity (1999) Journal of the Chemical Society, Dalton Transactions, 21, pp. 3687-3692 | |
| dc.description | Fonseca, M.G., Airoldi, C., Mercaptopropyl magnesium phyllosilicate - Thermodynamic data on the interaction with divalent cations in aqueous solution (2000) Thermochimica Acta, 359, pp. 1-9. , 10.1016/S0040-6031(00)00490-1 | |
| dc.description | Kraus, U., Wiegand, J., Long-term effects of the Aznalcóllar mine spill-heavy metal content and mobility in soils and sediments of the Guadiamar river valley (SW Spain) (2006) Science of the Total Environment, 367 (2-3), pp. 855-871. , DOI 10.1016/j.scitotenv.2005.12.027, PII S0048969705009253 | |
| dc.description | Zhuang, X., Zhao, Q., Wan, Y., Multi-constituent co-assembling ordered mesoporous thiol-functionalized hybrid materials: Synthesis and adsorption properties (2010) Journal of Materials Chemistry, 20, pp. 4715-4724. , 10.1039/c000063a | |
| dc.description | Kurniawan, T.A., Chan, G.Y.S., Lo, W.H., Babel, S., Physico-chemical treatment techniques for wastewater laden with heavy metals (2006) Chemical Engineering Journal, 118, pp. 83-98. , 10.1016/j.cej.2006.01.015 | |
| dc.description | Barbette, F., Rascalou, F., Chollet, H., Babouhot, J.L., Denat, F., Guilard, R., Extraction of uranyl ions from aqueous solutions using silica-gel-bound macrocycles for alpha contaminated waste water treatment (2004) Analytica Chimica Acta, 502 (2), pp. 179-187. , DOI 10.1016/j.aca.2003.09.065 | |
| dc.description | Sayari, A., Hamoudi, S., Yang, Y., Applications of pore-expanded mesoporous silica. 1. Removal of heavy metal cations and organic pollutants from wastewater (2005) Chemistry of Materials, 17 (1), pp. 212-216. , DOI 10.1021/cm048393e | |
| dc.description | Khan, A., Badshah, S., Airoldi, C., Biosorption of some toxic metal ions by chitosan modified with glycidylmethacrylate and diethylenetriamine (2011) Chemical Engineering Journal, 171, pp. 159-166. , 10.1016/j.cej.2011.03.081 | |
| dc.description | Basso, M.C., Cerrella, E.G., Cukierman, A.L., Lignocellulosic materials as potential biosorbents of trace toxic metals from wastewater (2002) Industrial and Engineering Chemistry Research, 41 (15), pp. 3580-3585 | |
| dc.description | Saeed, A., Iqbal, M., Akhtar, M.W., Removal and recovery of lead(II) from single and multimetal (Cd, Cu, Ni, Zn) solutions by crop milling waste (black gram husk) (2005) Journal of Hazardous Materials, 117 (1), pp. 65-73. , DOI 10.1016/j.jhazmat.2004.09.008, PII S0304389404004704 | |
| dc.description | Sciban, M., Klasnja, M., Skrbic, B., Modified softwood sawdust as adsorbent of heavy metal ions from water (2006) Journal of Hazardous Materials, 136 (2), pp. 266-271. , DOI 10.1016/j.jhazmat.2005.12.009, PII S0304389405008022 | |
| dc.description | Anirudhan, T.S., Divya, L., Ramachandran, M., Mercury(II) removal from aqueous solutions and wastewaters using a novel cation exchanger derived from coconut coir pith and its recovery (2008) Journal of Hazardous Materials, 157, pp. 620-627. , arxiv:/18313209, 10.1016/j.jhazmat.2008.01.030 | |
| dc.description | Santana, S.A.A., Vieira, A.P., Da, S.F.E.C., Melo, J.C.P., Airoldi, C., Immobilization of ethylenesulfide on babassu coconut epicarp and mesocarp for divalent cation sorption (2010) Journal of Hazardous Materials, 174, pp. 714-719. , arxiv:/19836886, 10.1016/j.jhazmat.2009.09.109 | |
| dc.description | Hua, M., Zhang, S., Pan, B., Zhang, W., Lv, L., Zhang, Q., Heavy metal removal from water/wastewater by nanosized metal oxides: A review (2012) Journal of Hazardous Materials, 211-212, pp. 317-331. , arxiv:/22018872, 10.1016/j.jhazmat.2011.10.016 | |
| dc.description | Moscofian, A.S.O., Airoldi, C., Synthesized layered inorganic-organic magnesium organosilicate containing a disulfide moiety as a promising sorbent for cations removal (2008) Journal of Hazardous Materials, 160, pp. 63-69. , arxiv:/18395976, 10.1016/j.jhazmat.2008.02.084 | |
| dc.description | Burkett, S.L., Press, A., Mann, S., Synthesis, Characterization, and Reactivity of Layered Inorganic-Organic Nanocomposites Based on 2:1 Trioctahedral Phyllosilicates (1997) Chemistry of Materials, 9 (5), pp. 1071-1073 | |
| dc.description | Gatta, G.D., Merlini, M., Valdrè, G., Liermann, H.P., Nénert, G., Rothkirch, A., On the crystal structure and compressional behavior of talc: A mineral of interest in petrology and material science (2013) Physics and Chemistry of Minerals, 40, pp. 145-156. , 10.1007/s00269-012-0554-4 | |
