The Removal Of Cu(ii) And Co(ii) From Aqueous Solutions Using Cross-linked Chitosan-evaluation By The Factorial Design Methodology

dc.creatorCestari A.R.
dc.creatorVieira E.F.S.
dc.creatorde Oliveira I.A.
dc.creatorBruns R.E.
dc.date2007
dc.date2015-06-30T18:46:59Z
dc.date2015-11-26T14:35:33Z
dc.date2015-06-30T18:46:59Z
dc.date2015-11-26T14:35:33Z
dc.date.accessioned2018-03-28T21:38:58Z
dc.date.available2018-03-28T21:38:58Z
dc.identifier
dc.identifierJournal Of Hazardous Materials. , v. 143, n. 01/02/15, p. 8 - 16, 2007.
dc.identifier3043894
dc.identifier10.1016/j.jhazmat.2006.08.063
dc.identifierhttp://www.scopus.com/inward/record.url?eid=2-s2.0-34147141003&partnerID=40&md5=1cfcdea657477d1d2d2b5c1b6e942167
dc.identifierhttp://www.repositorio.unicamp.br/handle/REPOSIP/104756
dc.identifierhttp://repositorio.unicamp.br/jspui/handle/REPOSIP/104756
dc.identifier2-s2.0-34147141003
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/1248404
dc.descriptionA 23 factorial design was employed to evaluate the quantitative removal of Cu(II) and Co(II) on glutaraldehyde-cross-linked chitosan from kinetic isotherms, using chitosan masses of 100 and 300 mg and temperatures of 25 and 35 °C. The adsorption parameters were analyzed statistically using modeling polynomial equations and a cumulative normal probability plot. The results indicated the higher quantitative preference of the chitosan for Cu(II) in relation to Co(II). Increasing the chitosan mass decreases the adsorption/mass ratio (mol g-1) for both metals. The principal effect of the temperature did not show statistical importance. The adsorption thermodynamic parameters, namely ΔadsH, ΔadsG and ΔadsS, were determined. Exothermic and endothermic results were found in relation to a specific factorial design experiment. A comparison of ΔadsH values was made in relation to some metal-adsorbent interactions in literature. It is suggested that the adsorption thermodynamic parameters are determined by the influence of the principal and interactive experimental parameters and not by the temperature changes alone. © 2006 Elsevier B.V. All rights reserved.
dc.description143
dc.description01/02/15
dc.description8
dc.description16
dc.descriptionUnited States Environmental Protection Agency (USEPA), (1992) National Primary Drinking Water Regulations, , USEPA, USA
dc.descriptionCrini, G., Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment (2005) Prog. Polym. Sci., 30, pp. 38-70
dc.descriptionGuibal, E., Interactions of metal ions with chitosan-based sorbents: a review (2004) Separ. Purif. Technol., 38, pp. 43-74
dc.descriptionGuibal, E., Heterogeneous catalysis on chitosan-based materials: a review (2005) Prog. Polym. Sci., 30, pp. 71-109
dc.descriptionVarma, A.J., Deshpande, S.V., Kennedy, J.F., Metal complexation by chitosan and its derivatives: a review (2004) Carbohydr. Polym., 55, pp. 77-93
dc.descriptionMuzzarelli, R.A.A., (1973) Natural Chelating Polymers: Alginic Acid, Chitin and Chitosan, , Pergamon Press, Oxford
dc.descriptionNo, H.K., Meyers, S.P., Application of chitosan for treatment of wastewaters (2000) Rev. Environ. Contam. Toxicol., 163, pp. 1-28
dc.descriptionSun, W.Q., Payne, G.F., Moas, M.S.G.L., Chu, J.H., Wallace, K.K., Tyrosinase reaction/chitosan adsorption for removing phenols from wastewater (1992) Biotechnol. Prog., 8, pp. 179-186
dc.descriptionMagalhães, J.M.C.S., Machado, A.A.S.C., Urea potentiometric biosensor based on urease immobilized on chitosan membranes (1998) Talanta, 47, pp. 183-191
dc.descriptionZeng, X., Ruckenstein, E., Cross-linked macroporous chitosan anion-exchange membranes for protein separations (1998) J. Membr. Sci., 148, pp. 195-205
dc.descriptionJuang, R.S., Wu, F.C., Tseng, R.L., Solute adsorption and enzyme immobilization on chitosan beads prepared from shrimp shell wastes (2001) Biores. Technol., 80, pp. 187-193
dc.descriptionMonteiro Jr., O.A.C., Airoldi, C., Some thermodynamic data on copper-chitin and copper-chitosan biopolymer interactions (1999) J. Colloid Interf. Sci., 212, pp. 212-219
dc.descriptionKaratepe, N., Adsorption of a non-ionic dispersant on lignite particle surfaces (2003) Energy Conver. Manage., 44, pp. 1275-1284
