Substituent-induced 1h Chemical Shifts Of 3-substituted Camphors

dc.creatorKaiser C.R.
dc.creatorRittner R.
dc.creatorBasso E.A.
dc.date1997
dc.date2015-06-30T14:49:05Z
dc.date2015-11-26T14:41:35Z
dc.date2015-06-30T14:49:05Z
dc.date2015-11-26T14:41:35Z
dc.date.accessioned2018-03-28T21:48:37Z
dc.date.available2018-03-28T21:48:37Z
dc.identifier
dc.identifierMagnetic Resonance In Chemistry. , v. 35, n. 9, p. 609 - 613, 1997.
dc.identifier7491581
dc.identifier
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0031533736&partnerID=40&md5=f35229c7630cd62830f16fef3d982d97
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/100161
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/100161
dc.identifier2-s2.0-0031533736
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1250906
dc.descriptionThe high-field 1H NMR analysis of 3-substituted camphors with OH, OMe, SMe, NHMe, NMe2 and Me substituents at endo and exo positions, and also with an oxo substituent, is reported. The substituent-induced chemical shifts (SCS) obtained for these difunctional systems, including those from previous work on 3-halocamphors, were examined in view of multilinear correlations with steric and electronic parameters. The resultant data show a strong contribution from the electric field mechanism, principally for the protons closer to the substituent. Carbonyl group interference on the expected SCS for the α-proton is also observed, with less deshielding than those of substituted bornanes and norbornanes. © 1997 by John Wiley & Sons, Ltd.
dc.description35
dc.description9
dc.description609
dc.description613
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dc.languageen
dc.publisher
dc.relationMagnetic Resonance in Chemistry
dc.rightsfechado
dc.sourceScopus
dc.titleSubstituent-induced 1h Chemical Shifts Of 3-substituted Camphors
dc.typeArtículos de revistas


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