Thermochemical Properties Of Chelates Of Di-n-butyldithiocarbamate With Phosphorus-group Elements

dc.creatorAiroldi C.
dc.creatorDe Souza A.G.
dc.date1989
dc.date2015-06-30T13:40:52Z
dc.date2015-11-26T14:37:06Z
dc.date2015-06-30T13:40:52Z
dc.date2015-11-26T14:37:06Z
dc.date.accessioned2018-03-28T21:41:20Z
dc.date.available2018-03-28T21:41:20Z
dc.identifier
dc.identifierThe Journal Of Chemical Thermodynamics. , v. 21, n. 3, p. 283 - 291, 1989.
dc.identifier219614
dc.identifier10.1016/0021-9614(89)90018-9
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0008618541&partnerID=40&md5=3be2da94e3ee2b4b9c32d2a5c4a331ff
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/98202
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/98202
dc.identifier2-s2.0-0008618541
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1249019
dc.descriptionThe standard molar enthalpies of formation of crystalline tris(di-n-butyldithiocarbamato)e(III), (e = P, As, Sb, or Bi), determined at 298.15 K by solution-reaction calorimetry, are -(705.5 ± 7.3), -(443.1 ± 5.4), -(526.2 ± 2.5), and -(530.7 ± 5.5) kJ·mol-1, respectively. The enthalpies of sublimation: (136 ± 3), (128 ± 3), (179 ± 3), and (202 ± 3) kJ·mol-1, were estimated. From the enthalpies of formation of the gaseous complexes, the homolytic and hemolytic and heterolytic mean standard molar element-sulphur bond enthalpies were calculated. These values are correlated with element-sulphur bond distances, and a larger phosphorus-sulphur bond enthalpy reflects a better overlap of d orbitals in bonding formation. © 1989.
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dc.languageen
dc.publisher
dc.relationThe Journal of Chemical Thermodynamics
dc.rightsfechado
dc.sourceScopus
dc.titleThermochemical Properties Of Chelates Of Di-n-butyldithiocarbamate With Phosphorus-group Elements
dc.typeArtículos de revistas


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