dc.descriptionChegrouche, S., Bensmaili, A., Removal of Ga(III) from aqueous solution by adsorption on activated bentonite using a factorial design (2002) Water Res., 36, pp. 2898-2904
dc.descriptionAnnadurai, G., Juang, R.S., Lee, D.J., Factorial design analysis for adsorption of dye on activated carbon beads incorporated with calcium alginate (2002) Adv. Environ. Res., 6, pp. 191-198
dc.descriptionNicholls, G., Clark, B.J., Brown, J.E., Solid-phase extraction and optimized separation of doxorubicin, epirubicin and their metabolites using reversed-phase high-performance liquid chromatography (1992) J. Pharm. Biomed. Anal., 10, pp. 949-957
dc.descriptionde Brito, D., Campana, S.P., A kinetic study on the thermal degradation of N,N,N-trimethylchitosan (2004) Polym. Degrad. Stab., 84, pp. 353-361
dc.descriptionMonteiro Jr., O.A.C., Airoldi, C., The influence of chitosans with defined degrees of acetylation on the thermodynamic data for copper coordination (2005) J. Colloid Interf. Sci., 282, pp. 32-37
dc.descriptionLeal, O., Bolévar, C., Ovalles, C., Garcia, J.J., Espidel, Y., Reversible adsorption of carbon dioxide on amine surface-bonded silica gel (1995) Inorg. Chim. Acta, 240, pp. 183-189
dc.descriptionVieira, E.F.S., Cestari, A.R., Simoni, J.A., Airoldi, C., Thermochemical data for interaction of some primary amines with complexed mercury on mercapto-modified silica gel (2003) Thermochim. Acta, 399, pp. 121-126
dc.descriptionLopes, E.C.N., dos Anjos, F.S.C., Vieira, E.F.S., Cestari, A.R., An alternative Avrami equation to evaluate kinetic parameters of the interaction of Hg(II) with thin chitosan membranes (2003) J. Colloid Interf. Sci., 263, pp. 542-547
dc.descriptionCestari, A.R., Vieira, E.F.S., Bruns, R.E., Airoldi, C., Some new data for metal desorption on inorganic-organic hybrid materials (2000) J. Colloid Interf. Sci., 227, pp. 66-70
dc.descriptionCestari, A.R., Vieira, E.F.S., Silva, E.S., Interactions of anionic dyes with silica-aminopropyl. 1. A quantitative multivariate analysis of equilibrium adsorption and adsorption Gibbs free energies (2006) J. Colloid Interf. Sci., 297, pp. 22-30
dc.descriptionCestari, A.R., Vieira, E.F.S., dos Santos, A.G.P., Mota, J.A., de Almeida, V.P., Adsorption of anionic dyes on chitosan beads. 1. The influence of the chemical structures of dyes and temperature on the adsorption kinetics (2004) J. Colloid Interf. Sci., 280, pp. 380-386
dc.descriptionBox, G.P.G., Hunter, W.G., Hunter, J.S., (1978) Statistics for Experimenters: An Introduction for Design, Data Analysis and Model Building, , John Wiley & Sons, New York
dc.descriptionCestari, A.R., Vieira, E.F.S., Nascimento, A.J.P., Airoldi, C., New factorial designs to evaluate chemisorption of divalent metals on aminated silicas (2001) J. Colloid Interf. Sci., 241, pp. 45-51
dc.descriptionShen, J., Duvnjak, Z., Adsorption kinetics of cupric and cadmium ions on corncob particles (2005) Process Biochem., 40, pp. 3446-3454
dc.descriptionHo, Y.-S., Ofomaja, A.E., Kinetics and thermodynamics of lead ion sorption on palm kernel fibres from aqueous solution (2005) Process Biochem., 40, pp. 3455-3461
dc.descriptionTahir, S.S., Rauf, N., Thermodynamic studies of Ni(II) adsorption onto bentonite from aqueous solution (2003) J. Chem. Thermodyn., 35, pp. 2003-2009
dc.descriptionGimenez-Martin, E., Espinosa-Jiménez, M., Influence of tannic acid in leacril/rhodamine B system: thermodynamics aspects (2005) Colloids Surf. A, 270-271, pp. 93-101
dc.descriptionLima, I.S., Airoldi, C., A thermodynamic investigation on chitosan-divalent cation interactions (2004) Thermochim. Acta, 421, pp. 133-139
dc.descriptionMohan, D., Pittman Jr., C.U., Steele, P.H., Single, binary and multi-component adsorption of copper and cadmium from aqueous solutions on Kraft lignin-a biosorbent (2006) J. Colloid Interf. Sci., 297, pp. 489-504
dc.descriptionEl-Batouti, M., Sadek, O.M., Assaad, F.F., Kinetics and thermodynamics studies of copper exchange on Na-montmorillonite clay mineral (2003) J. Colloid Interf. Sci., 259, pp. 223-227