| dc.description | Kogure, T., Jige, M., Kameda, J., Yamagishi, A., Miyawaki, R., Kitagawa, R., Stacking structures in pyrophyllite revealed by high-resolution transmission electron microscopy (HRTEM) (2006) American Mineralogist, 91 (8-9), pp. 1293-1299. , DOI 10.2138/am.2006.1997 | |
| dc.description | Petit, S., Martin, F., Wiewiora, A., De Parseval, P., Decarreau, A., Crystal-chemistry of talc: A near infrared (NIR) spectroscopy study (2004) American Mineralogist, 89 (2-3), pp. 319-326 | |
| dc.description | Huheey, J.E., Keiter, F.A., Kieter, R.L., (1993) Inorganic Chemistry: Principles of Structure and Reactivity, , fourth ed. Harper Collins College New York | |
| dc.description | Richard-Plouet, M., Vilminot, S., Guillot, M., Kurmoo, M., Canted antiferromagnetism in an organo-modified layered nickel phyllosilicate (2002) Chemistry of Materials, 14, pp. 3829-3836. , 10.1021/cm0211498 | |
| dc.description | Fyfe, C.A., Zhang, Y., Aroca, P., An alternative preparation of organofunctionalized silica gels and their characterization by two-dimensional high-resolution solid-state heteronuclear NMR correlation spectroscopy (1992) Journal of the American Chemical Society, 114, pp. 3252-3255. , 10.1021/ja00035a014 | |
| dc.description | Nakata, S., Tanaka, Y., Asaoka, S., Nakamura, M., Recent advances in applications of multinuclear solid-state NMR to heterogeneous catalysis and inorganic materials (1998) Journal of Molecular Structure, 441 (2-3), pp. 267-281. , DOI 10.1016/S0022-2860(97)00259-7, PII S0022286097002597 | |
| dc.description | Whilton, N.T., Burkett, S.L., Mann, S., Hybrid lamellar nanocomposites based on organically functionalized magnesium phyllosilicate clays with interlayer reactivity (1998) Journal of Materials Chemistry, 8 (8), pp. 1927-1932. , 8/02120A | |
| dc.description | Perez-Maqueda, L.A., Franco, F., Perez-Rodriguez, J.L., Comparative study of the sonication effect on the thermal behaviour of 1:1 and 2:1 aluminium phyllosilicate clays (2005) Journal of the European Ceramic Society, 25 (9), pp. 1463-1470. , DOI 10.1016/j.jeurceramsoc.2004.06.005, PII S0955221904002730 | |
| dc.description | Gallego, J.-C., Jaber, M., Miehe-Brendle, J., Marichal, C., Synthesis of new lamellar inorganic-organic talc-like hybrids (2008) New Journal of Chemistry, 32 (3), pp. 407-412. , DOI 10.1039/b713004j | |
| dc.description | Fukushima, Y., Tani, M., An organic/inorganic hybrid layered polymer: Methacrylate- magnesium(nickel) phyllosilicate (1995) Journal of the Chemical Society. Chemical Communications, pp. 241-242 | |
| dc.description | Silva, C.R., Fonseca, M.G., Barone, J.S., Airoldi, C., Layered inorganic-organic talc-like nanocomposites (2002) Chemistry of Materials, 14, pp. 175-179. , 10.1021/cm010474c | |
| dc.description | De Farias, R.F., Airoldi, C., Thermogravimetry as a reliable tool to estimate the density of silanols on a silica gel surface (1998) Journal of Thermal Analysis and Calorimetry, 53 (3), pp. 751-756 | |
| dc.description | Melo, Jr.M.A., Airoldi, C., Energetic features of copper and lead sorption by innovative aminoalcohol-functionalizedcobaltphyllosilicates (2010) Dalton Transactions (Cambridge, England: 2003), 39, pp. 10217-10227. , arxiv:/20922219, 10.1039/c0dt00413h | |
| dc.description | Macedo, T.R., Petrucelli, G.C., Airoldi, C., Sorption and thermodynamic of cation-basic center interactions of inorganic-organic hybrids synthesized from RUB-18 (2010) Thermochimica Acta, 502, pp. 30-34. , 10.1016/j.tca.2010.02.001 | |
| dc.description | Marcus, Y., The thermodynamics of solvation of ions. Part 2. The enthalpy of hydration at 298.15 K (1987) Journal of the Chemical Society, Faraday Transactions, 1 (83), pp. 339-349 | |
| dc.description | MacHado, M.O., Lazarin, A.M., Airoldi, C., Thermodynamic features associated with intercalation of some n-alkylmonoamines into barium phosphate (2006) Journal of Chemical Thermodynamics, 38 (2), pp. 130-135. , DOI 10.1016/j.jct.2005.04.008, PII S0021961405000844 | |
| dc.description | Lopes, E.C.N., Sousa, K.S., Airoldi, C., Chitosan-cyanuric chloride intermediary as a source to incorporate molecules - Thermodynamic data of copper/biopolymer interactions (2009) Thermochimica Acta, 483, pp. 21-28. , 10.1016/j.tca.2008.10.022 | |
| dc.language | en | |
| dc.publisher | Elsevier Ltd | |
| dc.relation | Journal of Environmental Chemical Engineering | |
| dc.rights | fechado | |
| dc.source | Scopus | |
| dc.title | Pendant Chains Containing Thiopropanamide Groups Inside Talc-like Phyllosilicate Galleries As Thermodynamically Favorable Agents For Cation Removal | |
| dc.type | Artículos de revistas | |
