Artículos de revistas
Remote Intramolecular Functionalization Of Arylnitrenium Ions. Ipso-substitution And Spiro-lactone Formation
Registro en:
Journal Of The Chemical Society, Chemical Communications. , v. , n. 4, p. 283 - 284, 1986.
224936
10.1039/C39860000283
2-s2.0-37049077699
Autor
Abramovitch R.A.
Hawi A.
Rodrigues J.A.R.
Trombetta T.R.
Institución
Resumen
Acid-catalysed decomposition of (4′-azidophenyl)propanoic and butyric acids leads to ipso-attack by the carboxy group para to the nitrenium ion and the formation of imines of cyclohexadienone spiro-lactones, which can rearrange to the benz-fused lactones; 4′-azido-2-carboxydiphenyl ether behaves the same way to give spiro-lactone (9).
4 283 284