dc.descriptionBurgess, J., (1978) Metal Ions in Solution, , John Wiley & Sons, New York
dc.descriptionRomero-Gonzalez, J., Peralta-Videa, J.R., Rodriguez, E., Ramirez, S.L., Gardea-Torresdey, J.L., Determination of thermodynamic parameters of Cr(VI) adsorption from aqueous solution onto Agave lechuguilla biomass (2005) J. Chem. Thermodyn., 37, pp. 343-347
dc.descriptionMeena, A.K., Mishra, G.K., Rai, P.K., Rajagopal, C., Nagar, P.N., Removal of heavy metal ions from aqueous solutions using carbon aerogel as an adsorbent (2005) J. Hazard. Mater. B, 122, pp. 161-170
dc.descriptionEspínola, J.G.P., Arakaki, L.N.H., Oliveira, S.F., da Fonseca, M.G., Campos Filho, J.A.A., Airoldi, C., Some thermodynamic data of the energetics of the interaction cation-piperazine immobilized on silica gel (2003) Colloids Surf. A, 221, pp. 101-108
dc.descriptionChang, Y.-C., Chen, D.-H., Preparation and adsorption properties of monodisperse chitosan-bound Fe3O4 magnetic nanoparticles for removal of Cu(II) ions (2005) J. Colloid Interf. Sci., 283, pp. 446-451
dc.descriptionYavuz, O., Altunkaynak, Y., Guzel, F., Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite (2003) Water Res., 37, pp. 948-952
dc.descriptionCestari, A.R., Vieira, E.F.S., Simoni, J.A., Airoldi, C., Thermochemical investigation on the adsorption of some divalent cations on modified silicas obtained from sol-gel process (2000) Thermochim. Acta, 348, pp. 25-31
dc.descriptionSag, Y., Kutsal, T., Determination of the biosorption heats of heavy metal ions on Zoogloea ramigera and Rhizopus arrhizus (2000) Biochem. Eng. J., 6, pp. 145-151
dc.descriptionAcemioglu, B., Alma, M.H., Equilibrium studies on adsorption of Cu(II) from aqueous solution onto cellulose (2001) J. Colloid Interf. Sci., 243, pp. 81-84
dc.descriptionLima, I.S., Airoldi, C., Interaction of copper with chitosan and succinic anhydride derivative-a factorial design evaluation of the chemisorption process (2004) Thermochim. Acta, 421, pp. 133-139
dc.descriptionRodda, D.P., Wells, J.D., Johnson, B.B., Anomalous adsorption of Copper(II) on goethite (1996) J. Colloid Interf. Sci., 184, pp. 564-569
dc.descriptionLima, I.S., Lazarin, A.M., Airoldi, C., Favorable chitosan/cellulose film combinations for copper removal from aqueous solutions (2005) Int. J. Biol. Macromol., 36, pp. 79-83
dc.descriptionCestari, A.R., Vieira, E.F.S., Matos, C.R.S., Thermodynamics of adsorption of Cu(II) on vanillin-modified thin chitosan membranes (2006) J. Chem. Thermodyn., 38, pp. 1092-1099
dc.descriptionKalavathy, M.H., Karthikeyan, T., Rajgopal, S., Miranda, L.R., Kinetic and isotherm studies of Cu(II) adsorption onto H3PO4-activated rubber wood sawdust (2005) J. Colloid Interf. Sci., 292, pp. 354-362
dc.descriptionRamnani, S.P., Chaudhari, C.V., Patil, N.D., Sabharwal, S., Synthesis and Characterization of cross-linked chitosan formed by gamma irradiation in the presence of carbontetrachloride as a sensitizer (2004) J. Polym. Sci. A, 42, pp. 3897-3909
dc.descriptionAiroldi, C., Alcântara, E.F.C., Chemisorption of divalent cations on N-(2-pyridyl)acetamide immobilized on silica gel-a thermodynamic study (1995) J. Chem. Thermodyn., 27, pp. 623-632
dc.descriptionWang, S., Li, H., Xu, L., Application of zeolite MCM-22 for basic dye removal from wastewater (2006) J. Colloid Interf. Sci., 295, pp. 71-78
dc.descriptionLyubchik, S.I., Lyubchik, A.I., Galushka, D.L., Tikhonova, L.P., Vital, J., Fonseca, I.M., Lyubchik, S.B., Kinetics and thermodynamics of the Cr(III) adsorption on the activated carbon from co-mingled wastes (2004) Colloids Surf. A, 242, pp. 151-158
dc.descriptionUslu, G., Tanyol, M., Removal of Cu(II) using Pseudomonas putida (2006) J. Hazard. Mater. B, 135, pp. 87-93
dc.descriptionYavuz, O., Altunkaynak, Y., Guzel, F., Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite (2003) Water Res., 37, pp. 948-952
dc.languageen
dc.publisher
dc.relationJournal of Hazardous Materials
dc.rightsfechado
dc.sourceScopus
dc.titleThe Removal Of Cu(ii) And Co(ii) From Aqueous Solutions Using Cross-linked Chitosan-evaluation By The Factorial Design Methodology
dc.typeArtículos de revistas


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